Modern experimental methods and instruments for X-ray spectral
investigation of hot dense plasma provide complex information on
environmental conditions in extreme states of matter. The basic
spectroscopic conceptions for K-shell plasma diagnosis are
outlined, the main characteristics of toroidally bent crystal
spectrometers and vertical-dispersion instruments are briefly reviewed.
Selected applications (monitoring and optimization of the emission from
the femtosecond-laser-produced plasmas, characterization of colliding
laser-exploded foils, spectral line merging, and continuum lowering in
constrained-flow plasmas) demonstrate the usefulness of advanced
spectroscopic methods for plasma diagnostics and fundamental
research.