We introduce the notion of Killing normal Jacobi operator for real hypersurfaces in the complex quadric Qm = SOm+2/SOmSO2. The Killing normal Jacobi operator implies that the unit normal vector field N becomes 𝔄-principal or 𝔄-isotropic. Then according to each case, we give a complete classification of real hypersurfaces in Qm = SOm+2/SOmSO2 with Killing normal Jacobi operator.