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2 results

  • 8 - Self-Assembly and Phase Behaviors

  • Murugappan Muthukumar, University of Massachusetts, Amherst
  • Book:
    Physics of Charged Macromolecules
    Published online:
    16 February 2023
    Print publication:
    23 February 2023, pp 279-338

  • Summary

    Using the Flory-Huggins theory for uncharged polymer solutions, key concepts of the critical point, coexistence curve, and spinodal curve are presented. These concepts are then generalized to charged systems by explicitly considering restricted primitive model for electrolytes and new developments for polyelectrolyte solutions that include the liquid-liquid phase separation invoked in the formation of membrane-less organelles. Fibrillization in amyloids and collagen is discusses with a focus of electrostatic effects.

Physics of Charged Macromolecules
  • Synthetic and Biological Systems
  • Murugappan Muthukumar
  • Published online:
    16 February 2023
    Print publication:
    23 February 2023
  • A concise introduction to the physics of charged macromolecules, from the basics of electrostatics to cutting-edge modern research developments. This accessible book provides a clear and intuitive view of concepts and theory, and features appendices detailing mathematical methodology. Supported by results from real-world experiments and simulations, this book equips the reader with a vital foundation for performing experimental research. Topics include living matter and synthetic materials including polyelectrolytes, polyzwitterions, polyampholytes, proteins, intrinsically disordered proteins, and DNA/RNA. Serving as a gateway to the growing field of charged macromolecules and their applications, this concept-driven book is a perfect guide for students beginning their studies in charged macromolecules, providing new opportunities for research and discovery.