This paper focuses on the clay mineralogy (using XRD, SEM and TEM methods) of the lacustrine “Calizas de Torrente de Cinca” unit that represents the Oligocene-Miocene transition in the central part of the Ebro Basin (NE Spain). Phyllosilicates are mainly detrital although Mgsmectites could have been generated in the lake.Although a temperate, relatively humid climate dominated the source area during the Oligocene-Miocene transition (Chattian-Aquitanian), as deduced by detrital phyllosilicates assemblage, mineralogical vertical trends along with sedimentological studies indicate some changes.Relatively warmer and more humid conditions during the late Chattian, that favoured increasing chemical weathering, were replaced during the early Aquitanian by drier conditions coinciding with the Mi-1 glaciation effects; this change is coeval with a transition from deeper to shallower lacustrine facies.Phyllosilicate association analysis has also permitted an improvement in the palaeogeographical sketch and infers that the Pyrenees are the main source area for the lacustrine system.

Variations in clay mineral assemblages, changes in Kübler index (KI), and the chemical composition of chlorites are used to identify source areas in the lacustrine materials in the Lower Cretaceous Leza Limestone Formation of the Cameros Basin, northern Spain. This formation has fairly homogeneous lithological characteristics and facies associations which do not allow for identification and characterization of local source areas. The Arnedillo lithosome of the Leza Limestone Formation contains a clay mineral association (Mg-chlorite, illite and smectite) indicative of its provenance. Chlorite composition and illite KI values indicate that these minerals were formed at temperatures higher than those reached by the Leza Formation which indicates its detrital origin. The similarity in the Mg-chlorite composition between the Arnedillo lithosome and the Keuper sediments of the area indicates that these materials acted as a local source area. This implies that Triassic sediments were exposed, at least locally, at the time of deposition of the Leza Formation. The presence of smectite in the Leza Formation is related to a retrograde diagenesis event that altered the Mg-chlorites in some samples.

Lake Lisan, the late Pleistocene precursor of the Dead Sea, existed from ∼70,000 to 15,000 yr B.P. It evolved through frequent water-level fluctuations, which reflected the regional hydrological and climatic conditions. We determined the water level of the lake for the time interval ∼55,000–15,000 cal yr B.P. by mapping offshore, nearshore, and fan-delta sediments; by application of sequence stratigraphy methods; and by dating with radiocarbon and U-series methods. During the studied time interval the lake-level fluctuated between ∼340 and 160 m below mean sea level (msl). Between 55,000 and 30,000 cal yr B.P. the lake evolved through short-term fluctuations around 280–290 m below msl, punctuated (at 48,000–43,000 cal yr B.P.) by a drop event to at least 340 m below msl. At ∼27,000 cal yr B.P. the lake began to rise sharply, reaching its maximum elevation of about 164 m below msl between 26,000 and 23,000 cal yr B.P., then it began dropping and reached 300 m below msl at ∼15,000 cal yr B.P. During the Holocene the lake, corresponding to the present Dead Sea, stabilized at ca. 400 m below msl with minor fluctuations. The hypsometric curve of the basin indicates that large changes in lake area are expected at above 403 and 385 m below msl. At these elevations the lake level is buffered. Lake Lisan was always higher than 380 m below msl, indicating a significantly large water contribution to the basin. The long and repetitious periods of stabilization at 280–290 m below msl during Lake Lisan time indicate hydrological control combined with the existence of a physical sill at this elevation. Crossing this sill could not have been achieved without a dramatic increase in the total water input to the lake, as occurred during the fast and intense lake rise from ∼280 to 160 m below msl at ∼27,000 cal yr B.P.