Palmer amaranth (Amaranthus palmeri S. Watson, AMAPA) is one of the most troublesome weeds in North America due to its rapid growth rate, substantial seed production, competitiveness and the evolution of herbicide-resistant populations. Though frequently encountered in the South, Midwest, and Mid-Atlantic regions of the United States, A. palmeri was recently identified in soybean [Glycine max (L.) Merr.] fields in Genesee, Orange, and Steuben counties, NY, where glyphosate was the primary herbicide for in-crop weed control. This research, conducted in 2023, aimed to (1) describe the dose response of three putative resistant NY A. palmeri populations to glyphosate, (2) determine their mechanisms of resistance, and (3) assess their sensitivity to other postemergence herbicides commonly used in NY crop production systems. Based on the effective dose necessary to reduce aboveground biomass by 50% (ED50), the NY populations were 42 to 67 times more resistant to glyphosate compared with a glyphosate-susceptible population. Additionally, the NY populations had elevated EPSPS gene copy numbers ranging from 25 to 135 located within extrachromosomal circular DNA (eccDNA). Label rate applications of Weed Science Society of America (WSSA) Group 2 herbicides killed up to 42% of the NY populations of A. palmeri. Some variability was observed among populations in response to WSSA Group 5 and 27 herbicides. All populations were effectively controlled by labeled rates of herbicides belonging to WSSA Groups 4, 10, 14, and 22. Additional research is warranted to confirm whether NY populations have evolved multiple resistance to herbicides within other WSSA groups and to develop effective A. palmeri management strategies suitable for NY crop production.

Tolpyralate is an herbicide that is usually mixed with atrazine for broad-spectrum weed control in corn. Previous research has provided information on the effective dose (ED) of tolpyralate applied alone and in a 1:33.3 mixture with atrazine; however, tolpyralate is commercially applied at a dose of 30 to 40 g ai ha−1 with a minimum of 560 g ai ha−1 of atrazine. Therefore, five field trials were conducted over 3 yr (2019 to 2021) to determine the ED of atrazine to complement 30 g ai ha−1 of tolpyralate to achieve 80%, 90%, and 95% control of seven weed species 2, 4, and 8 wk after application (WAA). Tolpyralate was applied alone and in a mixture with atrazine doses ranging from 50 to 2,000 g ai ha−1. At 8 WAA, the ED of atrazine for 95% control of velvetleaf, common ragweed, common lambsquarters, and wild mustard was below the minimum label dose of atrazine on the commercial tolpyralate label, ranging from 430 to 520 g ai ha−1, which supports the use of the minimum label dose of atrazine. In contrast, redroot pigweed required 1,231 g ai ha−1 of atrazine to complement tolpyralate for 95% control 8 WAA. At 8 WAA, barnyardgrass and a mixture of green foxtail and giant foxtail (Setaria spp.) were not controlled by 80%, 90%, or 95% with tolpyralate applied alone or co-applied with any dose of atrazine evaluated in this study. The results of this study conclude that tolpyralate + atrazine is highly efficacious on several weed species at atrazine doses of 40 to 130 g ai ha−1 below the label dose of 560 g ai ha−1, but the use of the higher dose of tolpyralate or another herbicide may be required to improve control of redroot pigweed and grass weed species.

Tolpyralate is a 4-hydroxyphenylpyruvate dioxygenase–inhibiting herbicide that is applied postemergence for control of annual broadleaf and grass weeds in corn. Current Canadian label recommendations for tolpyralate specify the addition of a methylated seed oil (MSO) adjuvant (MSO Concentrate®) for improved weed control. The efficacy of tolpyralate applied with other proprietary adjuvants has not been widely reported in the peer-reviewed literature. Therefore, four field trials were conducted in corn over 2020 and 2021 in Ontario, Canada, to evaluate MSO Concentrate®, Agral® 90 (nonionic surfactant), Assist® Oil Concentrate (blended surfactant), Carrier® (blended surfactant), LI 700® (nonionic surfactant), and Merge® (blended surfactant) as adjuvants with tolpyralate for the control of annual broadleaf and grass weeds. At 8 wk after application (WAA), tolpyralate applied with MSO Concentrate®, Agral® 90, Assist® Oil Concentrate, Carrier®, or Merge® controlled velvetleaf, wild mustard, barnyardgrass, and foxtail species similarly. These adjuvants also enhanced the efficacy of tolpyralate similarly for the control of common ragweed at 8 WAA with the exception that Agral® 90 was inferior to Merge®. At 8 WAA, tolpyralate controlled common lambsquarters the greatest when applied with MSO Concentrate®, Agral® 90, Carrier®, or Merge®; these adjuvants with the exception of Agral® 90 were superior to Assist® Oil Concentrate. At 8 WAA, tolpyralate applied with LI 700® controlled common ragweed, barnyardgrass, and foxtail species less than when tolpyralate was applied with the other adjuvants tested; control of these weed species with tolpyralate was not improved with LI 700® when compared to tolpyralate applied without an adjuvant. Overall, tolpyralate applied with either MSO Concentrate®, Carrier®, or Merge® controlled all annual broadleaf and grass weed species similarly or greater than tolpyralate applied without an adjuvant or tolpyralate with Agral® 90, Assist® Oil Concentrate, or LI 700® at 8 WAA.

Only four herbicides are registered for smooth crabgrass or goosegrass control on creeping bentgrass golf putting greens. None of the four herbicides control weedy grasses for the entire season or control weeds postemergence when applied once at labeled rates. Three of the product labels prohibit repeated use or application during stressful summer conditions. We hypothesized frequently applying herbicides at low doses could provide season-long control of summer grasses while minimizing turf injury. Seven field experiments were conducted on creeping bentgrass putting greens to evaluate various herbicides applied monthly, biweekly, or weekly for postemergence and residual control of goosegrass and smooth crabgrass as well as creeping bentgrass putting green tolerance. Metamifop applied twice monthly at 200 g ai ha−1, topramezone applied eight times weekly at 1.5 g ae ha−1, and siduron applied weekly at 5.6 kg ai ha−1 or four times biweekly at 11 kg ha−1 did not injure creeping bentgrass greater than 10% and maintained creeping bentgrass quality and cover equivalent to nontreated turf. Weekly or biweekly programs of fenoxaprop or quinclorac caused unacceptable injury and quality decline. Metamifop applied monthly and either fenoxaprop program controlled both smooth crabgrass and goosegrass by 97% to 99% throughout the growing season. Programs containing either quinclorac or siduron controlled smooth crabgrass by 99% to 100% but did not control goosegrass greater than 39%. All topramezone programs controlled smooth crabgrass by 69% to 77% and goosegrass by 93% to 98%. In additional studies, siduron applied five times biweekly did not injure creeping bentgrass on putting greens and controlled smooth crabgrass by more than 90% at seasonal, cumulative rates between 17 and 65 kg ai ha−1. This method of frequent, low-dose herbicide treatment to control smooth crabgrass and goosegrass on golf putting greens is novel and currently could be legally implemented with siduron.

Manufacturers of several POST corn herbicides recommend tank-mixing their herbicides with atrazine to improve performance; however, future regulatory changes may place greater restrictions on atrazine use and limit its availability to growers. Our research objectives were to quantify the effects of tank-mixing atrazine with tembotrione compared to tembotrione alone on (1) weed control, (2) variability in weed control, and (3) sweet corn yield components and yield variability. Field studies were conducted for 2 yr each in Illinois, Oregon, Washington, and Ontario, Canada. Tembotrione at 31 g ha−1 was applied alone and with atrazine at 370 g ha−1 POST at the four- to five-collar stage of corn. The predominant weed species observed in the experiment were common to corn production, including large crabgrass, wild-proso millet, common lambsquarters, and velvetleaf. For nearly every weed species and species group, the addition of atrazine improved tembotrione performance by increasing mean levels of weed control 3 to 45% at 2 wk after treatment. Adding atrazine reduced variation (i.e., standard deviation) in control of the weed community by 45%. Sweet corn ear number and ear mass were 9 and 13% higher, respectively, and less variable when atrazine was applied with tembotrione, compared to tembotrione alone. Additional restrictions or the complete loss of atrazine for use in corn will necessitate major changes in sweet corn weed management systems.

The premix atrazine + S-metolachlor is commonly used to control a wide range of weeds in corn, but it is weak on velvetleaf and several other broadleaf species. RPA 201772, used at reduced rates in combination with atrazine + S-metolachlor, may improve the weed control spectrum. In field studies at Urbana and Dekalb in 1998 and 1999, RPA 201772 was combined with a premix of atrazine at 1,820 g ai/ha and S-metolachlor at 1,408 g ai/ha to compare RPA 201772 rate effects on corn injury, weed control, and yield. RPA 201772 was applied at 0, 26, 53, 78, 105, and 132 g ai/ha early preplant (EPP), preplant incorporated (PPI), and preemergence (PRE). Compared with atrazine + S-metolachlor alone, RPA 201772 combinations did not improve giant foxtail control. However, RPA 201772 at 26 or 53 g/ha increased control of redroot pigweed, common lambsquarters, ivyleaf morningglory, common ragweed, giant ragweed, and velvetleaf in some environments. At Urbana in both years, RPA 201772 at 26 g/ha in combination with atrazine + S-metolachlor increased velvetleaf control 15% compared with the premix alone. RPA 201722 at 26 to 78 g/ha decreased velvetleaf densities with all application methods. Greater weed control and higher corn yield occurred in treatments applied PRE or PPI compared with EPP applications, except where conditions were dry after PRE applications. This research demonstrates the benefit of RPA 201772 at low rates for broadleaf weed control with less potential for crop injury compared with high RPA 201772 rates.

POST combinations of photosystem II (PSII) and the 4-hydroxyphenylpyruvate dioxygenase (HPPD) inhibitors are effective for control of broadleaf weeds in corn. Field studies were conducted during 2007 and 2008 in Urbana and Dekalb, IL, to determine the nature of interactions between two PSII inhibitors, atrazine and bromoxynil, and the HPPD inhibitor mesotrione, based on control of common waterhemp, common lambsquarters, and giant ragweed. Two rates of each herbicide were evaluated, with the highest representing a typical recommended rate, and the lowest a fraction of that rate. Synergistic interactions occurred for common waterhemp control from 10 to 30 d after treatment (DAT) regardless of herbicide rates, rainfall accumulation, or plant height. Synergism between mesotrione and bromoxynil was not observed for common lambsquarters control at Urbana in 2008 at the lower herbicide rates, possibly due to taller weed heights at the time of herbicide application relative to 2007. Giant ragweed control indicated that a synergistic interaction occurred for all herbicides and rates in 2008. However, synergism between bromoxynil and mesotrione did not occur in 2007, likely due to limited rainfall before herbicide application. Reduced herbicide rates and adverse environmental conditions have the potential to regulate the expression of synergism between mesotrione and PSII inhibitors, and therefore may limit their effectiveness for weed management in corn.

The joint activity of mesotrione and atrazine can display synergistic effects on the control of both triazine-sensitive and site-of-action-based triazine-resistant (TR) broadleaf weeds. The first objective of this study was to evaluate a PRE application of atrazine followed by a POST application of mesotrione for potential interactions in both site-of-action-based TR redroot pigweed and metabolism-based atrazine-resistant (AR) velvetleaf. Results from these sequential experiments demonstrated that synergism was detected in reducing biomass of the TR redroot pigweed but not in the AR velvetleaf with metabolism-based resistance. The second objective was to evaluate the joint activity of mesotrione and atrazine in a tank-mix application in the AR velvetleaf biotype. Greenhouse studies with the AR biotype indicated that synergism resulted from a tank mix with a constant mesotrione rate of 3.2 g ai ha−1 in mixture with atrazine ranging from 126 to 13,440 g ai ha−1. Chlorophyll fluorescence imaging also revealed a synergistic interaction on the AR biotype when 3.2 g ha−1 of mesotrione was applied with 126 g ha−1 of atrazine beginning 36 h after treatment and persisting through 72 h.

Topramezone controls weeds in tolerant, cool-season turfgrasses, but injury potential during establishment has received limited investigation. The objectives of this research were to evaluate the tolerance of ‘Penn A-4’ creeping bentgrass, ‘Manhattan V' perennial ryegrass, and ‘Titan' tall fescue to topramezone at 18.5, 37, or 74 g ae ha−1 during establishment. Grasses were seeded in strips in October, and treatments were applied at 0, 2, 4, or 6 wk after seeding (WAS). Perennial ryegrass and tall fescue had minimal (≤ 8%) injury from all treatments, and ground cover was greater or equal to the nontreated at all application timings. Topramezone applied 4 WAS at 37 and 74 g ha−1 injured creeping bentgrass 16 and 23% at 2 wk after treatment, respectively. However, all other topramezone rates and timings caused < 10% injury. Mesotrione at 175 g ai ha−1 injured creeping bentgrass 14 to 43% at all timings and was more injurious than topramezone. Mesotrione applied at 2, 4, or 6 WAS controlled lesser swinecress ≥ 99% at 20 WAS, whereas applications on the day of seeding provided 71% control. All topramezone treatments provided poor control (< 70%) of lesser swinecress at 20 WAS. Overall, perennial ryegrass and tall fescue are tolerant to topramezone during establishment at the rates tested. Seedling creeping bentgrass has better tolerance to topramezone from 18.5 to 74 g ha−1, than to mesotrione at 175 g ha−1 and may provide end-users an HPPD inhibitor for use during establishment.

Joint action of the effects of atrazine and mesotrione can lead to synergistic herbicidal activity in broadleaf weed species. The objective of these experiments was to determine if specific rates are required to provide synergistic joint activity between mesotrione and atrazine in both triazine-sensitive (TS) and triazine-resistant (TR) redroot pigweed. Herbicide rates were evaluated in TS and TR redroot pigweed in two experiments: a dose response of mesotrione alone and in mixture with a constant rate of atrazine and a dose response of atrazine alone and in mixture with a constant rate of mesotrione. Results from these experiments revealed that synergism was detected in the TS pigweed when 56 g ai ha−1 mesotrione was mixed with 126 g ai ha−1 atrazine. In the TR pigweed, synergism was detected when mesotrione rate at 10 to 56 g ha−1 was mixed with a constant rate of atrazine at 126 g ha−1. Additionally, when mesotrione was held constant at 10 g ha−1, synergism was detected in mixture with atrazine from 31 to 3556 g ha−1 in TR pigweed. Furthermore, in TR pigweed, analysis of slope deviation across the dose-response curves of mesotrione with and without atrazine revealed a divergence that increased in magnitude as the rate of mesotrione increased. In other words, increased synergism was observed with increased mesotrione rate in the TR pigweed, which was also supported by biomass reduction and atrazine-like injury to the leaves. An additional experiment investigated synergism between mesotrione and bromoxynil in both TS and TR pigweed. Mesotrione at 10 g ha−1 was synergistic when paired with bromoxynil from 70 to 210 g ha−1 in both the TS and the TR pigweed.

Creeping bentgrass creates a dense, high-quality playing surface on golf courses, but it often encroaches adjacent areas of Kentucky bluegrass. Mesotrione can control creeping bentgrass in Kentucky bluegrass, but more information is needed regarding the effect of herbicide rate and number of applications on creeping bentgrass control and the impact to Kentucky bluegrass. Field experiments were conducted to determine the effect of application rate and number of applications on creeping bentgrass control. One application of mesotrione controlled 7 to 43% of creeping bentgrass in Kentucky bluegrass, and two applications of mesotrione controlled 39 to 88% as rates increased from 70 to 1,120 g ai/ha. Gaps present in the canopy after the creeping bentgrass died reduced overall turfgrass quality 2 to 6 wk after treatment (WAT) before recovering. These data indicate the capability of mesotrione to selectively control creeping bentgrass while providing excellent safety to Kentucky bluegrass.