B supergiants (BSGs) lie on the cool end of line-driven wind regime, such that the study of their atmospheres can help us to understand the physics of line-driven winds. So far key features of their spectra, especially in the UV region, could not be reproduced consistently with atmosphere models. This represents a significant gap in our knowledge of their physical properties and behavior, which is particularly striking for BSGs on the cool side of the Bi-Stability Jump (cooler than B1). To address this problem, we analysed a sample of Galactic cool BSGs, with sufficient UV and optical coverage. None of our targets are detected in X-rays with only upper limits existing for some of them.