In this paper, we consider positive linear operators L representable in terms of stochastic processes Z having right-continuous non-decreasing paths. We introduce the equivalent notions of derived operator and derived process of order n of L and Z, respectively. When acting on absolutely continuous functions of order n, we obtain a Taylor's formula of the same order for such operators, thus extending to a positive linear operator setting the classical Taylor's formula for differentiable functions. It is also shown that the operators satisfying Taylor's formula are those which preserve generalized convexity of order n. We illustrate the preceding results by considering discrete time processes, counting and renewal processes, centred subordinators and the Yule birth process.