Methyl bromide has been widely used for weed control in polyethylene-mulched tomato production. With the phaseout of methyl bromide in the United States, an effective alternative is needed. Field experiments were conducted in 2007 and 2009 to determine if allyl isothiocyanate (ITC) would provide substantive weed control in tomato along with crop tolerance under low-density polyethylene (LDPE) and virtually impermeable film (VIF) mulch. Treatment factors included two mulch types (LDPE and VIF) and six rates of allyl ITC (0, 15, 75, 150, 750, 1,500 kg ha−1). A standard treatment of methyl bromide : chloropicrin (67 : 33%) at 390 kg ha−1 under LDPE mulch was also established. Allyl ITC was broadcast applied and incorporated in soil before forming raised beds and laying plastic mulch. Tomatoes were transplanted 3 wk after applying allyl ITC or methyl bromide treatments. Tomato injury was ≤ 8% in all treatments at 2 wk after transplanting (WATP). Allyl ITC at 913 (± 191) kg ha−1 was required to control yellow nutsedge, Palmer amaranth, and large crabgrass equivalent to methyl bromide at 6 WATP and maintain marketable tomato yield equivalent to methyl bromide treatment. VIF mulch was not effective in increasing weed control or improving the marketable yield of tomato over LDPE mulch. This research demonstrates that allyl ITC under an LDPE mulch can have a practical application for weed control in polyethylene-mulched tomato in the absence of methyl bromide.

Brassicaceae cover crops are gaining attention as potential biofumigants for soil pest suppression because of their ability to release biologically active isothiocyanates (ITCs) and other compounds from hydrolysis of glucosinolates (GSLs). However, biofumigation potential of a Brassicaceae is related to its GSL and ITC profile and GSL to ITC conversion efficiency. Field and laboratory experiments were conducted to evaluate the biofumigation potential of seven Brassicaceae cover crops for weed control in plasticulture tomato and bell pepper. GSL concentration and composition varied among cover crops and between roots and shoots of each cover crop. Similar GSLs were produced in both years by roots or shoots of each cover crop, but GSL concentrations were variable between years. Total GSLs contributed to the soil by incorporation of Brassicaceae cover crop tissues were estimated between 47 to 452 nmol g−1 soil. Highest ITC concentration was detected in soil at 3 h after cover crop incorporation, and concentration decreased at later timings. GSL to ITC conversion efficiency ranged from 1 to 39%, with variation among cover crops and between years. No injury was observed in tomato and bell pepper transplanted 1 wk after cover crop incorporation, indicating the tolerance of tomato and pepper to ITCs released by the cover crops. Early-season yellow nutsedge control from Brassicaceae cover crops was ≤ 53% at 2 wk after transplanting and declined to ≤ 18% later in the season. This research demonstrates that Brassicaceae cover crops have marginal potential for early-season weed control and cannot be used as a weed control practice in commercial tomato and bell pepper production.