We study a skew Ornstein–Uhlenbeck process with zero being a sticky reflecting boundary, which is defined as the weak solution to a stochastic differential equation (SDE) system involving local time. The main results obtained include: (i) the existence and uniqueness of solutions to the SDE system, (ii) the scale function and speed measure, and (iii) the distributional properties regarding the transition density and the first hitting times. On the application side, we apply the process to interest rate modeling and obtain the explicit pricing formula for zero-coupon bonds. Numerical examples illustrate the impacts on bond yields of skewness and stickiness parameters.