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Tetragonal low-temperature phase of MgCr2O4
H. Ehrenberg, M. Knapp, C. Baehtz, S. Klemme
Journal:

Powder Diffraction / Volume 17 / Issue 3 / September 2002

Published online by Cambridge University Press:

05 March 2012, pp. 230-233
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Magnesiumchromite, MgCr2O4, undergoes a structural transition from a cubic spinel structure [space group Fd3m, a=8.32768(4) Å at 16 K] into a tetragonal distorted structure [space group I41/amd, a=5.89199(5) Å, c=8.31677(8) Å at 10 K], isotypic with Hausmannite, Mn3O4. This phase transition is translationengleich and takes place very close or at the antiferromagnetic ordering temperature.

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Tetragonal low-temperature phase of MgCr2O4