The Maz Metasedimentary Series is part of the Maz Complex that crops out in the sierras of Maz and Espinal (Western Sierras Pampeanas) and in the Sierra de Umango (Andean Frontal Cordillera), northwestern Argentina. The Maz Complex is found within a thrust stack of Silurian age, which later underwent open folding. The Maz Metasedimentary Series mainly consists of medium-grade garnet–staurolite–kyanite–sillimanite schists and quartzites, with minor amounts of marble and calc-silicate rocks. Transposed metadacite dykes have been recognized along with amphibolites, metagabbros, metadiorites and orthogneisses. Schist, quartzite and metadacite samples were analysed for SHRIMP U–Pb zircon dating. The Maz Metasedimentary Series is polymetamorphic and records probably three metamorphic events during the Grenvillian orogeny, at c. 1235, 1155 and 1035 Ma, and a younger metamorphism at c. 440–420 Ma resulting from reactivation during the Famatinian orogeny. The sedimentary protoliths were deposited between 1.86 and 1.33–1.26 Ga (the age of the Andean-type Grenvillian magmatism recorded in the Maz Complex), and probably before 1.75 Ga. The main source areas correspond to Palaeoproterozoic and, to a lesser magnitude, Meso-Neoarchaean rocks. The probable depositional age and the detrital zircon age pattern suggest that the Maz Metasedimentary Series was laid down in a basin of the Columbia supercontinent, mainly accreted between 2.1 and 1.8 Ga. The sedimentary sources were diverse, and we hypothesize that deposition took place before Columbia broke up. The Rio Apa block, and the Río de la Plata, Amazonia and proto-Kalahari cratons, which have nearby locations in the palaeogeographic reconstructions, were probably the main blocks that supplied sediments to this basin.

The North Qilian Orogenic Belt is surrounded by the Tarim Craton to the NW and the North China Craton to the NE. The Precambrian continental crust remnants that are distributed in the North Qilian Orogenic Belt are termed the North Qilian Block (NQB), and their tectonic evolution has profound implications for the evolution of the Columbia Supercontinent. Here we present major- and trace-element and Sr–Nd–Hf isotope data for (meta-) basalts from the Beidahe Group (BDHG) and Zhulongguan Group (ZLGG) in the western North Qilian Orogenic Belt, to investigate the tectonic evolution of the NQB during the Proterozoic Eon. The protoliths of Palaeoproterozoic amphibole gneisses and plagioclase amphibolites from the BDHG are calc-alkaline series basalts. These metabasalts show island-arc-basalt affinities with variable Nd and Hf isotopes (ϵNd(t) = −5.0–0.6 and 2.7–4.3; ϵHf(t) = −14.2–2.0 and 6.9–8.8) and were generated by partial melting of the asthenospheric mantle that was metasomatized by aqueous fluid and sediment melt in a continental-arc setting. The early Mesoproterozoic ZLGG basalts show features of shoshonite-series basalts and are geochemically similar to ocean-island basalts. These basalts show variable (87Sr/86Sr)i, ϵNd(t) and ϵHf(t) values of 0.70464–0.70699, −1–2.6 and −1.5–5.7, and are products of mantle plume magmatism that participated with subducted oceanic crust in an intracontinental rift setting. This study suggests that the NQB underwent tectonic evolution from palaeo-oceanic subduction to intracontinental rifting during the Palaeoproterozoic–Mesoproterozoic eras. Furthermore, the above tectonomagmatic events were in response to convergence–splitting events of the Columbia Supercontinent during the Palaeoproterozoic–Mesoproterozoic eras.

Palaeoproterozic metasedimentary rocks, also referred to as khondalites, characterized by Al-rich minerals, are extensively exposed in the nucleus of the Yangtze craton, South China block. Samples of garnet–sillimanite gneiss in the khondalite suite were collected from the Kongling complex for Nd isotopic and elemental geochemical study. These rocks are characterized by variable SiO2 contents ranging from 35.71 to 58.07 wt%, and have low CaO (0.45–0.84 wt%) but high Al2O3 (18.56–29.04 wt%), Cr (174–334 ppm) and Ni (42.5–153 ppm) contents. They have high CIW (Chemical Index of Weathering) values (90.4–94.7), indicating intense chemical weathering of the source material. The samples display light rare earth elements (LREE) enrichment with negative Eu anomalies (Eu/Eu*=0.40–0.68), and have flat heavy rare earth elements (HREE) patterns. The high contents of transition elements (e.g. Cr, Ni, Sc, V) and moderately radiogenic Nd isotopic compositions suggest that the paragneisses might be those of first-cycle erosion products of predominantly mafic rocks mixing with small amounts of felsic moderately evolved Archaean crustal source. Geochemical and Nd isotopic compositions reveal that at least some of the protoliths of Kongling khondalite were sourced from local pre-existing mafic igneous rocks in a continental arc tectonic setting. Combined with documented zircon U–Pb geochronological data, we propose that the Palaeoproterozoic high-pressure granulite-facies metamorphism, rapid weathering, erosion and deposition of the khondalites in the interior of the Yangtze craton might be related to a Palaeoproterozoic collisional orogenic event during 2.1–1.9 Ga, consistent with the worldwide contemporary orogeny, implying that the Yangtze craton may have been an important component of the Palaeoprotorozoic Columbia supercontinent.

The late Palaeoproterozoic to early Mesoproterozoic igneous rocks of southwestern China are characterized by a number of mafic intrusions and dykes. However, the origin and tectonic implications of these mafic intrusions and dykes remain unclear. The Hekou mafic intrusion, intruding into the Hekou Group in the Hekou area, SW China, is the biggest and most representative one. The intrusion is mainly composed of coarse-grained in the central zone (CZ) and medium- to fine-grained gabbroic rocks in the outer zone (OZ). Cameca secondary ion mass spectroscopy (SIMS) U–Pb zircon ages, and geochemical and Nd isotopic results for the intrusion are reported in this paper. SIMS U–Pb zircon ages indicate that the gabbroic rocks from the CZ and OZ were emplaced at 1735±6.5 Ma and 1736±4.0 Ma, respectively. This suggests that the Hekou intrusion originated from c. 1.7 Ga mafic magmatism in the southwestern Yangtze Block. The coarse-grained rocks in the CZ of the intrusion show fairly homogeneous major- and trace-element compositions. In contrast, the medium- to fine-grained rocks from the OZ display slightly evolved compositions, with relatively lower Mg nos, MgO, Al2O3, Cr and Ni contents, and higher SiO2, CaO and Zr concentrations than those of the rocks from the CZ. Although the gabbroic rocks of the intrusion have low total rare earth element (REE) contents (REE = 29.3–40.2 ppm) with slightly light REE (LREE)-enriched and heavy REE (HREE)-depleted patterns, they exhibit distinct trace-element and Nd isotopic features. The rocks from the CZ are characterized by slightly LREE-enriched and ‘convex upwards’ incompatible trace-element patterns with significant Th depletion and insignificant Nb and Ta depletion relative to La. However, the rocks from the OZ have relatively flatter REE patterns than those of the rocks from the CZ. In addition, the rocks from the OZ are slightly enriched in Th and depleted in Nb and Ta relative to La. The εNd(T) values of the CZ and the OZ rocks are +0.70 to +2.3 and −0.30 to +0.24, respectively. The parental magma for the Hekou gabbroic intrusion exhibits affinity with a subalkaline basaltic magma, which was possibly generated by relatively high degrees of partial melting of a slightly depleted asthenospheric mantle source. Their geochemical and isotopic variations were due to slight crystal fractionation with varying degrees of crustal contamination. The Hekou intrusion was therefore supposed to form in an anorogenic extensional environment. It is further suggested that c. 1.7 Ga is an important onset timing of widespread anorogenic magmatism in the southwestern Yangtze Block. We interpret the late Palaeoproterozoic gabbroic intrusion to represent anorogenic mafic magmatism, which was most likely related to the break-up of the Columbia supercontinent.

Fifteen sandstone samples taken from pre-Cretaceous strata of the Yangtze Block are analysed to constrain the evolution of the South China Block, especially the assembly between the Yangtze and Cathaysia blocks. The results show that the maximum depositional age of the Neoproterozoic Lengjiaxi Group adjacent to the Cathaysia Block is c. 830 Ma, differing from that of the Kunyang and Dahongshan groups (> 960 Ma) on the southwestern margin of the Yangtze Block. The detrital zircons from Palaeozoic samples from the Yangtze Block have similar age populations to those in the Cathaysia Block, and they may originate from the Cathaysia Block according to palaeogeographic, palaeocurrent and former research data. The detrital zircons of Middle–Upper Jurassic sandstones in the southwestern and central Yangtze Block yield dominant age populations at 2.0–1.7 Ga and subordinate groups of 2.6–2.4 Ga, 0.8–0.7 Ga and 0.6–0.4 Ga. The Upper Triassic strata may be derived from the southern Yangtze and North China blocks due to the collisions between the Indosina, South China and North China blocks, whereas the Jurassic sediments may be partly derived from uplift and erosion of the Jiangnan Orogen due to an intracontinental orogeny induced by Pacific subduction towards the Eurasia Plate. The detrital age spectra and provenance data for basement in the South China Block are analysed and compared with each other. The South China Block has affinity with Australia not only in the Columbia supercontinent but also in the Rodinia supercontinent. We infer the existence of an ancient orogen under the western Jiangnan Orogen, which may have occurred during the Columbia age, earlier than the Sibao orogeny. This is supported by seismic profile proof from the SinoProbe.