In recent years, automatic speaker verification (ASV) is used extensively for voice biometrics. This leads to an increased interest to secure these voice biometric systems for real-world applications. The ASV systems are vulnerable to various kinds of spoofing attacks, namely, synthetic speech (SS), voice conversion (VC), replay, twins, and impersonation. This paper provides the literature review of ASV spoof detection, novel acoustic feature representations, deep learning, end-to-end systems, etc. Furthermore, the paper also summaries previous studies of spoofing attacks with emphasis on SS, VC, and replay along with recent efforts to develop countermeasures for spoof speech detection (SSD) task. The limitations and challenges of SSD task are also presented. While several countermeasures were reported in the literature, they are mostly validated on a particular database, furthermore, their performance is far from perfect. The security of voice biometrics systems against spoofing attacks remains a challenging topic. This paper is based on a tutorial presented at APSIPA Annual Summit and Conference 2017 to serve as a quick start for those interested in the topic.