The decomposability number of a von Neumann algebra $\mathcal{M}$ (denoted by $\text{dec}\left( \mathcal{M} \right)$) is the greatest cardinality of a family of pairwise orthogonal non-zero projections in $\mathcal{M}$. In this paper, we explore the close connection between $\text{dec}\left( \mathcal{M} \right)$ and the cardinal level of the Mazur property for the predual ${{\mathcal{M}}_{*}}$ of $\mathcal{M}$, the study of which was initiated by the second author. Here, our main focus is on those von Neumann algebras whose preduals constitute such important Banach algebras on a locally compact group $G$ as the group algebra ${{L}_{1}}(G)$, the Fourier algebra $A(G)$, the measure algebra $M(G)$, the algebra $LUC{{(G)}^{*}}$, etc. We show that for any of these von Neumann algebras, say $\mathcal{M}$, the cardinal number dec$(\mathcal{M})$ and a certain cardinal level of the Mazur property of ${{\mathcal{M}}_{*}}$ are completely encoded in the underlying group structure. In fact, they can be expressed precisely by two dual cardinal invariants of $G$: the compact covering number $\kappa (G)$ of $G$ and the least cardinality $\mathcal{X}(G)$ of an open basis at the identity of $G$. We also present an application of the Mazur property of higher level to the topological centre problem for the Banach algebra $A{{(G)}^{**}}$.