Spatial confinement effects on plasma parameters and surface morphology of laser-ablated Mg are studied by introducing a metallic blocker as well as argon (Ar) gas at different pressures. Nd: YAG laser at various fluences ranging from 7 to 28 J/cm2 was employed to generate Mg plasma. Confinement effects offered by metallic blocker are investigated by placing the blocker at different distances of 6, 8, and 10 mm from the target surface; whereas spatial confinement offered by environmental gas is explored under four different pressures of 5, 10, 20, and 50 Torr. Laser-induced breakdown spectroscopy analysis revealed that both plasma parameters, that is, excitation temperature and electron number density initially are strongly dependent upon both pressures of environmental gases and distances of blockers. The maximum electron temperature of Mg plasma is achieved at Ar gas pressure of 20 Torr, whereas maximum electron number density is achieved at 50 Torr. It is also observed that spatial confinement offered by metallic blocker is responsible for the significant enhancement of both electron temperature and electron number density of Mg plasma. Maximum values of electron temperature and electron number density without blocker are 8335 K and 2.4 × 1016 cm−3, respectively, whereas these values are enhanced to 12,200 K and 4 × 1016 cm−3 in the presence of blocker. Physical mechanisms responsible for the enhancement of Mg plasma parameters are plasma compression, confinement and pronounced collisional excitations due to reflection of shock waves. Scanning electron microscope analysis was performed to explore the surface morphology of laser-ablated Mg. It reveals the formation of ripples and channels that become more distinct in the presence of blocker due to plasma confinement. The optimum combination of blocker distance, fluence and Ar pressure can identify the suitable conditions for defining the role of plasma parameters for surface structuring.

This paper presents a simplified theoretical model for the study of emission from laser produced plasma to better understand the processes and the factors involved in the onset of saturation in plasma emission as well as in increasing emission due to plasma confinement. This model considers that plasma emission is directly proportional to the square of plasma density, its volume, and the fraction of laser pulse absorbed through inverse Bremsstrahlung in the pre-formed plasma plume produced by the initial part of the laser. This shows that plasma density and temperature (that means the electron-ion collision frequency νei) decide the threshold for saturation in emission, which occurs for νei ≥ 1013 s−1, beyond which plasma shielding effects become dominant. Any decrease in plasma sound (expansion) velocity shows drastic enhancement in emission supporting the results obtained by magnetic as well as spatial confinement of laser produced plasma. The temporal evolution of plasma emission in the absence and presence of plasma confinement along with the effect of laser pulse duration are also discussed in the light of this model.