Consider a stationary Markov chain with state space consisting of the ξ -letter alphabet set Λ= {a1, a2, ···, aξ }. We study the variables M=M(n, k) and N=N(n, k), defined, respectively, as the number of overlapping and non-overlapping occurrences of a fixed periodic k-letter word, and use the Stein–Chen method to obtain compound Poisson approximations for their distribution.