An ideal $I$ of a ring $R$ is called a radical ideal if $I\,=\,\mathcal{R}(R)$ where $\mathcal{R}$ is a radical in the sense of Kurosh–Amitsur. The main theorem of this paper asserts that if $R$ is a valuation domain, then a proper ideal $I$ of $R$ is a radical ideal if and only if $I$ is a distinguished ideal of $R$ (the latter property means that if $J$ and $K$ are ideals of $R$ such that $J\,\subset \,I\,\subset \,K$ then we cannot have $I/J\,\cong \,K/I$ as rings) and that such an ideal is necessarily prime. Examples are exhibited which show that, unlike prime ideals, distinguished ideals are not characterizable in terms of a property of the underlying value group of the valuation domain.