Oxygen isotope ratios of <0.1-μm smectite in bottom sediments of the Mississippi River and the Gulf of Mexico near the mouth of the river have been determined to investigate diagenesis of land-derived clay minerals during sedimentation in the sea. No difference was detected in δ18O (SMOW) between the river and the Gulf samples indicating that no smectite alteration or addition of neoformed smectite to the river samples took place during sedimentation. Thus, authigenic minerals in the river sediments cannot make up more than a few tenths of a percent of the bulk sediments.

Similar results were obtained from 3 × 106-yr b.p. sediments buried to 80 to 600 m at Deep Sea Drilling Project site 323, Bellingshausen Abyssal Plain. No significant change with depth was noted in the δ18O of the <0.3-μm size fraction, mostly smectite, of these land-derived sediments. On the basis of the δ18O of the deepest sample, the maximum amount of authigenic minerals in the land-derived sediments during burial in the sea cannot be more than one or two percent of the bulk sediments. Hence, the alteration at seafloor temperatures of 25-45% of the <0.1-μm size clays in 3 × 106 yr b.p. sediments reported in a previous study is not substantiated. The data demonstrate that land-derived smectite is stable in the sea, and that oxygen isotopes can be used to investigate the modes and the temperatures of formation of authigenic smectites in marine sediments that are younger than 25 × 106 yr and that formed below 25°C.

Mineralogy, kaolin crystallinity, Fe content, δO18, and δD were determined for late Cretaceous “soft” and early Tertiary “hard” Georgia kaolins. The crystallinity of the <0.5-, 0.5–1.0-, and 1.0–2.0- μm size fractions of soft kaolins was higher than that of equivalent size fractions of hard kaolins. δO18 and δD of the soft and hard kaolins ranged between 18.5 to 23.1‰, and −64 to −41‰, respectively, and could not be used to discriminate soft from hard kaolins. The trends of crystallinity vs. δO18 were different for kaolins collected at different localities, and, for a given sample, δO18 generally decreased with increasing crystallinity and with increasing crystallite size. These data indicate that the Tertiary kaolins could not have been simply derived from the Cretaceous kaolins by winnowing unless post-sedimentation recrystallization of one or both occurred. δD vs. δO18 systematics indicate that the late Cretaceous to early Tertiary Georgia kaolins crystallized over a temperature range of about 15°C in the presence of waters that varied little in isotopic composition.

In two forensic cases, radiocarbon (14C) bomb-pulse datings of human bones have been performed and analyzed using detailed models to correct for collagen-carbon turnover rates and reservoir effects. The modeled corrections are discussed and the resulting 14C ages compared to later information on actual time of birth and death of the individuals. Simple time lag corrections of bone dates are found to be inadequate, whereas modeling based on age dependent turnover rates and bomb-pulse levels through life combined with substantial reservoir age corrections can explain the observed 14C results.

This study investigates the Danian siliciclastic successions in the East Tethys in the Kopet-Dagh Basin, NE Iran, which are composed of conglomerates, sandstones, shales and mudstones. The studied interval includes significant changes in sedimentary environments from alluvial to fluvial systems. The Danian siliciclastic formation is sandwiched between two marine carbonate sequences. The effects of the late Palaeocene sea transgression can be traced back to the precipitation of several types of carbonate cement in the studied siliciclastic formation. Several diagenetic features have been identified in the studied successions. The most observed features comprise physical and chemical compaction, cementation, alteration, dissolution, fractures and fillings. Some of the mentioned diagenetic processes, such as cementation, may be seen in a range of diagenetic environments and phases, such as early meteoric, low depth and deep burial, and late meteoric after the tectonic uplifting. The calcite cements considered in this study have been subdivided into four types. Some of the calcite cements, such as the rim, gravity pendant and meniscus, are classified as type one. They have formed around the rock grains and show no luminescence. The blocky and poikilotopic types have been grouped in type two. They are deposited between grains and exhibit dark luminescence. Type three cement consists of some of the blocky and poikilotopic cements that have formed amid grains and present a bright luminescence. Finally, type four comprises filled fractures which display a dark luminescence (blocky cement). Geochemical data revealed that the categorized cement types were precipitated in three diagenetic environments: early meteoric; burial; and late meteoric after the uplifting. The meteoric diagenetic environment is subdivided into vadose and phreatic meteoric. The burial diagenetic environment is subdivided into shallow burial and deeper burial. The qualitative petrographic method contributed to the initial recognition of the diagenetic features. The semi-quantitative cathodoluminescence method, the quantitative major and trace elements, and oxygen and carbon stable isotope analysis were utilized to evaluate the exact diagenetic processes and environments. Finally, the diagenetic sequence was reconstructed and depicted as diagenetic models and a paragenesis sequence. The data of this study can lay the foundation for future studies on the siliciclastic diagenesis in the studied basin.

The cosmic evolution of the chemical elements from the Big Bang to the present time is driven by nuclear fusion reactions inside stars and stellar explosions. A cycle of matter recurrently re-processes metal-enriched stellar ejecta into the next generation of stars. The study of cosmic nucleosynthesis and this matter cycle requires the understanding of the physics of nuclear reactions, of the conditions at which the nuclear reactions are activated inside the stars and stellar explosions, of the stellar ejection mechanisms through winds and explosions, and of the transport of the ejecta towards the next cycle, from hot plasma to cold, star-forming gas. Due to the long timescales of stellar evolution, and because of the infrequent occurrence of stellar explosions, observational studies are challenging, as they have biases in time and space as well as different sensitivities related to the various astronomical methods. Here, we describe in detail the astrophysical and nuclear-physical processes involved in creating two radioactive isotopes useful in such studies, $^{26}\mathrm{Al}$ and $^{60}\mathrm{Fe}$ . Due to their radioactive lifetime of the order of a million years, these isotopes are suitable to characterise simultaneously the processes of nuclear fusion reactions and of interstellar transport. We describe and discuss the nuclear reactions involved in the production and destruction of $^{26}\mathrm{Al}$ and $^{60}\mathrm{Fe}$ , the key characteristics of the stellar sites of their nucleosynthesis and their interstellar journey after ejection from the nucleosynthesis sites. This allows us to connect the theoretical astrophysical aspects to the variety of astronomical messengers presented here, from stardust and cosmic-ray composition measurements, through observation of $\gamma$ rays produced by radioactivity, to material deposited in deep-sea ocean crusts and to the inferred composition of the first solids that have formed in the Solar System. We show that considering measurements of the isotopic ratio of $^{26}\mathrm{Al}$ to $^{60}\mathrm{Fe}$ eliminate some of the unknowns when interpreting astronomical results, and discuss the lessons learned from these two isotopes on cosmic chemical evolution. This review paper has emerged from an ISSI-BJ Team project in 2017–2019, bringing together nuclear physicists, astronomers, and astrophysicists in this inter-disciplinary discussion.

We tested the potential for sand calcites to serve as a novel paleoclimate archive by investigating their age and formation conditions. Fontainebleau sand calcites are Pleistocene in age (based on 14C and U-Th dating) and were primarily formed during glacial periods. δ13C values increase with the depth at which these sand calcites formed, consistent with open and closed CO2 systems. Interpretation of the δ18O-T relationship in sand calcites points primarily to their formation at a low temperature, around 2°C in shallow ground water and at about 9°C in deeper ground-water settings. Their occurrence, characteristics, and compositions suggest crystallization from paleo-ground waters in permafrost environments. Crystallization of sand calcites was triggered by degassing of cold carbonate-containing surface waters as they infiltrated warmer subsurface ground-water environments. We consider sand calcites to be important indicators of interactions between meteoric water and ground water in Pleistocene periglacial landscapes. Their disposition may point to specific features of periglacial landscapes, and their ages could permit an assessment of landscape incision rates. Large crystals and zoned spheroliths may, in fact, encapsulate continuous high-resolution records of continental glacial and periglacial paleoenvironments.

We study exceptional Jordan algebras and related exceptional group schemes over commutative rings from a geometric point of view, using appropriate torsors to parametrize and explain classical and new constructions, and proving that over rings, they give rise to nonisomorphic structures.

We begin by showing that isotopes of Albert algebras are obtained as twists by a certain $\mathrm F_4$ -torsor with total space a group of type $\mathrm E_6$ and, using this, that Albert algebras over rings in general admit nonisomorphic isotopes even in the split case, as opposed to the situation over fields. We then consider certain $\mathrm D_4$ -torsors constructed from reduced Albert algebras, and show how these give rise to a class of generalised reduced Albert algebras constructed from compositions of quadratic forms. Showing that this torsor is nontrivial, we conclude that the Albert algebra does not uniquely determine the underlying composition, even in the split case. In a similar vein, we show that a given reduced Albert algebra can admit two coordinate algebras which are nonisomorphic and have nonisometric quadratic forms, contrary, in a strong sense, to the case over fields, established by Albert and Jacobson.

Protein turnover is an energy-consuming process that is essential for ensuring the maintenance of living organisms. Gold standard methods for whole-body protein turnover (WBPT) measurement have inherent drawbacks precluding their generalization for large farm animals and use during long periods. Here, we proposed a non-invasive proxy for the WBPT over a long period of time and in a large number of beef cattle. The proxy is based on the rate at which urine-N and plasma proteins are progressively depleted in terms of 15N after a slight decrease in the isotopic N composition of the diet (i.e. diet switch). We aimed to test the ability of this proxy to adequately discriminate the WBPT of 36 growing-fattening young bulls assigned to different dietary treatments known to impact the WBPT rate, with different protein contents (normal v. high) and amino acid profiles (balanced v. unbalanced in methionine). The 15N depletion rate found in plasma proteins represented their fractional synthesis rate, whereas the slow depletion rate found in urine was interpreted as a proxy of the WBPT. The proxy tested in urine suggested different WBPT values between the normal- and high-protein diets but not between the balanced and unbalanced methionine diets. In contrast, the proxy tested in plasma indicated that both dietary conditions affected the fractional synthesis rate of plasma proteins. We considered that the rate at which urine is progressively 15N-depleted following an isotopic diet switch could be proposed as a non-invasive proxy of the WBPT rate in large farm animals.

The principal clays of the northern and central North Sea are illite (sometimes with interlayered smectite) and kaolin. Chlorite is only locally important. Although it has been proposed that kaolin within North Sea sandstones is detrital in origin, the majority of workers have concluded that it is authigenic, largely the product of feldspar alteration. Kaolin is found within a wide range of sedimentary settings (and within shales) apparently defying the notion that kaolin is an indicator of meteoric water deposition. Within sandstones, the earliest authigenic kaolin has a vermiform morphology, the distribution of which is controlled by the availability of detrital mica to act as a nucleus, and the composition of the post-depositional porewaters. This vermiform kaolin formed in meteoric water, the presence of which is easily accounted for below sub-aerial exposure surfaces in non-marine formations, and below unconformities over marine units. In fully marine sands, and even marine shale units, kaolin still occurs. It has therefore been suggested that even these locations have been flushed with meteoric water.

Early vermiform kaolin recrystallizes to a more blocky morphology as burial proceeds, at least in the Brent Group. Blocky kaolin has been reported as growing before, synchronously with, and after the formation of quartz overgrowths, though oxygen isotope studies support low-temperature growth, pre-quartz. Blocky kaolin may form during meteoric flushing associated with lower Cretaceous uplift and erosion, though it is found in fault blocks that are thought to have remained below sea level. Here, the kaolin may form in stagnant meteoric water, relics of the post-depositional porewater. It has also been proposed that the blocky kaolin grew in ascending basinal waters charged with carboxylic acids and CO2, though this hypothesis is not supported by stable oxygen isotope data. Some of the blocky kaolin is dickite, the stable polymorph above ∼100°C.

Fibrous illite occurs almost ubiquitously within the clastic sediments of the North Sea. An early pore-lining phase has been interpreted as both infiltrated clastic clay, and as an early diagenetic phase. Early clays may have been quite smectite-rich illites, or even discrete smectites. Later, fibrous illite is undoubtedly neoformed, and can degrade reservoir quality significantly. Both within sandstones and shales, there is an apparent increase in the K content deeper than 4 km of burial, which could be due to dilution of the early smectite-rich phase by new growth illite, or to the progressive illitization of existing I-S. Much of the ‘illite’ that has been dated by the K-Ar method may therefore actually be I-S.

The factors that control the formation of fibrous illite are only poorly known, though temperature must play a role. Illite growth has been proposed for almost the entire range of diagenetic temperatures (e.g. 15–20°C, Brent Group; 35–40°C, Oxfordian Sand, Inner Moray Firth; 50–90°C, Brae formation; 100–110°C, Brent Group; 130–140°C, Haltenbanken). It seems unlikely that there is a threshold temperature below which illite growth is impossible (or too slow to be significant), though this is a recurring hypothesis in the literature. Instead, illite growth seems to be an event, commonly triggered by oil emplacement or another change in the physiochemical conditions within the sandstone, such as an episode of overpressure release. Hence fibrous illite can grow at any temperature encountered during diagenesis.

Although there is an extensive dataset of K-Ar ages of authigenic illites from the Jurassic of the North Sea, there is no consensus as to whether the data are meaningful, or whether the purified illite samples prepared for analysis are so contaminated with detrital phases as to render the age data meaningless. At present it is unclear about how to resolve this problem, though there is some indication that chemical micro-analysis could help. It is a common belief that illite ages record the timing of oil charge, and so can be used to calibrate basin models.

Grain-coating Fe-rich chlorite cements can preserve exceptional porosity during burial. They are found in marginal marine sandstones, formed during diagenesis from precursor Fe-rich clays such as berthierine or verdine.

Analyses of sediment cores from Jellybean Lake, a small, evaporation-insensitive groundwater-fed lake, provide a record of changes in North Pacific atmospheric circulation for the last ∽7500 yr at 5- to 30-yr resolution. Isotope hydrology data from the southern Yukon indicate that the oxygen isotope composition of water from Jellybean Lake reflects the composition of mean-annual precipitation, δ18Op. Recent changes in the δ18O of Jellybean sedimentary calcite (δ18Oca) correspond to changes in the North Pacific Index (NPI), a measure of the intensity and position of the Aleutian Low (AL) pressure system. This suggests that δ18Op variability was related to the degree of fractionation during moisture transport from the Gulf of Alaska across the St. Elias Mountains and that Holocene shifts were controlled by the intensity and position of the AL. Following this model, between ∽7500 and 4500 cal yr B.P., long-term trends suggest a predominantly weaker and/or westward AL. Between ∽4500 and 3000 cal yr B.P. the AL shifted eastward or intensified before shifting westward or weakening between ∽3000 and 2000 cal yr B.P. Rapid shifts eastward and/or intensification occurred ∽1200 and 300 cal yr B.P. Holocene changes in North Pacific atmospheric circulation inferred from Jellybean Lake oxygen isotopes correspond with late Holocene glacial advances in the St. Elias Mountains, changes in North Pacific salmon abundance, and shifts in atmospheric circulation over the Beaufort Sea.

Two stalagmites from Devil's Icebox Cave, central Missouri, display similar δ13C and δ18O values and trends during the late Holocene. Positive δ13C excursions at 3.5–2.6 ka and 1.2–0.9 ka are interpreted to reflect drier conditions. These elevated stalagmite δ13C values could have plausibly been driven by increasing C4 plant abundances over the cave or an increased contribution of bedrock carbon, both of which could reflect decreased effective moisture. A lack of corresponding oxygen isotopic anomalies during these intervals suggests that neither mean annual temperature nor the seasonality of precipitation changed concomitantly with dryness. Both of the δ13C excursions identified in our stalagmite record are roughly coincident with dry intervals from a number of sites located across the Great Plains.

We studied a 5.1-m sediment core from Aguada X'caamal (20° 36.6′N, 89° 42.9′W), a small sinkhole lake in northwest Yucatan, Mexico. Between 1400 and 1500 A.D., oxygen isotope ratios of ostracod and gastropod carbonate increased by an average of 2.2‰ and the benthic foraminifer Ammonia beccarii parkinsoniana appeared in the sediment profile, indicating a hydrologic change that included increased lake water salinity. Pollen from a core in nearby Cenote San José Chulchacá showed a decrease in mesic forest taxa during the same period. Oxygen isotopes of shell carbonate in sediment cores from Lakes Chichancanab (19° 53.0′N, 88° 46.0′W) and Salpeten (16° 58.6′N, 89° 40.5′W) to the south also increased in the mid-15th century, but less so than in Aguada X'caamal. Climate change in the 15th century is also supported by historical accounts of cold and famine described in Maya and Aztec chronicles. We conclude that climate became drier on the Yucatan Peninsula in the 15th century A.D. near the onset of the Little Ice Age (LIA). Comparison of results from the Yucatan Peninsula with other circum-Caribbean paleoclimate records indicates a coherent climate response for this region at the beginning of the LIA. At that time, sea surface temperatures cooled and aridity in the circum-Caribbean region increased.

Traits of primary producers associated with tissue quality are commonly assumed to have strong control over higher trophic levels. However, this view is largely based on studies of vascular plants, and cryptogamic vegetation has received far less attention. In this study natural gradients in nutrient concentrations in cryptogams associated with the proximity of penguin colonies on a Maritime Antarctic island were utilized to quantify the impact of nitrogen content on micro-arthropod communities. Proximity to penguin colonies increased the nitrogen concentration of cryptogams, and the penguin source was confirmed by decreasing δ15N values at greater distances from colonies. Micro-arthropod abundance, diversity (H’) and richness declined with distance from the penguin colonies, and was positively correlated with the nitrogen concentrations of cryptogams. Δ15N of micro-arthropods was positively correlated (r2=0.865, P<0.01) with δ15N of the moss Andreaea depressinervis indicating that penguin-derived nitrogen moves through Antarctic food webs across multiple trophic levels. Nitrogen content of cryptogams was correlated with associated micro-arthropods indicating that biotic interactions affect community development in Antarctic terrestrial ecosystems. The spatial patterns of Antarctic biodiversity can therefore be affected by local factors, such as marine vertebrates, beyond existing latitudinal patterns of temperature and water availability.

Fifty six sediment cores were collected along a 100 km longitudinal transect of the Thames estuary. Total Hg ranged from 0.01 to 12.07 mg/kg, with a mean of 2.10 mg/kg (n=351). Concentrations of the toxic metal decreased downstream from London to the outer estuary and were positively correlated to total organic carbon (TOC) content. Many Hg profiles showed a clear rise, peak and fall, reflecting changing anthropogenic input through time. Surface concentrations averaged 1.27 mg/kg, confirming the effectiveness of recent environmental legislation and improved river management. Sediments at >40 cm depth from London reaches of the river (Waterloo Bridge, Cuckolds Point (Rotherhithe), Butlers Wharf (Tower Bridge), Millwall, Deptford and Millennium Dome) were highly contaminated, with levels of Hg of >7 mg/kg. The outer Thames had lower Hg, with the exception of Rainham, Crossness and Cliffe. Benchmarking against UK guidelines for the disposal of dredged material revealed that 88 samples from 21 sites exceeded the 3 mg/kg criteria (unsuitable for disposal at sea); 173 fell between 0.3 and 3 mg/kg (further assessment required); and 90 were of no concern. Using Hg as a generic pollution marker, the tidal Thames is one of the world's most contaminated river–estuarine sediment systems.

Using the Delingha 13.7 m telescope with a 9-beam SIS superconducting receiver installed, we carried out mapping of C18O and C17O J = (1 − 0) toward molecular clouds in the central molecular zone (CMZ) and in the halo of our galaxy. From the integrated intensity ratio of C18O to C17O, the isotope ratio 18O/17O ratio can be estimated, which is considered to be one of the most useful tracers of nuclear processing and metal enrichment. Here preliminary results are presented toward Sgr A, Sgr B2, Sgr C, Sgr D, and the 1.°3 complex in the CMZ and M+5.3–0.3 in the halo.

Considerable debate persists concerning the origins of those involved in the adventus Saxonum: the arrival of Germanic peoples in Britain during the fifth century AD. This question was investigated using oxygen and strontium isotope ratios obtained from archaeological dental samples from individuals in the ‘Migration Period’ cemetery, Ringlemere, Kent (n = 7) and three continental European sites (n = 17). Results demonstrated that strontium alone is unable to distinguish between individuals from south-east England and north-west Europe. Although 87Sr/86Sr values from Ringlemere fell within local biosphere parameters and suggest a spatially and temporally related group, δ18O values were inconsistent with origins in eastern England or on the North German plain. Results from the European sites negate past climate change as an explanation. It is possible that culturally mediated behaviour has obscured geographical relationships. Further work to characterize water sources and human δ18O values in the putative European homelands is required.