Recent pedological evidence of the widespread distribution of beidellites in soils indicates the need for a greater knowledge of the effect of charge location on the microstructural organization of Na+ smectite in gels. After equilibration at a suction pressure of 3.2 kPa before and after desiccation, TEM observations showed large differences between a beidellite and both a low and high charge montmorillonite. Monolayers were rare; individual layers were instead organized in particles with larger interparticle distances. This has implication for theories relating swelling pressures to interlayer distances or surface areas and implies the need for a geometrical approach to the study of swelling in smectites. Location of isomorphous substitution in the tetrahedral sheet of smectites results in an increased lateral extension of overlapping layers. This was reflected in a greater capacity to rehydrate after desiccation. Increased number of layers in particles were found with increasing surface charge density. The geometric organization of the particles is critical to the understanding of the ability of Na+ smectite to hold water against an applied suction.

Smectite was reacted at several temperatures between 200°C and 500°C to produce interstratified illite/smectite (I/S) with different proportions of expandable layers. Dispersed and sedimented products were examined using a transmission electron microscope. Particle size and aspect ratio showed no systematic change as a function of reaction extent during R0 illitization. However, particles exhibited rounded edges during the early stages of the reaction, suggesting some dissolution of primary smectite. Additionally, increasing particle contrast in the electron beam suggests thickening of particles with increasing reaction extent. The thickening of particles is thought to be produced by the nucleation and precipitation of secondary illite layers on primary smectite layers. In the most extensively reacted I/S, particles have become aggregated into clumps or quasicrystals by lateral growth of illite layers. Internal uniformity of crystallographic alignment of individual growing crystals within each aggregate was reflected in the increasing frequency of 60° and 120° interfacial angles within each aggregate. In highly illitic I/S, these aggregates took on an overall euhedral form and became crystallographically contiguous, producing single crystal electron diffraction patterns.

This article focuses on the interrelationship between two events taking place simultaneously in Odysseus’ megaron: Phemius’ performance and the conversation between Telemachus and Athena. I argue that at Hom. Od. 1.298–302 Athena, in her mention of Orestes’ kleos, refers directly to Phemius’ song that Telemachus can hear from where he is sitting. This reading sheds new light on the characters’ receptions of Phemius’ song. Between the well-known contrasting responses of the nearest and the farthest audiences – the suitors’ silence and Penelope's over-reaction – stands Athena's cognitively constructive use of it, by which the goddess attempts to establish a shared understanding with Telemachus, whose kleos is one of the main concerns of her visit to Ithaca.

This paper is concerned with the syntactic representation of inner aspect in Hungarian. We contribute to the extant research on inner aspectual markers by providing an analysis of entailed versus implied telicity as well as the (non)maximality effects with which telic predicates are associated. Although we focus on the grammar of Hungarian, we also draw parallels between typologically different languages like Finno-Ugric (e.g. Hungarian and Finnish) and Germanic (e.g. English) regarding their inner aspectual marking strategies, and the interaction of inner aspect and case assignment.

Scanning electron microscopy, coupled with energy-dispersive X-ray spectroscopy (EDS), is a powerful tool used in many scientific fields. It can provide nanoscale images, allowing size and morphology measurements, as well as provide information on the spatial distribution of elements in a sample. This study compares the capabilities of a traditional EDS detector with a recently developed annular EDS detector when analyzing electron transparent and beam-sensitive NaCl particles on a TEM grid. The optimal settings for single particle analysis are identified in order to minimize beam damage and optimize sample throughput via the choice of acceleration voltage, EDS acquisition time, and quantification model. Here, a linear combination of two models is used to bridge results for particle sizes, which are neither bulk nor sufficiently thin to assume electron transparent. Additionally, we show that the increased count rate obtainable with the annular detector enables mapping as a viable analysis strategy compared with feature detection methods, which only scan segmented regions. Finally, we discuss advantages and disadvantages of the two analysis strategies.

This paper investigates the use of modal particles in spoken Dutch imperatives. Two types of particles are differentiated: mitigating, which are often used as a politeness strategy, and reinforcing, which add extra force to the utterance (Vismans 1994). Our findings show that in Netherlandic Dutch, the use of mitigating particles is determined by the type of occupation that the speaker has: Speakers in service-oriented occupations use mitigating particles significantly more often than speakers in nonservice-oriented occupations, and it is argued that this is a function of their need to be more polite in their role as a service provider. Since the data do not come from the speakers’ workplace interactions but from informal conversations with friends and family, it is suggested that speech patterns of speakers’ professional and private language practices influence each other. The effect of occupation is not observed in Belgian Dutch, however, where mitigating particles are significantly less frequent. Moreover, an important methodological consideration arises from this analysis: There is the need for researchers to examine the data beyond the standard sociolinguistic categorizations made available by large corpora.

In this study, a micromechanics model has been proposed for predicting the effects of particle size and aggregation on elastic properties of nanocomposites, and the interphase between the particle and matrix is also taken into account. Inherent characteristics of nanoparticle, such as small size and high surface area ratio, make nanoparticle in a state of unstable energy and easy to agglomerate in matrix. The analytical expressions for the effective elastic modulus of nanocomposites are derived, which can consider the effect of particle agglomeration. The dispersion state or degree of agglomeration of nanoparticle and the thickness and stiffness of interphase are known to have a significant influence on nanocomposites. The results show that the increase of particle radius and agglomeration volume fractions reduces the elastic stiffness of nanocomposites. Moreover, the composite reinforcement can be improved by increases of interphase thickness and stiffness.

Interaction of vortex rings with solid is an important research topic of hydrodynamic. In this study, a multiple-relaxation time (MRT) lattice Boltzmann method (LBM) is used to investigate the flow of a vortex ring impacting spheroidal particles. The MRT-LBM is validated through the cases of vortex ring impacting a flat wall. The vortex evolution due to particle size, the aspect ratio of a prolate particle, as well as Reynolds (Re) number are discussed in detail. When the vortex ring impacting a stationary sphere, the primary and secondary vortex rings wrap around each other, which is different from the situation of the vortex ring impacting a plate. For the vortex ring impacting with a prolate spheroid, the secondary vortex ring stretches mainly along the long axis of the ellipsoid particle. However, it is found that after the vortex wrapping stage, the primary vortex recovers along the short axis of the particle faster than that in the long axis, i.e., the primary vortex ring stretches mainly along the short axis of the particle. That has never been address in the literature.

This study was conducted to investigate the effect of stage of maturity at harvest on the intake of grass silage, eating and ruminating activity and the distribution of faecal particle size in ewes during late pregnancy. A total of 18 Swedish Finull × Dorset 85 ± 8 kg (mean ± s.d.) ewes bearing twins were randomly assigned to three dietary treatments 6 weeks before lambing. The treatments included ad libitum feeding with early harvested (EH), medium harvested (MH) or late harvested (LH) primary-growth grass silage with 45%, 58% and 63% NDF on a dry matter (DM) basis, respectively. Intake and chewing activity were recorded and faeces were sampled over 4 continuous days for each individual ewe. The faeces samples were washed in nylon bags, freeze dried and sieved with pore sizes from 2.4 mm to 0.1 mm; particles less than 0.1 mm in size were also collected. Subsamples of each sieving fraction were scanned and the dimensions of the individual particles in each sieving fraction were measured by image analysis. In addition, the number of particles longer than 7 mm was counted from the particles retained on a sieve with a pore size of 2.4 mm using a simple wet sieving technique. The time spent eating and ruminating per kg of DM intake was affected by the stage of maturity at harvest; it was shorter in ewes fed EH compared with ewes fed MH and LH (P < 0.05). In comparison with feeding LH, feeding EH resulted in the retention of a larger proportion of particles in the lower and upper sieve fractions (<0.2 mm and >1 mm, respectively, P < 0.01), a smaller mean particle size (P < 0.05) and a smaller mean particle width in faeces (P < 0.01). The results from the simple wet sieving technique confirmed the results from dry sieving and image analysis, showing a higher number of large particles in faeces from ewes fed the EH compared with the ewes fed the MH and LH (P < 0.001). In conclusion, the distribution of faecal particle size might be considered as a footprint of the characteristics of forage fibre eaten by ewes.

This study is concerned with the relationship between carbonisation conditions and properties of the resultant bagasse char, and the challenging proposal for the use of fine bagasse char particles as high-performance solar light collectors. Bagasse char was obtained by carbonising raw bagasse at temperatures of 200–900°C for three hours in nitrogen (N2) gas. Characterisation of the resultant bagasse char was performed by elemental analysis (EA), scanning electric microscope (SEM) observation, estimation of colour, nominal bulk density and evaluation of specific surface area and pore structure by N2 gas absorption/desorption. The most typical property of the resultant bagasse char is its unique pore structure, which is clear in SEM observation. The largest specific surface area of bagasse char in this study was about 600 m2/g, which is as large as commercial activated carbon materials. Macro-, meso- and micro-porous structures in the bagasse char induce many important characteristics, such as increased hydrophilicity, very low bulk density and excellent light absorption and accumulation. We also suggest the use of bagasse char as an excellent heat insulation material. The energy used for air conditioning in a private house or office building can be decreased by more than 50–60% by use of this insulator on the roof or walls.

A high quality X-ray spectrum image of a 3.3 μm diameter sphere of K411 glass resting on a copper substrate was collected at 25 keV. The same sample configuration was modeled using the NISTMonte Monte Carlo simulation of electron and X-ray transport as is integrated into the quantitative X-ray microanalysis software package DTSA-II. The distribution of measured and simulated X-ray intensity compare favorably for all the major lines present in the spectra. The simulation is further examined to investigate the influence of angle-of-incidence, sample thickness, and sample diameter on the generated and measured X-ray intensity. The distribution of generated X-rays is seen to deviate significantly from a naive model which assumes that the distribution of generated X-rays is similar to bulk within the volume they share in common. It is demonstrated that the angle at which the electron beam strikes the sample has nonnegligible consequences. It is also demonstrated that within the volume that the bulk and particle share in common that electrons, which have exited and later reentered the particle volume, generate a significant fraction of the X-rays. Any general model of X-ray generation in particles must take into account the lateral spread of the scattered electron beam.

This paper presents a new planar particle that shows negative effective permittivity under irradiation by an electromagnetic wave. The mutual coupling between the couples of these particles is studied in particular. The response of this particle sensitive to an electric field is strongly anisotropic. The particle is aimed to be used to compose an isotropic epsilon-negative metamaterial in two forms. First, a unit cell of the metamaterial consists of a cube bearing six particles on its faces, located with specific orientations. The experiments showed that this unit cell is suitable for manufacturing an isotropic epsilon-negative metamaterial obtained by arranging these cells in a 3D cubic periodic system. The second form of an epsilon-negative metamaterial with an isotropic response consists of the planar particles themselves, distributed quasi-randomly, composing a 2D system and/or of particles placed in spherical shells and distributed fully randomly in a hosting material forming a 3D system. The isotropy of these systems was verified by measurements in a rectangular waveguide.

Concernant la pollution particulaire des ambiances, qu'elles soient habitables ou destinées à accueillir une population parfois importante (telles que les grands halls publics, les gares ou lieux de vie), c'est essentiellement l'étude du dépôt des particules ou de leur migration dans l'air, qui a le plus souvent été traité dans la bibliographie. Pour l'instant trop peu d'études ont été consacrées aux aspects de la remise en suspension des particules car de façon générale, qu'il s'agisse d'habitations ou de grands volumes ouverts au public, les vitesses de l'air restent relativement faibles et permettent difficilement d'"arracher" les particules déposées. C'est dans cet esprit que nous avons élaboré en cellule-test, un protocole expérimental pour mettre en évidence ce phénomène. Nos expérimentations permettront une quantification de la contribution de l'activité humaine (déplacement par la marche) dans la remise en suspension de particules initialement sur le plancher. Le paramètre sur lequel nous nous sommes focalisés ici concerne la rugosité du revêtement posé au plancher (même nature mais de rugosité différente). Nos résultats permettront d'une part de caractériser le facteur humain comme une "pseudo-source" de pollution particulaire, et d'autre part, de l'inclure dans la caractérisation particulaire des ambiances.

A radioactive particle embedded in a sediment collected from the Irish Sea was examined with spectrometric methods to understand the potential bioavailability of its constituents. Images of the particle surface were acquired in the backscattering mode by scanning electron microscopy. The elemental composition of the particle surface layer was measured using energy dispersive (SEM-EDX) and wavelength dispersive (SEM-WDX) X-ray spectrometers. The investigation showed that the sample consists of a calcite matrix in which uranium is present in the form of separate inclusions. The diameter of U inclusions was less than 10 μm. Synchrotron radiation based X-ray fluorescence in confocal geometry (confocal μ-XRF) was used to determine the spatial distribution of elements in the particle. Three-dimensional reconstructions of the Ca, Cr, Mn, Fe, Zn, Sr, Ba, Pb, and U distributions were performed. The oxidation state of uranium in the different inclusions was determined by synchrotron radiation based X-ray absorption in confocal geometry (confocal μ-XANES). The isotopic composition of uranium was measured by secondary ion mass spectrometry. The results revealed that uranium was depleted in 235U. Pu and other actinides were not detected.

In this paper, I take a closer look at a set of observations concerning word order and co-occurrence restrictions on verb-particle constructions, benefactive double object constructions and resultative constructions in Norwegian. While a particle can co-occur with both a beneficiary DP and a resultative AP, beneficiary DPs and resultatives cannot co-occur at all. I give an analysis in terms of the system proposed in Ramchand (2006), where I argue that the co-occurrence restrictions follow from the syntactic structure assumed together with independent properties of adjectival resultative constructions and verb-particle constructions.