The extent of elemental mobility during lower greenschist to
amphibolite facies metamorphism of a uniform turbidite suite
(Greenland Group, New Zealand) has been evaluated using data for
major elements and 19 trace elements. Simple comparison of average
compositions at 2 wt % Al2O3 intervals in the
data suites shows little contrast between lower greenschist protolith
and upper greenschist and amphibolite facies equivalents, except for
enrichment of CaO and Sr, and loss of Ba and Rb, particularly in the
sandier end members. Division into psammitic and pelitic suites using
TiO2/Al2O3 and
Zr/Al2O3 ratios allows delineation of
individual residual enrichment models on Ti-reference element plots,
and both lithotypes can be used to assess potential elemental
mobility. These plots show that a large number of elements (Ti, Al,
Fe, Mg, Ce, Cr, Ga, La, Nb, Ni, Sc, Th, V, Zn and Zr) constitute
immobile reference species, with abundances equal to their equivalent
lithotype in the protolith, and little mass loss or residual
enrichment. K and Rb also largely conform to the residual model, but
in the amphibolite facies some exchange between pelite and psammite
may occur. A number of elements show enrichment (Mn, Cu, Pb, U, Na,
P) or depletion (Y) in a small number of samples, but the
significance of these contrasts is questionable due to relatively
large variation in the protolith. In contrast, Ca and Sr show
progressive and marked enrichment with increasing grade, and Ba and
As are clearly depleted in amphibolite facies psammites. In the
amphibolite facies some Si may have been lost by psammites, and
gained by the pelites, although there has been no mass change from
the suite as a whole. A large part of the Ca and Sr enrichment in the
amphibolite facies can be accounted for by metasomatic homogenization
of calcareous concretions which occur in the lower grade protolith.
The metamorphism of the Greenland Group is thus considered to be
essentially isochemical.