Samples of ash layers and associated background sediments from Site 808 of ODP Leg 131 in the Nankai Trough accretionary prism were analyzed for changes in mineralogy, porosity and micro-fabric associated with alteration of volcanic ash. Ash layers range from incipient stages of alteration and dissolution to complete alteration to clay minerals and clinoptilolite. Ash layers contain greater abundances of total clay minerals and lower percentages of quartz than do surrounding background hemipelagic sediments. The clay-sized fraction of ash layers is dominated by pure dioctahedral smectite, whereas the background sediments contain primarily illite and chlorite with minor amounts of smectite. Analysis of microfabric revealed dramatic changes in the distributions and abundances of grains and pores during ash alteration. The relative abundances of large pores, grains, and matrix material were quantified on digital back-scattered electron images (BSEI) of ash layer and background sediment samples. During burial, the abundant glass shards of shallow ash layers are initially altered, presumably to smectite. Subsequent dissolution of the glass leaves open, shard-shaped pores, resulting in increased porosities. With greater burial, these pores are filled with clinoptilolite. Although the presence of ash and its alteration products clearly influences sediment physical properties, there is no apparent correlation of the abundance of ash or its alteration products with the formation of thrust faults or other structures within the Nankai Trough accretionary prism.

In the late Palaeozoic fore-arc system of north-central Chile at latitudes 31–32°S (from the west to the east) three lithotectonic units are telescoped within a short distance by a Mesozoic strike-slip event (derived peak P–T conditions in brackets): (1) the basally accreted Choapa Metamorphic Complex (CMC; 350–430°C, 6–9 kbar), (2) the frontally accreted Arrayán Formation (AF; 280–320°C, 4–6 kbar) and (3) the retrowedge basin of the Huentelauquén Formation (HF; 280–320°C, 3–4 kbar). In the CMC, Ar–Ar spot ages locally date white-mica formation at peak P–T conditions and during early exhumation at 279–242 Ma. In a local garnet mica-schist intercalation (570–585°C, 11–13 kbar) Ar–Ar spot ages refer to the ascent from the subduction channel at 307–274 Ma. Portions of the CMC were isobarically heated to 510–580°C at 6.6–8.5 kbar. The age of peak P–T conditions in the AF can only vaguely be approximated at ≥ 310 Ma by relict fission-track ages consistent with the observation that frontal accretion occurred prior to basal accretion. Zircon fission-track dating indicates cooling below ~ 280°C at ~ 248 Ma in the CMC and the AF, when a regional unconformity also formed. Ar–Ar white-mica spot ages in parts of the CMC and within the entire AF and HF point to heterogeneous resetting during Mesozoic extensional and shortening events at ~ 245–240 Ma, ~ 210–200 Ma, ~ 174–159 Ma and ~ 142–127 Ma. The zircon fission-track ages are locally reset at 109–96 Ma. All resetting of Ar–Ar white-mica ages is proposed to have occurred by in situ dissolution/precipitation at low temperature in the presence of locally penetrating hydrous fluids. Hence syn- and postaccretionary events in the fore-arc system can still be distinguished and dated in spite of its complex heterogeneous postaccretional overprint.

A thick Ordovician marine flysch succession including greywackes, conglomer- ates, siltstones and shales occurs in West Nithsdale in the Northern belt of the Southern Uplands. Five new formations of Caradoc and ?Ashgill age are defined based mainly on petrographical and lithological evidence. The proposed correlation with areas up to 80 km distant to the SW, emphasises the persistent nature of the greywacke formations in the Southern Uplands when traced along strike. It is demonstrated that the main inliers of black shale in the Northern belt cannot be simple anticlines but are closely associated with large strike faults. The position of the investigated flysch succession in the accretionary prism model for the development of the Southern Uplands during the evolution of the Caledonides is indicated and its significance assessed.