The third chapter examines the capabilities of liquid-state NMR systems for quantum computing. It begins by grounding the reader in the basics of spin dynamics and NMR spectroscopy, followed by a discussion on the encoding of qubits into the spin states of the nucleus of atoms inside molecules. The narrative progresses to describe the implementation of single-qubit gates via external magnetic fields, weaving in key concepts such as the rotating-wave approximation, the Rabi cycle, and pulse shaping. The technique for orchestrating two-qubit gates, leveraging the intrinsic couplings between the spins of nuclei of atoms within a molecule, is subsequently detailed. Additionally, the chapter explains the process of detecting qubits’ states through the collective nuclear magnetization of the NMR sample and outlines the steps for qubit initialization. Attention then shifts to the types of noise that affect NMR quantum computers, shedding light on decoherence and the critical T1 and T2 times. The chapter wraps up by providing a synopsis, evaluating the strengths and weaknesses of liquid-state NMR for quantum applications, and a note on the role of entanglement in quantum computing.

This chapter surveys several different mathematical methods for time-dependent change of quantum states using quantum field theory. The Bloch sphere method is introduced, which can be used to show the physics discussed in Chapter 3, that electronic transitions, or “jumps,” are not instantaneous.

Appendix G: interaction between a monochromatic field and two-level atom. The problem is treated first in the case of a classical field and a quantum two-level system (semiclassical approach): It is characterised by a rotation of the Bloch vector (Rabi ocillation) and allows us to generate any qubit state by applying a field of well-controlled duration and amplitude. One then includes spontaneous emission to the model, and finally obtains the set of Bloch equations that are used in many different problems of light–matter interaction. One then considers the full quantum case of cavity quantum electrodynamics (CQED), where the field is single mode and fully quantum: this is the Jaynes–Cummings Hamiltonian approach, which is fully solvable when one negelcts spontaneous emission: quantum oscillations and revivals are predicted. Damping is then introduced in the model, and two regimes of strong and weak couplings are predicted in this case.

Welearn the key aspect of quantum mechanics – how to predict the future with Schrödinger’s equation. We learn the general recipe for solving time-dependent problems by diagonalizing the Hamiltonian to find the energy eigenvalues and eigenvectors.