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Formation of Highly Selective Cesium-Exchange Sites in Montmorillonites
André Maes, Dirk Verheyden, Adrien Cremers
Journal:

Clays and Clay Minerals / Volume 33 / Issue 3 / June 1985

Published online by Cambridge University Press:

02 April 2024, pp. 251-257
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Ion-exchange sites with very high selectivity for Cs ( $Δ G_{{C a}^{2 +}}^{{C s}^{+}}$ = 40 kJ/eq) similar to illite were generated in a controlled way in montmorillonites b. (1) repeated wetting-drying cycles and b. (2) charge reduction using the Hofmann-Klemen effect. An almost continuous range of sites with selectivities varying from ln $K_{{C a}^{2 +}}^{{C s}^{+}}$ = 33 to 5 was observed.

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Formation of Highly Selective Cesium-Exchange Sites in Montmorillonites