The predominantly carbonate nature of the mountains near the coast of Málaga and Marbella (Costa del Sol, southern Spain) and the presence of springs have favored the formation of travertine buildups during the Quaternary. The geomorphic characteristics of the slopes and the location of the springs have determined the development of three types of travertine growths: (1) spring travertines, located preferentially on the south mountainside, where the slope is steepest; (2) pool-dam-cascade travertines, which form along the north and east edges, far from the carbonate relief and with a gentler slope; and (3) river-valley travertines, formed in the courses of the springs of any sector. Field observations combined with new amino acid racemization (AAR) dating of Helicidae gastropods show that most of the travertine formations are polyphasic and that their development was interrupted by stages of erosion and incision. Five stages of travertine development are evident, most of which are related to warm, moist episodes corresponding to marine oxygen isotope stages (MIS) 7, 5, 3, and 1, although local travertine growth also occurred during MIS 6 and during the transition from MIS 3 to 2.

Ultramafic rocks, such as the Semail Ophiolite in the Sultanate of Oman, are considered to be a potential storage site for CO2. This type of rock is rich in divalent cations that can react with dissolved CO2 and form carbonate minerals, which remain stable over geological periods of time. Dissolution of the ophiolite mobilizes heavy metals, which can threaten the safety of surface and groundwater supplies but secondary phases, such as iron oxides, clays and carbonate minerals, can take up significant quantities of trace elements both in their structure and adsorbed on their surfaces.

Hyperalkaline spring waters issuing from the Semail Ophiolites can have pH as high as 12. This water absorbs CO2 from air, forming carbonate mineral precipitates either as thin crusts on the surface of placid water pools or bottom precipitates in turbulent waters. We investigated the composition of the spring water and the precipitates to determine the extent of trace element uptake. We collected water and travertine samples from two alkaline springs of the Semail Ophiolite. Twenty seven elements were detected in the spring waters. The bulk of the precipitate was CaCO3 in aragonite, as needles, and rhombohedral calcite crystals. Traces of dypingite (Mg5(CO3)4(OH)2·5H2O) and antigorite ((Mg,Fe)3Si2O5(OH)4) were also detected. The bulk precipitate contained rare earth elements and toxic metals, such as As, Ba, Cd, Sr and Pb, which indicated scavenging by the carbonate minerals. Boron and mercury were detected in the spring water but not in the carbonate phases. The results provide confidence that many of the toxic metals released by ophiolite dissolution in an engineered CO2 injection project would be taken up by secondary phases, minimizing risk to water quality.

Screes on high serpentinite sea cliffs in Shetland have been internally cemented by deposits of brucite, hydromagnesite and aragonite since the last glaciation. These minerals have been deposited from solutions originating as rain (often contaminated with salt spray), which fell on the serpentinite screes and dissolved Mg and minor amounts of Ca from the more finely divided and powdery scree components. As the solutions filtered down through the screes they deposited cements in the form of spherulitic layers of brucite and hydromagnesite with minor amounts of aragonite. At sea level the Mg-rich solutions mingled with sea water impregnating the scree and there cementation within the scree took place by the crystallization of plush-type layers of aragonite on the serpentinite fragments.

The Deseado Massif hosts numerous Late Jurassic (150 Ma) fossil geothermal systems related to an extensive volcanic event developed in a diffuse extensional back-arc setting. Detailed mapping, petrography and mineralogical observations of El Macanudo outcrops verify that it represents a hot-spring-related travertine partially replaced by silica and delineated by six sedimentary facies. These are large concentric cones (F1), laminated vertical columnar structures (F2), porous layers (F3), shrubby and irregular lamination (F4), low-amplitude wavy bedding (F5) and mounds and breccias (F6). The Macanudo Norte Outcrop rocks constitute a silica-replaced travertine sequence, with development of large conical stromatolites in a deep pool or geothermally influenced shallow lacustrine environment, surrounded by a subaerial travertine apron terrace; whereas, the Macanudo Sur Outcrop is a subaerial travertine mound sequence. Structurally controlled vent areas occur in both northern (F1) and southern (F6) outcrops, mainly located along regional NNE- and ENE-trending faults. The other sedimentary units display a concentric distribution of travertine facies with respect to the interpreted vent areas. The El Macanudo palaeo-hot spring deposit is situated in an eroded Jurassic volcanic centre, and records a complex evolutionary-fluid history. The sediments archived three different Jurassic events, when large and long-lasting hydrothermal systems were active across the region. This relative temporal sequence was formed by: (1) travertine precipitation; (2) development of a silica cap, where early silicification was responsible for exceptional preservation of some stromatolitic fabrics; and (3) acid alteration, recorded by dissolution textures and clay formation, and caused by a palaeo-phreatic water-level drop.

Late-Quaternary travertine at two sites near Stuttgart formed entirely during interglacial periods. The travertine contains structures from growth induced by bacteria, and such structures have been dated by 230Th/U mass spectrometry. The resulting ages from both sites imply growth episodes of short duration, with growth rates up to 5 mm yr−1, at 99,800 ± 1300 yr B.P. (2σ n = 8) and 105,900 ± 1300 yr B.P. (2σ n = 7). These episodes were likely part of marine isotope stage (MIS) 5.3. Deposition of silt interrupted travertine growth at one of the sites ∼105,000 yr B.P. Likely correlatives of this silt are the St. Germain I-B stade recorded in the Grand Pile peat bog and a cold episode ∼1000 yr long recorded by δ18O values in the GRIP ice core. Travertine also formed during stage 5.5 (∼115,000 yr) and during the early Holocene. We found no evidence for travertine accumulation in stages 2, 3, 4, and 5.1. At both sites, the Sr/U ratio and the initial 234U/238U activity ratio resemble those of modern spring water. However, the sites differ in the chemical composition of spring water and in stratigraphic sequence of travertine accumulation.

Fossil travertine and subaqueous speleothems in presently dry caves suggest periods of enhanced ground-water recharge during the Quaternary Period in semiarid northeastern Brazil. Travertine deposits and water-table speleothems were dated by the 230Th/234U technique, yielding new evidence for the timing of past periods of increased rainfall. The travertine was deposited in two distinct phases, extensive in situ deposits during marine isotope stage 2 and fragmentary, indurated deposits dating to ca. 400,000 yr B.P. (possibly marine isotope stage 10 or 12). Dating of water-table speleothems showed that the regional water table was 13±1 m above the present level at the last glacial maximum. A second site yielded ages suggesting a still higher water table during marine isotope stage 6. These new data demonstrate that northeastern Brazil did not follow the general pattern of a dry last glacial maximum, as suggested by other continental records in Amazonia and southeastern Brazil, and as depicted in recent General Circulation Model (GCM) simulations. Our results thus indicate that significant variability in regional rainfall patterns occurred in the area during glaciations and caution against overgeneralization of paleoclimate patterns.

Holocene and modern travertine formed in spring-fed Havasu Creek of the Grand Canyon, Arizona, was studied to determine the factors governing its oxygen-isotope composition. Analysis of substrate-grown travertine indicates that calculated calcite-formation temperatures compare favorably with measured water temperatures, and include silt-rich laminae deposited by monsoon-driven floods. Ancient spring-pool travertine is dated by U-series at 7380 ± 110 yr and consists of 14 travertine-silt couplets of probable annual deposition. One hundred eighty high-resolution δ18O analyses of this mid-Holocene sample average −11.0‰ PDB. The average value for modern travertine is ∼0.5‰ lower, perhaps because mid-Holocene temperature was higher or there was proportionally greater summer recharge. δ18O cyclicity in the mid-Holocene travertine has average amplitude of 1.9 ± 0.5‰ PDB, slightly less than the inferred modern-day annual temperature range of Havasu Creek. The annual temperature range might have been reduced during the 14-yr interval compared to present, although other non-temperature factors could account for the muted annual variation. Silt-rich laminae within isotopically lower calcite in the modern and mid-Holocene travertine verifies the seasonal resolution of both samples, and suggests that similar temperature-precipitation conditions, as well as monsoon-generated summer floods, prevailed in the mid-Holocene as they do throughout the Grand Canyon region today.

Salt weathering is a major erosive process affecting porous materials in buildings. There have been attempts to relate erosive mass loss to physical characteristics of materials, but in the case of natural stone it is necessary to consider the effect of petrographic features that are a source of heterogeneity. In this paper, we use scanning electron microscopy before and after salt weathering tests in cubic specimens of three limestone types (two grainstones and a travertine) in an attempt to built conceptual models that relate petrographic features and salt weathering susceptibility (represented by mass loss). In the grainstones, the most relevant feature in controlling salt weathering processes is the interface between micrite aggregates and sparry cement that constitute weakness surfaces and barriers to fluid migration. Given the small size of the heterogeneities in relation to the test sample dimension and their spatial distribution, the macroscopic erosive patterns are globally homogeneously distributed, affecting edges and corners. In the travertine specimens, there are macroheterogeneities related to the presence of detritic-rich portions that cause heterogeneous erosive patterns in the specimens. Petrological modeling helps to understand results of salt weathering tests, supporting field studies for natural stone selection.

A comprehensive palaeoenvironmental reconstruction of the last 219 ka has been carried out by determining the isotopic signatures (δ18O and δ13C) in 766 samples of a thermogene travertine formation in the Guadix-Baza Tertiary basin (Granada, SE Spain). This travertine formation was dated from ≈ 220 to ≈ 5 ka by means of the alpha-spectrometry technique. Initially, the study of the δ18O values of the travertine formation was carried out because they are excellent indicators of the overall palaeoclimatic condition of a particular site. Likewise, the evolution of δ13C values, which can be directly related to the biomass development of the site, has also been studied. Finally, an integrated study of both isotopic records has been performed, identifying a total of 12 climatic periods based on their palaeoclimatic and palaeoenvironmental conditions. These periods are grouped into four climatic scenarios: scenario A, characterized by warm and dry periods; scenario B, characterized by cold and humid periods; scenario C, constituted by warm and humid periods; and scenario D, which is characterized by cold and dry periods. Palaeoclimatic scenarios A and B mainly characterized the palaeoclimatic evolution of the site, while in northern Europe the palaeoclimatic evolution is mainly characterized by scenarios C and D. Therefore, it is suggested that the palaeoenvironmental evolution at lower latitudes on the Iberian Peninsula is the opposite of that identified in northern Europe. However, the main climatic events identified at higher latitudes are also reflected in the studied area.

Deposition of calcium carbonate from groundwater was examined on a moss, Didymodon tophaceus, from a Niagara Escarpment waterfall. A spectrophotometer on a polarizing microscope was used for interferometry. A second-order blue interference with an interference minimum around 620 nm was found when moss cell spaces were fully calcified. Filled cell spaces were often surrounded by empty cell spaces. Complete calcification of whole leaflets resulted in progressively higher orders of interference colors and a positive shift in interference minima. Calcified leaflets finally became cemented together, but each retained a weak extinction when rotated. Small calcareous spherulites (mean diameter 15.7 ± 2.1 μm) were found between leaflets. Spherulites exhibited first-order white interference with a Maltese cross that rotated when the polarizer and analyzer were rotated in tandem. A Nikitin-Berek compensator was tilted at 5.5° to give an interference minimum at 600 nm in the optical axis. Quadrants of spherulites with radii more or less in line with the tilting axis of the compensator had lower (P < 0.001) interference minima (535 ± 27 nm) than quadrants with radii more or less perpendicular to the compensator (659 ± 15 nm), thus indicating a radial internal structure. Spherulites were tentatively identified as vaterite.

Plant litter breakdown, an important process for energy and matter flows in freshwater ecosystems, has been extensively studied except in the karst (and calcite depositing) habitats. The aim of this paper was to answer three questions regarding the breakdown of leaf litter in calcite depositing environment: (i) Does leaf decomposition hinder calcite deposition and vice versa?; (ii) What role do other environmental factors play?; and (iii) How long does leaf litter persist in these habitats? Leaves of beech (Fagus sylvatica) and butterbur (Petasites hybridus) were exposed for 8 weeks in 8 microhabitats: 2 calcite deposition rates × 2 flow velocities × 2 seasons. A linear model was better at predicting leaf litter persistence but only for the period after the extreme loss of leaf mass occurring during the initial leaching of highly hydrosoluble compounds in the first week (11.6% of beech and 54.2% of butterbur regardless of the studied environmental factors). Higher flow velocity and calcite deposition rates stimulated the breakdown of both leaf species. During summer, breakdown was accelerated for butterbur leaves only. Since breakdown rates of both litter types were faster at high calcite depositing sites, it can be concluded that the breakdown process is not hindered by calcite deposition in general. The amount of deposited calcite per gram of leaf litter increased linearly over time (after the first week of exposure) on both leaf species. More calcite was deposited on the fast-decomposing butterbur leaves than on beech leaves.

A newly investigated travertine deposit in southern Tibet provides a window into Holocene hydrological, geomorphic and climatic processes near the boundary of the Tibetan Plateau and High Himalaya. Travertine, deposited as a result of the degassing of CO2-rich groundwater as it emerges on the Earth's surface, is in many cases formed along the trace of major crustal-scale faults in primarily extensional tectonic regimes. A travertine platform measuring roughly 1 km by 0.5 km exists near the town of Nyalam in southern Tibet along a major Himalayan down-to-the-N normal fault, the South Tibetan Fault System. A wide variety of travertine depositional textures and features are recorded in the platform on a series of terraces. Active travertine deposition was observed from spring mounds and seeps along the base of the platform at the modern river level. Palaeotemperatures of spring water, calculated from δ18O of the travertine, range from 9 to 25 °C, which closely matches the temperatures recorded from modern springs in the area. A complex geomorphological landscape records interaction between growing alluvial fans, travertine accumulation, and a rapidly down-cutting river with associated fluvial terraces. River incision was contemporaneous with travertine deposition, as indicated by cemented fluvial river gravel layers interbedded with travertine. High 87Sr/86Sr ratios in the travertine (mean of 0.7168) indicate subsurface fluid interaction with radiogenic crystalline rocks of the underlying Greater Himalaya. Uranium-series ages of the travertine platform range from 5400 a (±950 a) to 11600 a (±1000 a), and indicate a younging progression from higher terraces near the valley wall to lower terraces at present-day river level. Travertine that overlies a river gravel terrace 18 m above river level formed at 11600 a. This date yields a local incision rate of 1.6 mm a−1, consistent with estimated fluvial incision rates in the High Himalaya. The range of our U-series ages coincides with an interval of higher precipitation associated with greater intensity of the Indian monsoon, which led to elevated spring discharge and carbonate precipitation in this part of the High Himalayas.

The 150-m-thick Kuetsjärvi Sedimentary Formation (KSF) from the Pechenga Greenstone Belt, NW Russia, is one of the key formations in the study of a positive δ13Ccarb excursion occurring globally in the Palaeoproterozoic. The KSF formed in an intracratonic rift setting and is sandwiched between two, 2-km-thick subaerially erupted volcanic units. The KSF was previously interpreted as shallow marine, but new data reported here indicate that it is a non-marine unit deposited on a deeply subaerially weathered surface mantling the underlying volcanic rocks. The lowermost part of the KSF represents an alluvial–fluvial plain, followed by a laterally and vertically variable succession of variegated to mottled fine-grained siliciclastic rocks and ‘red beds‘, dolostones containing stromatolite sheets, hydrothermal travertine deposits and abundant desiccation features (e.g.tepees, surfical silicified crusts and dissolution cavities), including probable pseudomorphed evaporites. Measured S and Corg concentrations for the carbonate and siliciclastic rocks are low. Combined, these features indicate that the carbonate rocks of the KSF accumulated in a shallow lacustrine setting. Major types of carbonate facies were formed by: (1) biologically-induced precipitation; (2) evaporitic removal of CO2 in a closed lake environment; and (3) chemical precipitation from thermal springs. Apparently, none of these carbonate facies was in full isotopic equilibrium with atmospheric CO2. This interpretation shows the importance of taking into account the interplay between global and local depositional factors when interpreting the isotopic signature of the KSF dolostones and its implication for the Palaeoproterozoic carbon isotope excursion