Precipitation of calcium phosphates occurs in dairy products and depending on pH and ionic environment, several salts with different crystallinity can form. The present study aimed to investigate the effects of NaCl and citrate on the characteristics of precipitates obtained from model solutions of calcium phosphate at pH 6·70 maintained constant or left to drift. The ion speciation calculations showed that all the starting solutions were supersaturated with respect to dicalcium phosphate dihydrate (DCPD), octacalcium phosphate (OCP) and hydroxyapatite (HAP) in the order HAP>OCP>DCPD. X-ray diffraction (XRD) and Fourier transform infrared (FTIR) analyses of the precipitates showed that DCPD was formed at drifting pH (acidic final pH) whereas poor crystallised calcium deficient apatite was mainly formed at constant pH (6·70). Laser light scattering measurements and electron microscopy observations showed that citrate had a pronounced inhibitory effect on the crystallisation of calcium phosphates both at drifting and constant pH. This resulted in the decrease of the particle sizes and the modification of the morphology and the microstructure of the precipitates. The inhibitory effect of citrate mainly acted by the adsorption of the citrate molecules onto the surfaces of newly formed nuclei of calcium phosphate, thereby changing the morphology of the growing particles. These findings are relevant for the understanding of calcium phosphate precipitation from dairy byproducts that contain large amounts of NaCl and citrate.

Plutonic complexes with interlayered mafic and silicic rocks commonly contain layers (1–50 m thick) with a chilled gabbroic base that grades upwards to dioritic or silicic cumulates. Each chilled base records the infusion of new basaltic magma into the chamber. Some layers preserve a record of double-diffusive convection with hotter, denser mafic magma beneath silicic magma. Processes of hybridisation include mechanical mixing of crystals and selective exchange of H2O, alkalis and isotopes. These effects are convected away from the boundary into the interiors of both magmas. Fractional crystallisation aad replenishment of the mafic magma can also generate intermediate magma layers highly enriched in incompatible elements.

Basaltic infusions into silicic magma chambers can significantly affect the thermal and chemical character of resident granitic magmas in shallow level chambers. In one Maine pluton, they converted resident I-type granitic magma into A-type granite and, in another, they produced a low-K (trondhjemitic) magma layer beneath normal granitic magma. If comparable interactions occur at deeper crustal levels, selective thermal, chemical and isotopic exchange should probably be even more effective. Because the mafic magmas crystallise first and relatively rapidly, silicic magmas that rise away from deep composite chambers may show little direct evidence (e.g. enclaves) of their prior involvement with mafic magma.

The Hidaka Metamorphic Belt (HMB) in Hokkaido, northern Japan, consists of tilted metamorphic layers of an island-arc type crust from lower (granulite facies) to upper (very low-grade metasedimentary) horizons. Abundant granitic rocks, mainly S-type tonalites of crustal origin, intrude various metamorphic layers and are classified into four depth types, namely upper, middle, lower and basal. The basal orthopyroxene-garnet (S-type) tonalities were intruded into granulite facies country rocks. Textural and compositional evidence from minerals in the basal tonalite indicates that the crystallisation sequence is Grt-Pl-Opx-Bt-Qtz-Crd-Kfs, and that crystallisation took place at about 600 MPa and 900°C-700°C.

Some crystallisation experiments were carried out in an internally heated pressure vessel, using the basal tonalite, under the conditions of 300 and 600 MPa, 700-900°C, and with 0-20 wt% H2O, respectively. The results show that the primary S-type tonalite magma was at a temperature above 900°C and contained 3-4 wt% H2O at the beginning of crystallisation. In order to study the influence of normative orthoclase content on orthopyroxene crystallisation, some starting materials also included 15, 20 and 25% normative orthoclase, by adding KAlSi3O8 gel to the rock powder. Normative orthoclase content has an influence on the subliquidus crystallisation limit of orthopyroxene.

The changes in P-T conditions and chemical composition of the magma during ascent would generate the sequence from the basal to upper S-type granite. Opx-free S-type granitic magma can be generated from lower crustal Grt-Opx S-type granitic magma, by differentiation with falling magmatic temperature.

When basaltic magma is emplaced into continental crust, melting and generation of granitic magma can occur. We present experimental and theoretical investigations of the fluid dynamical and heat transfer processes at the roof and floor of a basaltic sill in which the wall rocks melt. At the floor, relatively low density crustal melt rises and mixes into the overlying magma, which would form hybrid andesitic magma. Below the roof the low-density melt forms a stable layer with negligible mixing between it and the underlying hotter, denser magma. Our calculations applied to basaltic sills in hot crust predict that sills from 10-1500 m thick require only 2-200 years to solidify, during which time large volumes of overlying layers of convecting silicic magma are formed. These time scales are very short compared with the lifetimes of large silicic magma systems of around 106 years, and also with the time scale of 107 years for thermal relaxation of the continental crust. An important feature of the process is that crystallisation and melting occur simultaneously, though in different spots of the source region. The granitic magmas formed are thus a mixture of igneous phenocrysts and lesser amounts of restite crystals. Several features of either plutonic or volcanic silicic systems can be explained without requiring large, high-level, long-lived magma chambers.