Fifty six sediment cores were collected along a 100 km longitudinal transect of the Thames estuary. Total Hg ranged from 0.01 to 12.07 mg/kg, with a mean of 2.10 mg/kg (n=351). Concentrations of the toxic metal decreased downstream from London to the outer estuary and were positively correlated to total organic carbon (TOC) content. Many Hg profiles showed a clear rise, peak and fall, reflecting changing anthropogenic input through time. Surface concentrations averaged 1.27 mg/kg, confirming the effectiveness of recent environmental legislation and improved river management. Sediments at >40 cm depth from London reaches of the river (Waterloo Bridge, Cuckolds Point (Rotherhithe), Butlers Wharf (Tower Bridge), Millwall, Deptford and Millennium Dome) were highly contaminated, with levels of Hg of >7 mg/kg. The outer Thames had lower Hg, with the exception of Rainham, Crossness and Cliffe. Benchmarking against UK guidelines for the disposal of dredged material revealed that 88 samples from 21 sites exceeded the 3 mg/kg criteria (unsuitable for disposal at sea); 173 fell between 0.3 and 3 mg/kg (further assessment required); and 90 were of no concern. Using Hg as a generic pollution marker, the tidal Thames is one of the world's most contaminated river–estuarine sediment systems.

This study uses marine geophysical data, principally single-beam and high-resolution multibeam echo sounder bathymetry, combined with seismic sub-bottom profiles, and existing Quaternary geological information, to map the glacial geomorphology of a large area of seafloor (∼50,000 km2) on the continental shelf around northern Scotland, from west of Lewis to north of the Orkney Islands. Our new mapping reveals the detailed pattern of submarine glacial landforms, predominantly moraines, relating to ice sheets that covered Scotland and much of the continental shelf during the Late Weichselian glaciation and earlier in the Mid to Late Pleistocene. The reconstructed retreat pattern based on geomorphological evidence highlights the large number of different retreat stages and the asymmetric, non-uniform evolution of this ice sheet sector during Late Weichselian deglaciation. Time-equivalent ice-front reconstructions show that marine sectors of the ice sheet, such as the Minch, changed their geometry significantly, perhaps rapidly; whilst other sectors remained relatively unchanged and stable. We suggest that this behaviour, governed principally by bed topography/bathymetry and ice dynamics, led to reorganisation of the Late Weichselian ice sheet as it retreated back to two main ice centres: one in Western Scotland and the other over Orkney and Shetland. This retreat pattern suggests relatively early deglaciation of NW Lewis (ca. 25 ka BP) and the mountains of far NW Scotland – the latter possibly forming a substantial ice-free land corridor. Our reconstructions differ from most previous syntheses, but are strongly supported by the independently-mapped offshore Quaternary succession and key onshore dating constraints.