The appreciation or reception of materials can create a positive or a negative reaction in the user and an individual’s understanding of materials comes from their own experiential knowledge, influence of others, and cultural perception. The condemnation of the overuse of plastics materials and their impact on the environment when they become waste has, understandably, meant that today the cultural perception of plastics is largely that they are cheap, rubbish, throw away—all bad news. This position of negativity has been reached because we currently see the mismanagement of plastics waste as it blows about in the wind; we see it as rubbish in our streets, and as detritus in the oceans. However, our relationships with the material family, over the time they have existed, have had a varied and turbulent history with different perspectives generated by different people at different times. This article will briefly explore ‘a’, rather than ‘the’, history of the use of plastics with the aim of putting the current societal relationship with them into context.