This Paper reveals a novel single layer five band frequency selective surface (FSS). Novelties of the proposed FSS lie in its five closely spaced stop bands at 2.4, 3.38, 4.82, 6.32, and 7.75 GHz as well as the reduced single layer structural thickness (0.0016 λ0) and the miniaturized unit cell size (0.0656 λ0) at lower resonant frequency as compared to the existing multiband FSS. The unit cell structure consists of six octagonal concentric interconnected loops. Adjacent loop interconnection technique reduces the cell size by more than 44%. Furthermore, arrow-shaped rings are also introduced on each corner of the outermost octagonal loop, and using this technique approximate 23% cell miniaturization can be achieved. In addition, the proposed FSS exhibits excellent angular stability.