The only published δ13C data from the Ordovician of China are from the Lower and Upper Ordovician, and only the latter records include a significant excursion, namely the Hirnantian excursion (HICE). Our recent chemostratigraphic work on the Upper Ordovician (Sandbian–Katian) Pagoda and Yanwashan formations at several localities on the Yangtze Platform and Chiangnan (Jiangnan) slope belt has resulted in the recognition of a positive δ13C excursion that has values of ~+1.5‰ above baseline values. This excursion starts a few metres above a stratigraphic interval with B. alobatus Subzone conodonts as well as graptolites of the N. gracilis Zone. The distinctive conodonts Amorphognathus aff. Am. ventilatus and Hamarodus europaeus first occur at, or very near, the excursion interval. Because these conodonts appear in the stratigraphic interval of the Guttenberg δ13C excursion (GICE) in Estonia, we identify the Chinese excursion as the GICE. This is the first record of the GICE in the entire Asian continent. It confirms that GICE is a global excursion and provides an illustration of how δ13C chemostratigraphy, combined with new biostratigraphic data, solves the problem of the previously controversial age of the Pagoda Formation and how this classical stratigraphic unit correlates with the Baltoscandian and North American successions.

A diverse fauna of phacopid trilobites is described from the Late Devonian (middle Frasnian to early Famennian) of the northern Canning Basin, Western Australia. One new genus and four species in two genera are described from zones 11, 13a and 13b of the middle and late Frasnian: Trimerocephaloides sinevisus gen. nov. and sp. nov., T. ? linguiformis sp. nov., Acuticryphops acuticeps (Kayser, 1889) and A. klapperi sp. nov. Late Frasnian phacopines are either blind, as shown for the first time in Trimerocephaloides sinevisus, or show trends to decreasing eye size up to the Frasnian–Famennian ‘Kellwasser’ mass extinction event. This evolutionary trend in Acuticryphops is demonstrated to have been global at this time. One new genus and six species of early Famennian phacopids are described, from the Upper triangularis, crepida and rhomboidea zones: Houseops gen. nov. with the new taxa H. canningensis sp. nov., H. beckeri sp. nov. and H. sp. A, Babinops planiventer Feist & Becker, 1997, B. minor sp. nov., Trimerocephalus tardispinosus Feist & Becker, 1997 and T. mimbi sp. nov. In contrast to European sections where exclusively blind phacopids are known in earliest Famennian sites, initial recovery following the mass extinction event in Canning peri-reefal environments is characterized by oculated forms. These trilobites must have evolved from conservative ancestors with normal eyes that had succeeded in surviving the Kellwasser biocrises in reef-related shallow water niches. Thus the origin of post-event phacopids from shallow water environments is demonstrated for the first time. Descendant lineages show increasing eye size, increased cephalic vaulting and effacement during the early Famennian.

The northern Kenya Rift is bounded on the west by uplands of Turkana which comprise horst-like blocks that include metamorphic basement rocks, locally overlain unconformably by the Cretaceous Lubur Sandstone, in turn overlain by predominantly volcanic sequences in which relatively thin sedimentary packages occur. Amphibolite facies crystalline rocks of the basement yield Early Palaeozoic K–Ar cooling ages reflecting the Pan-African Orogeny. Volcanism in Turkana was initiated through voluminous eruptions of transitional tholeiitic basalts commencing about 36 Ma ago in the Late Eocene, with some evidence for concomitant rhyolitic volcanism. Volcanism became dominantly rhyolitic in the interval from about 27 to 23 Ma ago, but remained bimodal as basaltic lavas are also known from this period. From about 19 to 15 Ma or younger, basaltic volcanism again dominated, often alkaline in nature, with thin but significant sedimentary sequences interleaved that have yielded important vertebrate faunal assemblages. Parallels exist between the volcanic history recorded in Turkana and that found in the Nabwal Hills east of Lake Turkana. In the southern Turkana region, oil exploration by seismic methods and deep drill holes has shown the existence of northerly-trending half-graben with up to 7 km of fill, and that these developed from at least Oligocene and possibly Late Eocene times. This suggests that the widespread basaltic volcanism at about 36 Ma ago (Late Eocene) heralds an earlier initiation of the Kenya Rift in northern Kenya than most workers have previously suggested.

Analyses of structures in the western part of the North Patagonian Massif (southern Argentina) suggest a polyphase evolution, accompanied by continuous intrusive activity. The first two deformations (D1, D2) and metamorphism affected the upper Palaeozoic, partly possibly older Cushamen Formation clastic succession and different intrusive rocks. A second group of intrusions, emplaced after the second deformational episode (D2), in many places contain angular xenoliths of the foliated country rocks, indicating high intrusive levels with brittle fracturing of the crust. Deformation of these magmatic rocks presumably began during (the final stage of) cooling and continued under solid-state conditions. It probably coincided with the third deformational event (D3) in the country rocks. Based on published U–Pb zircon ages of deformed granitoids, the D2-deformation and younger event along with the regional metamorphism are likely to be Permian in age. An onset of the deformational and magmatic history during Carboniferous times, however, cannot be excluded. The estimated ~W–E to NE–SW compression during the D2-deformation, also affecting the first group of intrusive rocks, can be related to subduction beneath the western Patagonia margin or an advanced stage of collisional tectonics within extra-Andean Patagonia. The younger ~N–S to NE–SW compression might have been an effect of oblique subduction in the west and/or continuing collision-related deformation. As a cause for its deviating orientation, younger block rotations during strike-slip faulting cannot be excluded. The previous D2-event presumably also had an effect on compression at the northern Patagonia margin that was interpreted as result of Patagonia's late Palaeozoic collision with the southwestern Gondwana margin. With the recently proposed Carboniferous subduction and collision south of the North Patagonian Massif, the entire scenario might suggest that Patagonia consists of two different pieces that were amalgamated with southwestern Gondwana during Late Palaeozoic times.

The incomplete Evros ophiolites in NE Greece form a NE–SW-oriented discontinuous belt in the Alpine orogen of the north Aegean. Field data, petrology and geochemistry are presented here for the intrusive section and associated mafic dykes of these ophiolites. Bodies of high-level isotropic gabbro and plagiogranite in the ophiolite suite are cross-cut by NE–SW-trending boninitic and tholeiitic–boninitic affinity dykes, respectively. The dykes fill tensile fractures or faults, which implies dyke emplacement in an extensional tectonic regime. The tholeiitic–transitional boninitic gabbro is REE- and HFS-depleted relative to N-MORB, indicating derivation from melting of a refractory mantle peridotite source. Associated boninitic dykes are slightly LREE-enriched, showing mineral and whole-rock geochemistry similar to the gabbro. The plagiogranite is a strongly REE-enriched high-silica trondhjemite, with textures and composition typical for an oceanic crust differentiate. Plagiogranite-hosted tholeiitic and transitional boninitic dykes are variably REE-enriched. Geochemical modelling indicates origin of the plagiogranite by up to 75 % fractional crystallization of basaltic magma similar to that producing the associated tholeiitic dykes. All mafic rocks have high LILE/HFSE ratios and negative Ta–Nb–Ti and Ce anomalies, typical for subduction zone-related settings. The mafic rocks show a similar trace-element character to the mafic lavas of an extrusive section in Bulgaria, suggesting they both form genetically related intrusive and extrusive suites of the Evros ophiolites. The field occurrence, the structural context, the petrology and geochemical signature of the studied magmatic assemblage provide evidence for its origin in a proto-arc (fore-arc) tectonic setting, thus tracing the early stages of the tectono-magmatic evolution of Jurassic arc-marginal basin system that has generated the supra-subduction type Evros ophiolites.

Dinoflagellate cysts and sequence stratigraphy are used to date accurately the Tunnel-Canal Dock section, which contains the most complete record of marine Pliocene deposits in the Antwerp harbour area. The Zanclean Kattendijk Formation was deposited between 5.0 and 4.4 Ma during warm-temperate conditions on a shelf influenced by open-marine waters. The overlying Lillo Formation is divided into four members. The lowest is the Luchtbal Sands Member, estimated to have been deposited between 3.71 and 3.21 Ma, under cooler conditions but with an open-water influence. The Oorderen Sands, Kruisschans Sands and Merksem Sands members of the Lillo Formation are considered a single depositional sequence, and biostratigraphically dated between 3.71 and c. 2.6 Ma, with the Oorderen Sands Member no younger than 2.72–2.74 Ma. Warm-temperate conditions had returned, but a cooling event is noted within the Oorderen Sands Member. Shoaling of the depositional environment is also evidenced, with the transgressive Oorderen Sands Member passing upwards into (near-)coastal high-stand deposits of the Kruisschans Sands and Merksem Sands members, as accommodation space decreased. Applying sequence stratigraphy to our section implies that the Kattendijk/Lillo Formation boundary corresponds to the sequence boundary (SB) Za2 (4.04 Ma), the Luchtbal/Oorderen sands boundary to SB Pia1 (3.21 Ma), and the top of the Merksem Sands to SB Pia2 (2.76 Ma). Finally, the Belgian deposits are compared with marine Pliocene deposits of eastern England.

The 1954, 1994, 1998 and 2006 block-and-ash flow deposits from Merapi volcano, Indonesia, contain andesite blocks that display localized, dark surface coatings. These coated blocks are typically found in clusters, but may also occur isolated within the block-and-ash flow deposits. The coatings form irregular patches (tens of centimetres across) on block surfaces, and are characterized by a silver, metallic appearance. The origin and composition of the coatings have not previously been determined, and no comparable deposits have been described in detail from any other volcanically active region of the world. Carbon isotope analyses of coated and uncoated bulk rock material, and of a range of charred and uncharred wood samples, suggest that the dark block coatings at Merapi volcano are organic in origin. Scanning electron microscopy and reflected light microscopy indicate that such coatings may form due to the migration and subsequent deposition of organic carbon in cavities within the andesite blocks. The most recent field evidence from the 2006 block-and-ash flow deposits at Merapi indicates that in situ charcoalification of plant material after block deposition and/or during the final stages of flow, is the major mechanism that forms localized concentrations of block coatings. Isolated coated blocks may result either from recycling of older deposits, or, more likely, from charcoalification and redistribution of plant material caught between colliding lava blocks during flow.

The newly recognized Nant Brianne turbidite system was a focus of laterally supplied coarse-grade sediment deposition that, along with the Caban–Ystrad Meurig system, punctuated late Hirnantian to early Telychian, mudstone-dominated slope apron deposition along the SE margin of the southern Welsh Basin. Geological mapping coupled with detailed biostratigraphy enable the depositional influence of sea-floor topography, an active Llyn Brianne Fault and eustatic sea-level changes to be tracked. The latter may represent ‘far field’ effects relating to the retreat and advance of contemporary Gondwanan ice sheets. Slope apron mudstone facies reveal a strong response to high order eustatic events; however, the response of contemporary, easterly sourced, coarse-grade turbidite systems was more complex, with some periods of increased sand and gravel input coinciding with times of rising global sea level. These anomalous relationships are explained by invoking a series of smaller-scale movements in marine base level. It was the interaction of these lower order events with the main eustatic cycles that appears to have been the primary control on sand and gravel input to the Welsh Basin. An early Telychian expansion of the Nant Brianne turbidite system records a marked increase in tectonically generated sediment at a time of palaeo-plate collision between Baltica/Avalonia and Laurentia before intra- and peri-basinal faulting led to its abandonment as a supply path to the basin centre.

We report on the newly discovered almandine garnet phenocrysts in rhyolitic ignimbrites (Sukhda Tuff) in the Precambrian Churtela Shale Formation of the Chhattisgarh Supergroup in central India. SHRIMP ages of igneous zircon from the ignimbrites range from 990 Ma to 1020 Ma. These ignimbrites exhibit characteristic eutaxitic texture with compacted curvilinear glass shards with triple junctions. Quartz (commonly embayed; bluish cathodoluminescence) and albite (altered but retaining ghosts of twinning) are common phenocrysts; others are apatite, ilmenite, rutile, magnetite, zircon, monazite and garnet. There are no metamorphic or granitic xenoliths in the ignimbrites. Garnet grains occur as isolated broken isotropic crystals with sharp or corroded boundaries in a very fine-grained groundmass of volcanic ash that consists principally of albite, quartz, magnetite and glass. They do not have any systematically distributed inclusions. A few have penetratively intergrown phenocrysts of apatite, ilmenite, rutile and zircon, which we interpret as subophitic texture. Extensive SEM-BSE imaging of more than 100 grains and electron microprobe traverses across about 30 grains showed no zoning or systematic compositional variability. Common (metamorphic) garnets are usually zoned with respect to Fe–Mg–Mn and typically have mineral inclusions. We infer, therefore, that these observed garnets are not metamorphic xenocrysts. The average major oxide composition of analysed garnets from five different horizons within the Sukhda Tuff, spanning approximately 300 m of the stratigraphic section, have very small standard deviation for each element, which is suggestive of a single magmatic source. Phenocrysts of quartz, including those in contact with coexisting garnets, show blue scanning electron CL, indicating rapid cooling from high temperature; this suggests that adjacent coexisting garnets are not slowly cooled restites. We conclude, on the basis of texture, mineral chemistry and absence of any indicative xenoliths or xenocrysts, that these almandine garnets (Al78.7Py12.3Gr7.4Sp1.6) are phenocrysts within the Sukhda Tuff. Almandine of such composition is stable under high pressure. We infer that almandine crystallized at lower crustal depths in a magma that ascended very rapidly and may have erupted explosively.

Thin-section observations and electron probe analyses, and trace element data are reported from a new mantle xenolith hosted in Miocene alkali basalt from the western flank of Simien shield volcano, Ethiopia. The spinel lherzolite enclaves contain variable proportions of olivine, orthopyroxene, green clinopyroxene and brown spinel, and have undergone deformation and partial recrystallization. They represent unmetasomatized, fertile xenoliths which were subjected to a late-stage melt–rock reaction. Trace element contents of clinopyroxene crystals are extremely low and quite different from those of the other xenoliths within the East African Rift System.

The widely exposed Kuluketage diabase dyke swarm, Tarim Block, NW China, has been considered to have been emplaced in Permian times. New precise zircon U–Pb SHRIMP ages for two samples from the dyke swarm yield Neoproterozoic ages of 823.8±8.7 Ma and 776.8±8.9 Ma. Correlated with peaks of magmatism in South China and Australia at c. 825 Ma and c. 780 Ma, these two new ages provide significant information for palaeocontinental reconstructions. The prolonged duration of the magmatic events, combined with regional stratigraphic relationships, imply that the Tarim Block may have been affected by a mantle plume during the breakup of Rodinia.