This review examines observations of magnetic fields in molecular clouds, that is, at spatial scales ranging from tens to tenths of parsecs and densities up to hundreds of particles per cubic centimetre. I will briefly summarize the techniques for observing and mapping magnetic fields in molecular clouds. I will review important examples of observational results obtained using each technique and their implications for our understanding of the role of the magnetic field in molecular cloud formation and evolution. Finally, I will briefly discuss the prospects for advances in our observational capabilities with telescopes and instruments now beginning operation or under construction.

Understanding how, when and where complex organic and potentially prebiotic molecules are formed is a fundamental goal of astrochemistry. Since its beginning the Atacama Large Millimeter/submillimeter Array (ALMA) has demonstrated its capabilities for studies of the chemistry of solar-type stars. Its high sensitivity and fine spectral and angular resolution makes it possible to study the chemistry of young stars on Solar System scales. We here present an unbiased spectral survey, Protostellar Interferometric Line Survey (PILS), of the astrochemical template source and Class 0 protostellar binary IRAS 16293-2422 using ALMA. The high quality ALMA data have allowed us to detect a wealth of species previously undetected toward solar-type protostars as well as the interstellar medium in general. Also, the data show the presence of numerous rare isotopologues of complex organic molecules and other species: the exact measurements of the abundances of the complex organic molecules and their isotopologues shed new light onto the formation of these species and provide a chemical link between the embedded protostellar stages and the early Solar System.

We report serendipitous detections of line emission with ALMA in band 3, 6, and 7 in the central parsec of the Galactic center at an up to now highest resolution (<0.7″). Among the highlights are the very first and highly resolved images of sub-mm molecular emission of CS, H13CO+, HC3N, SiO, SO, C2H, and CH3OH in the immediate vicinity (~1″ in projection) of Sgr A* and in the circumnuclear disk (CND). The central association (CA) of molecular clouds shows three times higher CS/X (X: any other observed molecule) luminosity ratios than the CND suggesting a combination of higher excitation - by a temperature gradient and/or IR-pumping - and abundance enhancement due to UV- and/or X-ray emission. We conclude that the CA is closer to the center than the CND is and could be an infalling clump consisting of denser cloud cores embedded in diffuse gas. Moreover, we identified further regions in and outside the CND that are ideally suited for future studies in the scope of hot/cold core and extreme PDR/XDR chemistry and consequent star formation in the central few parsecs.

The molecular clouds in the Central Molecular Zone of our Galaxy (CMZ; inner ~200 pc) show systematically higher gas than dust temperatures (>50 K vs <30 K) in recent H2CO line and dust continuum surveys. This discrepancy is puzzling since gas and dust temperatures should become equal over short times at the high densities observed in these clouds. In deep H2CO(3–2) and (4–3) observations of seven clouds in the CMZ, we detected not only large temperature differences between the clouds but also large gradients within the clouds. Comparing the temperatures and the main H2CO lines at 218 and 291 GHz, we found a positive correlation between those two parameters, indicating that turbulence plays an important role in the heating of the gas. As a follow-up, we mapped the temperature tracers CH3CCH and CH3CN in these seven clouds to derive multiple temperature estimates and test the accuracy of high gas temperatures.

The Herschel Space Observatory carried out observations at far-infrared wavelengths, which significantly increased our knowledge of the interstellar medium and the star-formation process in the Milky Way and external galaxies, as well as our understanding of astrochemistry.

Absorption features, known, e.g., from observations at millimeter wavelengths, are more commonly observed in the far-infrared, in particular toward strong dust continuum sources. The lowest energy transitions are not only observed at LSR-velocities related to the source, but often also at velocities associated with diffuse molecular clouds along the line of sight toward the background source.

Unbiased spectral line surveys of the massive and very luminous Galactic Center sources Sagittarius B2(M) and (N) were carried out across the entire frequency range of the high-resolution Heterodyne Instrument for Far-Infrared Astronomy (HIFI). An absorption feature was detected toward both sources at about 617.531 GHz, corresponding to 20.599 cm−1, 485.47 μm, or 2.5539 meV. This feature is unique in its appearance at all velocity components associated with diffuse foreground molecular clouds, together with its conspicuous absence at velocities related to the sources themselves. The carriers of at least a substantial part of the DIBs are thought to reside in the diffuse interstellar medium. Therefore, we consider this absorption feature to be a far-infrared DIB analog.

Subsequent dedicated observations confirmed that the line is present only in the foreground clouds on the line of sight toward other massive star-forming regions in the Galactic disk. There is indication that the feature has substructure, possibly of fine or hyperfine nature. Attempts to assign the feature to atomic or molecular species have been unsuccessful so far.