A new compositional variety of zirconolite characterized by high Mg, Al, Y2O3 and REE, and low Fe is described from a sapphirine granulite xenolith entrained in an intrusive norite body which was emplaced into the late Archaean (2520–2480 Ma) Vestfold Hills high-grade terrain during the early Proterozoic. The zirconolite, and similarly Mg-Al rich perrierite-(Ce), formed as a result of sanidinite facies partial melting of the particularly magnesian and aluminous sapphirine granulite xenolith during its incorporation into the c. 1170°C basic magma at c. 2240 Ma. The high REE compared to Al cations require that a previously unrecognized coupled substitution:

occurs in this zirconolite. Full chemical analyses are presented for zirconolite and perrierite from this unique occurrence.

Three types of mafic granulites, namely two pyroxene-plagioclase granutite (MG), two pyroxeneplagioclase-garnet granulite (GMG) and spinel-olivine-plagioclase-two pyroxene granulite (SMG) are exposed at Sunkarimetta, Eastern Ghats belt, India. The marie granulites exhibit a foliation concordant with that in associated granulite facies quartzofeldspathic gneisses. Textural characteristics and mineral chemical data suggest the following mineral reactions: olivine + plagioclase = spinel + orthopyroxene + clinopyroxene (SMG), orthopyroxene + plagioclase = garnet + quartz (GMG), clinopyroxene + plagioclase = garnet + quartz (GMG) and plagioclase + hemoilmenite + quartz = garnet + ilmenite + 02 (GMG). Geothermobarometry indicates maximum P-T conditions of metamorphism at c. 8.5 kbar, 950°C The marie granulites later suffered nearly isobaric cooling to c. 7.5 kbar, 750°C Bulk compositional characteristics suggest that SMG is of cumulate origin. The protoliths of the mafic granulites, emplaced at c. 32 km depth, are probably responsible for thermal perturbation causing granulite facies metamorphism of the enclosing rocks.

The Or-rich part of optically blebby to lamellar mesoperthite crystals from an Adirondack granulite has been shown by TEM to be a lamellar cryptoperthite, composed dominantly of tweed orthoclase. A fluid-absent, two-stage thermal history is proposed to explain the coarse and fine textures, with the cryptoperthite forming by coherent exsolution below ∼350°C probably during uplift. The mechanism was most probably homogeneous coherent nucleation rather than spinodal decomposition. However, cutting the orthoclase cryptoperthite are thin (<1 μm) seams of tartan microcline with sharp boundaries, often defined locally by {110} planes, and micropores. The microcline has replaced orthoclase by solution-redeposition along narrow planes infiltrated by fluid during minor retrogression at T < 350°C Solution-redeposition is a common process in feldspars at T < 500°C potentially accompanied by 18O exchange, because release of elastic strain energy in coherent perthite lamellar boundaries and twin-domain walls, followed by Si, Al ordering, provide driving forces for dissolution and reprecipitation of unstrained, more ordered phases.

The Transdanubian Volcanic Region (TVR) is composed mainly of Pliocene alkali basalts, basanites, olivine basalts and olivine tholeiites, as well as rare nephelinites. The partial melting and genesis of alkali basaltic liquids is a consequence of an upwelling of the upper mantle which also caused thinning of the lithosphere and recent sinking of the Pannonian Basin.

Four different types of lower crustal and upper-mantle xenoliths are found within the TVR: garnet-free and garnet-bearing granulites, clinopyroxenites and spinel lherzolites. We present mineralogical and geochemical data on granulite facies and clinopyroxenite xenoliths from three localities in the Hungarian part of the TVR (Bondoróhegy, Szentbékálla and Szigliget). It is concluded that, whilst the protoliths of the granulite facies xenoliths were tholeiitic igneous rocks and could be part of an ancient crust, the clinopyroxenite xenoliths represent recent underplating and may have formed from an alkali basaltic liquid similar to the host lava. Planar contact relations between clinopyroxenites and spinel lherzolites as observed in composite xenoliths, as well as high Al-contents in clinopyroxenes, point to a high-pressure genesis in the upper mantle for these rocks. In contrast, geobarometrical estimates yielded only a moderate pressure range characteristic of lower crustal levels for the garnet-free granulite xenoliths (7–9 kbar). Nevertheless, two-pyroxene geothermometry yielded high temperatures of equilibration (>900°C) for these xenoliths, probably caused by advective heat transfer connected with underplating and in agreement with the high present-day geothermal gradient of this region. In the Central Range localities only garnet-free granulite xenoliths occur, whereas at the border of the TVR both garnet-free and garnet-bearing granulite facies nodules are found. It is possible that the incoming of garnet is retarded by higher temperatures in the lower crust below the Central Range.

It is also suggested that the difference in seismically measured crustal thickness between the Central Range and adjacent basin areas may be connected with different thermal conditions below these regions and that the seismically defined Moho and the petrological Moho do not necessarily coincide.

In the central granulite belt of Sri Lanka, garnet-pyroxene granulites of granitic and gabbro-noritic composition are the most abundant rock types. The micro-structures and mineral chemistry data prove complete attainment of textural and large-scale chemical equilibrium during and following a phase of extreme penetrative deformation at conditions of the granulite facies (800–850 °C, 5 to 9 kbar). On a local scale, especially along the intergranular system, continued cation exchange decoupling from the early ceasing net-transfer reactions destroyed the near-peak metamorphic equilibrium. The extreme compositional variation of the coexisting ferro-magnesian phases (Fe/(Fe + Mg): gar 0.98−0.65, opx 0.92−0.40, cpx 0.88−0.28) and the near-isothermal conditions of equilibration throughout the studied area enabled examination of the effects of non-ideal mixing in garnet and pyroxenes on the equilibrium constants of reactions used in geothermobarometry, and tests on the quality of commonly applied thermometers/barometers and the validity of activity models adopted in the calibrations. The Sri Lankan data set reveals more or less pronounced compositional dependences for all of the tested gar-opx/gar-cpx Fe-Mg exchange thermometers and the opx + plg ⇌ gar + qtz barometers. Evidently the recommended solution models do not adequately describe the mixing properties of the involved ferro-magnesium mineral phases (garnet, orthopyroxene and clinopyroxene).

The Grenvillian granulite-facies complex on Holsnøy island, Bergen Arcs, W. Norway, has been metamorphosed at eclogite-facies conditions during the Caledonian orogeny (ca. 425 Ma). The granulite-eclogite facies transition takes place along shear zones and fluid pathways. Mineral thermobarometry indicates PT conditions of 800–900°C and 8–10 kbar for the Proterozoic granulite facies metamorphism and 700–800°C and 16–19 kbar for the eclogite-forming event. Quartz in the granulite facies complex contains CO2 fluid inclusions with less than 2.5 mole percent N2; the molar volumes are compatible with the PT conditions of the Proterozoic granulite metamorphism. Quartz in pegmatitic quartz + omphacite and quartz + phengite/paragonite veins coeval with shear-zone eclogites contain N2 ± CO2 fluid inclusions. Combined laser Raman microanalysis and microthermometry show that the least disturbed inclusions have XCO2 = 0.1–0.3, and molar volumes less than 40 cm3/mole, which may agree with the PT conditions during Caledonian high-pressure metamorphism. Younger, low-density N2 and N2-H2O fluid inclusions are the results of decrepitation and redistribution of early inclusions during the retrograde PT evolution of the eclogites.

Detailed electron-microprobe line profiles and small-area compositional maps of zoned garnets in a sample of high-pressure-high-temperature granulite show features inconsistent with commonly applied diffusion models. Larger grains of an early garnet generation have their highest Ca contents in domains away from the rim or inclusions but show a sharp fall in Ca balanced by increased Mg and Fe (and slightly higher XMg) towards inclusions and the rim. In domains with secondary biotite, the sharp decrease in Ca is accompanied by variations in XMg dependent upon proximity to biotite, thus producing one-sided, asymmetric profiles with XMg lower against biotite. As a consequence, rim compositions of the same grain are different on the sides adjacent and away from biotite and there is no relationship between grain size and rim XMg. Such a zoning pattern requires that grain-boundary diffusion is as slow as volume diffusion and implies the absence of a diffusion-enhancing grain-boundary fluid phase during the majority of the rock's high-temperature exhumation history. Diffusion models ignoring this probability could yield either cooling rates that were too fast, or extrapolated ages based on closure temperature models that were too old.

A second garnet generation in the same rock, grown in a Ca-rich domain resulting from kyanite breakdown, has irregularly distributed patches, identified by compositional mapping, containing higher Ca than the first-formed garnet but at lower XMg. Use of such garnet compositions for geothermobarometrical determination of the high-pressure granulite stage would clearly lead to erroneous results. The presence of such contrasting garnet compositions in a granulite-facies rock is clearly evidence of disequilibrium, and further supports the proposition that there was a lack of an effective transport medium even at the mm scale.

U–Pb zircon geochronology and trace element analysis was applied to eclogites and (ultra)high-pressure granulites that occur as volumetrically subordinate rock bodies within orthogneisses of the Orlica-Śnieżnik complex, Bohemian Massif. Under favourable circumstances such data may help to unravel protolith ages and yet-undetermined aspects of the metamorphic evolution, for example, the time span over which eclogite-facies conditions were attained. By means of ion-probe and laser ablation techniques, a comprehensive database was compiled for samples collected from prominent eclogite and granulite occurrences. The 206Pb/238U dates for zircons of all samples show a large variability, and no single age can be calculated. The protolith ages remain unresolved due to the lack of coherent age groups at the upper end of the zircon age spectra. The spread in apparent ages is interpreted to be mainly caused by variable and possibly multi-stage Pb-loss. Further complexities are added by metamorphic zircon growth and re-equilibration processes, the unknown relevance of inherited components and possible mixing of different aged domains during analysis. A reliable interpretation of igneous crystallization ages is not yet possible. Previous studies and the new data document the importance of a Carboniferous metamorphic event at c. 340 Ma. The geological significance of this age group is controversial. Such ages have previously either been related to peak (U)HP conditions, the waning stages of eclogite-facies metamorphism or the amphibolite-facies overprint. This study provides new arguments for this discussion because, in both rock types, metamorphic zircon is characterized by very low total REE abundances, flat HREE patterns and the absence of an Eu anomaly. These features strongly suggest contemporaneous crystallization of zircon and garnet and strengthen interpretations proposing that the Carboniferous ages document late-stage eclogite-facies metamorphism, and not amphibolite-facies overprinting.

The Amalaoulaou Neoproterozoic island-arc massif belongs to the Gourma belt in Mali. The metagabbros and pyroxenites forming the main body of this arc root show the pervasive development of garnet. In the pyroxenites, the latter has grown by reaction between pyroxene and spinel during isobaric cooling. By contrast, in the metagabbros, garnet textures and relations to felsic veins exclude an origin through solid-state reactions only. It is proposed that garnet has grown following dehydration and localized melting of amphibole-bearing gabbros at the base of the arc. The plagioclase-saturated melts represented by anorthositic veins in the metagabbros and by trondhjemites in the upper part of the massif provide evidence for melting in the deep arc crust, which locally generated high-density garnet–clinopyroxene–rutile residues. Garnet growth and melting began around 850 °C at 10 kbar and the tonalitic melts were most probably generated around 1050 °C at P ≥ 10 kbar. This HT granulitic imprint can be related to arc maturation, leading to a P–T increase in the deep arc root and dehydration and/or dehydration-melting of amphibole-bearing gabbros. Observation of such features in the root of this Neoproterozoic island arc has important consequences, as it provides a link to models concerning the early generation of continental crust.

The Larsemann Hills represent a low-pressure granulite terrain with a complex structural-metamorphic history that comprises two parts: 1) granulite facies D1 structures transposed within an early form surface that probably formed at 1000 Ma, and 2) a sequence of progressive, upper amphibolite to lower granulite facies D2–D6 structures that formed during the Pan-African at 500 Ma and were associated with the emplacement of granites and pegmatites with high-grade alteration zones. D2–D6 events comprise an early form surface that has been tightly folded and sheared twice after which it was warped and transected by discrete mylonites. D2–D6 assemblages are associated with decompression textures on D1 peak-assemblages, such as cordierite coronas on garnet + sillimanite in metapelite and plagioclase coronas on garnet in metabasite. This suggests that D2–D6 formed at slightly lower pressures than D1 structures. However, the spatial correlation between the coronas and alteration zones around pegmatitic intrusives indicates that the apparent decompression textures may have partly resulted from transient fluxes in water pressure following melt crystallization. Throughout East Antarctica tectonic provinces have been recognized in which the 1000 Ma tectonothermal events are identified as the main stage in the evolution, and Pan-African events are dismissed as a minor thermal overprint. Although the Larsemann Hills are small in area, they are representative of a great many granulite terrains in East Antarctica, and suggest that great care is needed in the structural-metamorphic analysis of such terrains to ensure the separation of tectonic stages before an interpretation of the tectonic path is attempted.

A varied suite of sapphirine-bearing and quartz-undersaturated granulites, the Taynaya Paragneiss, occur as boudins and enclaves within the c. 2500 Ma old felsic orthogneisses of northern Vestfold Hills. Highly magnesian varieties with XMg (=100x(Mg/(Mg+Fe)) near 95 preserve the assemblage sapphirine + enstatite + spinel, whereas sapphirine + cordierite + sillimanite + corundum occurs in aluminous and feldspathic types with XMg near 90. Phase equilibria and relative thermometry based on Al2O3 solubility in enstatite indicate equilibration of these assemblages at c. 830–880°C and 0.35–0.85 GPa. There is no evidence for the extreme temperatures (1000–1100°C) previously proposed for early metamorphism in the Vestfold Hills, and no indication in the metamorphic assemblages of isobaric cooling prior to 2500 Ma. Two types of metasomatism have altered the bulk rock compositions near boudin and enclave margins. Cordierite rinds locally formed on corundum-sillimanite granulites reflect interaction with magmatic precursors to the enclosing felsic gneisses, as supported by the isotopic and chemical compositions of cordierite channel volatiles. More extensive metasomatism producing schistose phlogopite + sapphirine rinds on all boudins involved infiltration of a LILE-enriched fluid which introduced K2O, H2O, Fe, Rb, Ba and minor Sr along the boudin margins. Whole rock geochemistry of Taynaya Paragneiss unaffected by this metasomatism is consistent with their derivation from evaporitic mudstones, and implies the existence of a basement older than the dominant 2500 Ma orthogneisses.

The long and complex Archaean evolution of the Napier Complex of Enderby Land, characterized by high-grade metamorphism and several strong deformations, is reassessed in the light of new SHRIMPU–Pb zircon dating results bearing on the ages of protoliths and possible regional extents of distinct Archaean tectonothermal events. Initial felsic igneous activity occurred over a significant time interval c. 3800 Ma ago. An age of 2980±9 Ma for the emplacement of charnockite at Proclamation Island might date the oldest tectonothermal event to be recognized in the Napier Complex. An ensuing, very-high grade, previously imprecisely dated tectonothermal event occurred at 2837±15 Ma. U–Pb zircon ages ranging from 2456+8/−5 Ma to 2481±4 Ma date a subsequent, protracted high-grade tectonothermal event. Whereas the ~2840 Ma event is of regional importance in the Amundsen Bay-Casey Bay area, it is possible that the ~2980 Ma event was of only moderate grade, minor importance, or even absent, in that part of the Complex. If so, the apparent trend to very-high temperature metamorphism in the Tula and Scott mountains compared with the Napier Mountains may reflect two distinct metamorphic events rather than a simple baric and thermal gradient. The oldest crustal component in the Napier Complex appears to have been of igneous derivation. Zircon populations in paragneisses at Mount Sones are similar to those in the nearby orthogneisses, which therefore may have been basement. Another paragneiss, in the Casey Bay area, yields no zircons older than 2840 Ma, probably indicating that pre-3000 Ma crust, which is now located nearby, was not exposed at the time of sedimentation there. The isotopic data are quite complex, particularly in rocks that experienced postcrystallization metamorphic temperatures of 1000°C or more. It is postulated that this complexity, which was largely the product of migration of radiogenic Pb within the zircon grains in ancient times, and produced local excesses of this element with respect to its parent U, was caused by volume diffusion at these abnormally high regional crustal temperatures.

The high-dT/dP-type Hidaka Metamorphic Belt in Hokkaido, northern Japan, represents a tilted crustal section of a magmatic arc of Tertiary age. The highest metamorphic grades reached are granulite facies, and the syn-metamorphic granitic rocks are widely distributed in this metamorphic terrane. The granitic rocks are mainly tonalitic and granodioritic in composition, and are classified into peraluminous (S-type) and metaluminous (I-type) granitoids. A large amount of pyroxene-bearing S-type tonalites (garnet-orthopyroxene tonalite) is distributed in the Niikappu river region in the northern part of the Hidaka Metamorphic Belt. Pyroxene-bearing I-type tonalite (two-pyroxene hornblende tonalite) bodies are also distributed in this area.

The pyroxene-bearing tonalites are classified into several sub-types on the basis of their field occurrence, texture, mineral assemblage and geochemical features. Homogeneous IH- and SH-type tonalite are thought to represent original magmas, i.e. those which have been generated by partial melting of mafic metamorphic rocks and pelitic-psammitic metamorphic rocks, respectively. Model calculations assuming batch partial melting indicate that possible restites are garnet-two-pyroxene mafic granulite for IH-type and garnet-orthopyroxene aluminous granulite for SH-type. The unexposed lowermost crust of the ‘Hidaka crust’ is thought to be composed of garnet-two-pyroxene mafic granulite, garnet-orthopyroxene aluminous granulite and metagabbros.

The Hidaka Metamorphic Belt (HMB) in Hokkaido, northern Japan, consists of tilted metamorphic layers of an island-arc type crust from lower (granulite facies) to upper (very low-grade metasedimentary) horizons. Abundant granitic rocks, mainly S-type tonalites of crustal origin, intrude various metamorphic layers and are classified into four depth types, namely upper, middle, lower and basal. The basal orthopyroxene-garnet (S-type) tonalities were intruded into granulite facies country rocks. Textural and compositional evidence from minerals in the basal tonalite indicates that the crystallisation sequence is Grt-Pl-Opx-Bt-Qtz-Crd-Kfs, and that crystallisation took place at about 600 MPa and 900°C-700°C.

Some crystallisation experiments were carried out in an internally heated pressure vessel, using the basal tonalite, under the conditions of 300 and 600 MPa, 700-900°C, and with 0-20 wt% H2O, respectively. The results show that the primary S-type tonalite magma was at a temperature above 900°C and contained 3-4 wt% H2O at the beginning of crystallisation. In order to study the influence of normative orthoclase content on orthopyroxene crystallisation, some starting materials also included 15, 20 and 25% normative orthoclase, by adding KAlSi3O8 gel to the rock powder. Normative orthoclase content has an influence on the subliquidus crystallisation limit of orthopyroxene.

The changes in P-T conditions and chemical composition of the magma during ascent would generate the sequence from the basal to upper S-type granite. Opx-free S-type granitic magma can be generated from lower crustal Grt-Opx S-type granitic magma, by differentiation with falling magmatic temperature.

The Steel Mountain terrane of the southern Long Range Mountains forms a fault-bounded massif of (meta)plutonic rocks including the Disappointment Hill complex (DHC), a sequence of granulite-facies lithologies containing charnockite emplaced at 1498 Ma (U-Pb, zircon). Quartzofeldspathic gneiss of the DHC contains garnet + biotite + orthopyroxene ± cordierite assemblages indicative of metamorphic P–T conditions of ca 750°C and 400 MPa. The relatively high thermal gradient (ca 70°C km−1) inferred for the DHC is attributed to a magmatic heat source.

On grounds of lithology, age and metamorphic grade, the DHC correlates to granulites of the Long Range Inlier (LRI) exposed farther north. Both complexes occur in blocks thrust westward over Taconic allochthons capped by ophiolite nappes. The block containing the DHC, however, preserves younger cover rocks, suggesting that it originated at a higher structural level than the LRI. This model is supported by lower pressure estimates for the DHC relative to the LRI (400 MPa vs 500–800 MPa). The DHC forms a link between Grenvillian rocks of the northern Long Range of Newfoundland and those of Cape Breton Island. The structural position of these massifs suggests that their emplacement was a post-Taconic event.

Graphite bodies of economic importance occur in the Eastern Ghats migmatite complex of Orissa, India, which consists of sillimanite-rich gneiss (khondalite), calc-silicate granulite, basic (pyroxene) granulite and acidic gneiss palaeosomes and a variety of quartzofeldspathic neosomes and pegmatite veins. There is more graphite in migmatised khondalite and calc-silicate granulite than in their unmigmatised counterparts and it is common at pegmatite-country rock margins. Lodes of graphite are structurally controlled by fold hinge zones, necks of boudins and along the dominant foliation in rocks that show the effects of polyphase deformation. Faults, fractures and joints also act as structural controls. The richest lodes are located where there is the coincidence of several lithological and structural features.

The graphite occurs in graphite-rich schists and gneisses, as veins and as disseminated flakes along grain boundaries and in microfractures and cleavages. It is present in all rock types except pegmatites emplaced after the D4 deformational phase, and is localised in structures developed during the D1, D2, D3 and D4 phases. Most of the bodies of graphite are lenticular and show pinch and swell characters. Fourteen textural and microstructural habits have been recognised and are described with many of the features of fabric, such as intergrowths, inclusions and kinks being particularly well shown under reflected light.

Methanation of carbonate minerals is considered the most likely initial stage in the formation of the carbon with subsequent pyrolysis of the methane being the process of graphitisation. While the possibility of the carbon being either of sedimentary derivation orfrom igneous-derived CO2 cannot be ruled out, there is no convincing evidence for such sources. Remobilisation of graphite following its formation by pyrolysis of methane in structurally controlled low pressure zones is the dominant mechanism of concentration. Thefabric features point to the graphite having moved as a solid phase along open spaces inthe gangue minerals while still maintaining its crystallinity, and having been deformed in the process. The effects of remobilisation apparently have obliterated evidence relating to other methods of concentration.

The existence of a basement of granulite beneath the Midland Valley is supported by investigations of inclusions in volcanic rocks and the geophysical studies of the LISPB experiment. To establish age constraints for this basement, a compilation is presented of available Rb–Sr whole-rock, common lead, U–Pb zircon and Sm–Nd radiometrie data for crystalline rocks in Scotland from the earliest recognised crust (c. 2900 Ma) to 380 Ma (“end” of Caledonian orogeny) including xenoliths in volcanic vents and boulders in conglomerates.

For rocks within the Midland Valley, isotopic data provide four lines of evidence. (1) An upper intercept U–Pb age of c. 1700 Ma for detrital zircons from a lower Palaeozoic greywacke from Dalmellington corresponds to a late stage of the Laxfordian orogenic episode (early Proterozoic) with possibly some overprinting during the Grenvillian episode (mid Proterozoic). (2) The common lead composition of the Distinkhorn granite suggests the participation of early Proterozoic basement during granite emplacement. (3) For xenoliths from the Carboniferous Partan Craig vent, one gives a Sm–Nd CHUR model age of 1180 ± 55 Ma, a second yielded a Sm–Nd garnet—potassium feldspar age of 356 ± 6 Ma and an upper intercept U–Pb age from zircons from the third is c. 2200 (± 240) Ma; for xenoliths from other vents, an Rb–Sr whole-rock isochron of 1101 ± 63 Ma and an Sm–Nd model age of c. 1100 Ma arerecorded. (4) A linear array corresponding to an apparent age of 770 ± 180 Ma on a Pb–Pb isochron diagram for Tertiary igneous rocks of Arran points to an underlying basement of late Precambrian orthogneiss.

The existence of basement made of products of the Grenvillian episode, or predominantly so, similar to the basement N of the Highland Boundary fault, is not inconsistent with the available evidence. However, zircons and other rock components appear to have an ultimate Lewisian provenance. At least in parts, there is also a strong late Proterozoic imprint. Further studies are required for an unequivocal solution.

Charnockite and homophanous leptynite are two quartz–feldspar neosomes in the late Archaean granulite-migmatite Eastern Ghats terrane of Orissa, India. Three phases of deformation and metamorphism are recognised to have preceded a late phase, or phases in which deformation was not intense. An early granulite facies event (D1–M1) produced basic granulites and khondalite (sillimanite-garnet aluminous paragneiss). A second event (D2–M2) involved some retrogression but temperatures and pressures remained high (possibly c. 750°C—>5 kb). D3–M3 was associated with the development of open folds (F3) with axial planar shear zones in pinched antiforms; temperatures and pressures were also falling (c. 650°C— 4kb), but the shear zones acted as a control on the development of firstly homophanous leptynite, and secondly charnockite. In both cases, neosomes of quartz and potassium feldspar have myrmekitic textures and intergranular occurrence. The palaeosome became strained and garnet–biotite and garnet–biotite–clinopyroxene ± orthopyroxene mineral assemblages were formed in association with the development, respectively, of homophanous leptynite and charnockite. The persistence of straining in the palaeosome and the presence of poikilitic textures indicate that this typical assemblage does not represent one in thermodynamic equilibrium. This has important consequences for geothermobarometry.

The structural control on neosome development reflects a regional characteristic where shear zones are the site of peralkaline plutons, fenitisation, carbonatites and epigenetic graphite development. The peculiar features of charnockite are seen as just one of several aspects related to the fluxing of hot CO2-dominated fluids from either the deep crust or mantle during the late Archaean development of the Indian craton.

Late Palaeozoic alkalic basalts in and around the Midland Valley of Scotland contain a wide variety of ‘plutonic’ xenoliths. Pyroxene-rich ultramark xenoliths (wehrlites, clinopyroxenites and garnet pyroxenites) may be representative of younger components within a dominantly peridotitic upper mantle represented by ubiquitous magnesian peridotite xenoliths. Glimmerites and other biotite-rich ultramafic xenoliths are probable samples of metasomatised upper mantle facies.

Xenoliths composed mainly of plagioclase, clinopyroxene ± orthopyroxene ± magnetite are widespread. These pyroxene granulites may typify the lower crustal layers. Garnet granulites are rare; such rocks may formerly have been important with loss of garnet occurring through retrograde metamorphism. Anorthositic xenoliths are relatively common. The lower crust may consist largely of anhydrous rocks, of gabbroic to anorthositic composition, ccurring as stratiform bodies of metacumulates.

Other xenoliths of igneous origin include tonalitic and trondhjemitic gneisses. Although these may play some role in the lower crust, they may be more abundant in the mid-crustal domains underlying the deformed upper Precambrian and lower Palaeozoic supracrustal strata. Xenoliths of quartzofeldspathic, granulitic gneisses containing garnet ± sillimanite ± rutile are also of widespread occurrence; many of these are of metasedimentary provenance and are regarded as being derived from the mid-crustal layers beneath the Southern Highlands, Midland Valley and Southern Uplands and their Irish counterparts.