The microstructure of carbon quantum dots (CQDs) has a great influence on their fluorescence properties. Here, different microstructures of CQDs were synthesized by the selective oxidation of graphitized activated carbon using HNO3/HClO4 as the oxidant. We characterized the microstructure and surface chemistry of the CQDs, and the results show that the degree of graphitization of activated carbon has a significant effect on the structure and fluorescence properties of the obtained CQDs. The fluorescence of the CQD solution can be tuned from yellow to green by regulating the degree of graphitization of the activated carbon by heat treatment at high temperature (up to 2500 °C). Moreover, the increased degree of graphitization of the raw carbon precursor is beneficial for significantly reducing the fluorescence self-absorption quenching of the concentrated CQD solution. Importantly, the as-prepared CQDs have no cytotoxicity and can be used as bioimaging agents.

The emergence of miniature light sources such as the vertical-cavity surface-emitting laser (VCSEL) is poised to advance the information age. The development of VCSELs has stimulated a wide range of materials research into epitaxial growth and device-fabrication technologies. In this article, current and emerging applications that are guiding the commercial development of VCSELs are first considered, followed by discussions of the VCSEL epitaxial structure and fabrication technologies. This brief overview will also mention recent efforts aimed at achieving long-wavelength VCSELs grown on GaAs substrates, as well as approaches for achieving a high modulation rate.