Methyl bromide is a common fumigant for effective weed control in polyethylene-mulched vegetable crops. However, the ban on methyl bromide in the United States has created a need to find a suitable alternative. This study investigated the herbicidal efficacy of phenyl isothiocyanate (ITC) as a methyl bromide alternative for weed control in polyethylene-mulched bell pepper during 2006 and 2007. Six rates of phenyl ITC (0, 15, 75, 150, 750, 1,500 kg ha−1) under low-density polyethylene (LDPE) or virtually impermeable film (VIF) mulch were tested against yellow nutsedge, Palmer amaranth, and large crabgrass. Additionally, a standard treatment of methyl bromide/chloropicrin (67 : 33%) at 390 kg ha−1 under LDPE mulch was included for comparison. VIF mulch provided no advantage over LDPE mulch in either improving weed control or marketable yield in bell pepper. Unacceptable pepper injury (≥ 60%) occurred at the highest phenyl ITC rate of 1,500 kg ha−1 at 2 WATP in both years, regardless of mulch type. Higher bell pepper injury was observed in 2006 (≥ 36%) than in 2007 (≤ 11%) at 750 kg ha−1 of phenyl ITC. The lower injury in 2007 could be attributed to aeration of beds 48 h prior to transplanting. Regardless of mulch type, phenyl ITC at 2,071 (± 197) and 1,655 (± 309) kg ha−1 was required to control yellow nutsedge, Palmer amaranth, and large crabgrass equivalent to methyl bromide in 2006 and 2007, respectively. Bell pepper marketable yield at all rates of phenyl ITC was lower than methyl bromide in 2006. In contrast, marketable yield in phenyl ITC at 750–kg ha−1 was equivalent to methyl bromide in 2007. It is concluded that phenyl ITC should be applied at least 4.2 times higher rate than methyl bromide for effective weed control, and bed aeration is required to minimize crop injury and yield loss. Additional research is needed to test phenyl ITC in combination with other weed control strategies to obtain effective weed control with acceptable crop safety.

Field studies were conducted to examine the dissipation of three soil-applied residual herbicides for bare soil compared with soil under low-density polyethylene (LDPE) mulch in 2003 and 2004. Studies indicated that halosulfuron and S-metolachlor dissipation was more rapid for bare soil than soil under LDPE mulch. Sulfentrazone dissipation from bare soil was equal to soil under LDPE mulch in 2003. However, sulfentrazone dissipation in 2004 was more rapid for soil under LDPE mulch than for bare soil. The order for half-life, defined as time for 50% dissipation (DT50), varied by herbicide and soil exposure. Averaged across 2003 and 2004, metolachlor DT50 was 2 d, halosulfuron 7 d, and sulfentrazone 16 d for bare soil. S-metolachlor DT50 was 4 d, halosulfuron 10 d, and sulfentrazone 13 d for soil under LDPE mulch. Correlation between quantified herbicide dissipation and bioassay for bare soil compared with soil under LDPE mulch in 2004 indicated that assay species root dry weights were negatively correlated with herbicide concentration. Data indicated that S-metolachlor and sulfentrazone bioassays, with oat and cotton, respectively, could be used to assess the level of dissipation for each herbicide.

Isothiocyanates (ITCs) were evaluated as an alternative to methyl bromide (MeBr) for control of Palmer amaranth, large crabgrass, and yellow nutsedge; reduction of tuber density; and increase in marketable tomato yield in low density polyethylene (LDPE)-mulched tomato production. Allyl ITC was applied at 450, 600, and 750 kg ai ha−1; metham sodium (methyl ITC generator) was applied at 180, 270, and 360 kg ai ha−1; and MeBr plus chloropicrin (mixture of MeBr and chloropicrin at 67 : 33%, respectively) was applied at 390 kg ai ha−1. A nontreated weedy check was included for comparison. There was no injury to tomato plants following allyl ITC, metham sodium, or MeBr application. Allyl ITC at 750 kg ha−1 or metham sodium at 360 kg ha−1 controlled Palmer amaranth ≥ 79%, large crabgrass ≥ 76%, and yellow nutsedge ≥ 80% and was comparable to the weed control with MeBr. Highest rates of allyl ITC and metham sodium reduced yellow nutsedge tuber density (≤ 76 tubers m−2) comparable to the MeBr application. Total marketable tomato yield was ≥ 31.6 t ha−1 in plots treated with allyl ITC at 750 kg ha−1 or metham sodium at 360 kg ha−1. Marketable tomato yield from the highest rate of allyl ITC or metham sodium were similar to the yield (38.2 t ha−1) with MeBr treatment. Therefore, allyl ITC at 750 kg ha−1 and metham sodium at 360 kg ha−1 are effective alternatives to MeBr for Palmer amaranth, large crabgrass, and yellow nutsedge control in LDPE-mulched tomato.

Methyl bromide (MeBr), classified as a Class I ozone-depleting substance, has been banned for ordinary agricultural uses. Weed control in commercial bell pepper production is complicated by the ban on MeBr and the lack of other available and effective soil fumigants. A field study was conducted to evaluate the effectiveness of allyl isothiocyanate (ITC) and metam sodium (methyl ITC generator) as MeBr alternatives for control of Palmer amaranth, large crabgrass, and yellow nutsedge; and for increasing marketable yields in low-density polyethylene (LDPE) –mulched bell pepper. Allyl ITC was applied at 450, 600, and 750 kg ha−1; metam sodium was applied at 180, 270, and 360 kg ha−1; and MeBr plus chloropicrin (67% and 33%, respectively) was applied at 390 kg ha−1. Allyl ITC and metam sodium did not injure bell pepper. Allyl ITC at 750 kg ha−1 or metam sodium at 360 kg ha−1 controlled Palmer amaranth (≥ 83%), large crabgrass (≥ 78%), and yellow nutsedge (≥ 80%) comparably to MeBr. Yellow nutsedge tuber density was ≤ 84 tubers m−2 in plots treated with the highest rate of allyl ITC and metam sodium and was comparable to the tuber density in MeBr-treated plots. Although allyl ITC at 750 kg ha−1 controlled weeds comparable to MeBr, total marketable bell pepper yield with allyl ITC was lower than the yield with MeBr. Conversely, total marketable bell pepper yield with the highest rate of metam sodium (53.5 ton ha−1) was equivalent to the yield (62.5 ton ha−1) in plots treated with MeBr. In conclusion, metam sodium at 360 kg ha−1 is an effective MeBr alternative for weed control in LDPE–mulched bell pepper.