The rediscovery of a unicum manuscript source of cantates françaises by Philippe II d'Orléans in the Württembergische Landesbibliothek, Stuttgart, provokes a re-evaluation of not only the provenance of the collection to which it belongs, but also the role played by diplomacy, sociability and cultural exchange in the history of the cantate française. The manuscript's contents all reflect Philippe's use of international connections to acquire music and engage musicians in the period 1701–1706. The manuscript forms part of a corpus of French scores that belonged to Marie-Thérèse de Lannoy de La Motterie, an aristocratic amateur harpsichordist with an interest in both French and Italian music, and in cantates. As wife of Joseph Lothar von Königsegg und Rothenfels, representative of the Austrian emperor to Philippe, then regent of France, she was engaged in the cultural life of Paris during the period 1717–1719, not only acquiring cantate prints but also a copy of Philippe's own works in the genre. Her collection reflects both her personal interests and her diplomatic cultivation of the social circles around Philippe in which music connoisseurship was an important skill. The manuscript thus highlights the important role played in the international transmission of cantates françaises by diplomatic and familial connections of noble amateurs, especially those curious about musical developments beyond their own regional practices.