The effects of pH and ionic strength on the rheological behavior of aqueous suspensions of both crude and purified Wyoming bentonite and natural interstratified illite-smectite from Tunisia were investigated. Flow tests were performed on the four clay suspensions at a 10% clay concentration at different pH values. They showed that the rheological properties were highly sensitive to pH and the nature of the clay. The evolution of the yield stress as a function of pH is characterized by the presence of maxima and minima attributed to changes in the mode of association of the particles. The effect of pH on the behavior of clay suspended in NaCl solutions was also studied. The results show that the presence of NaCl has very little effect on the pH and yield stress values of the four materials.

It is known that polymers used in laser sintering (LS) change their intrinsic properties due to processing conditions that are close to the crystalline melting temperature. This paper evaluates the aging behavior of a thermoplastic polyurethane powder, comparing with to a commercially available LS elastomeric material (Duraform®Flex, 3D Systems). To represent a realistic production environment, the materials were aged during 14 processing cycles in the LS process without refreshing with virgin material. Following each aging cycle, both the powder and the sintered parts were examined for chemical and physical aging effects. The results showed that the materials observed could be used without refreshing throughout the 14 aging stages, however, changes in the processing behavior as well as in the parts' mechanical properties were evident. These changes were due to the differing aging states of the LS-powder showing an increase in the particle size affecting the bulk materials packing density. Modifications in the rheological properties can be seen in a decrease of molecular weight likely to reduce the mechanical strength of tensile specimens.