We investigate the degree profile and total weight in Apollonian networks. We study the distribution of the degrees of vertices as they age in the evolutionary process. Asymptotically, the (suitably-scaled) degree of a node with a fixed label has a Mittag-Leffler-like limit distribution. The degrees of nodes of later ages have different asymptotic distributions, influenced by the time of their appearance. The very late arrivals have a degenerate distribution. The result is obtained via triangular Pólya urns. Also, via the Bagchi–Pal urn, we show that the number of terminal nodes asymptotically follows a Gaussian law. We prove that the total weight of the network asymptotically follows a Gaussian law, obtained via martingale methods. Similar results carry over to the sister structure of the k-trees, with minor modification in the proof methods, done mutatis mutandis.