The occurrence is reported of a saline spring water from Weardale, which compositionally closely resembles other saline waters derived from the Carnmenellis granite, southwest England. The total dissolved solutes achieve approximately 38 000 mg/L, and alkali geothermometers suggest equilibration temperatures of approximately 150°C, equivalent to a depth of 4 km. Using Na, K and Li it is possible to compare the composition of the spring water with those of other spring waters derived from Carboniferous sequences adjacent to the North Pennine Orefield and with published data for fluid inclusions from North Pennine fluorite. These compositional parameters suggest that the ancient mineralizing fluids resemble modern Carboniferous sediment-derived waters and contain a relatively minor component of granite-derived water. Data for Br and Cl indicate that a significant component of the present day Weardale spring waters was probably ultimately derived from organic-rich sedimentary sequences while data for K, Na and Li indicate the importance of a component derived from a permeable granite aquifer. The Weardale springwaters continue to have ‘mineralizing’ potential, in view of the possibility that they may have precipitated quartz or chalcedony during their ascent.

The ore-element associations of granite-related ore deposits in the eastern Australian Palaeozoic fold belts can be related to the inferred relative oxidation state, halogen content and degree of fractional crystallisation within the associated granite suites. Sn mineralisation is associated with both S- and I-type granites that are reduced and have undergone fractional crystallisation. Cu and Au are associated with magnetite- and/or sphene-bearing, oxidised, intermediate I-type suites. Mo is associated with similar granites that are more fractionated and oxidised. W is associated with a variety of granite types and shows little dependence on inferred magma redox state. The observed ore deposit-granite type distribution in eastern Australia, and the behaviour of ore elements during fractionation, is consistent with models of ore element sequestering by sulphides and Fe-Ti phases (e.g. pyrrhotite, ilmenite, sphene, magnetite) whose stability is nominally fO2-dependent. Fractional crystallisation acts to amplify this process through the progressive removal of compatible elements and the concentration of incompatible elements into decreasing melt volumes. The halogen content is also important. S-type granites are poorer in Cl than I-types. Cl decreases and F increases in both S- and I-type granites with fractional crystallisation. Low Cl contents combined with low magma fO2 in themselves seem to provide an adequate explanation for the rarity of Mo, Cu, Pb and Zn type mineralisation with S-type granites. Although such properties of granite suites seem adequately to predict the associated ore-element assemblage to be expected in associated mineral deposits, additional factors determine whether or not there is associated economic mineralisation.