In modern petrology increasing importance is being attached to the content of minor chemical constituents, the determination of which is now frequently required, whereas hitherto they have usually been disregarded. In consequence, methods for their accurate determination in small amount have not always been fully worked out. Copper is a case in point, and it is already clear that the method here advocated will show that this metal is much more widely distributed in rocks than is generally realized. Moreover, the use of a large sample, such as 20-50 grams, is no longer necessary.
In attempting to apply to rocks the very sensitive colorimetric method described by T. Callan and J. A. Russell Henderson, various difficulties were encountered, and modifications were developed whereby the method can be adapted to the determination of from 0·001-0·25 % of CuO in silicate rocks and minerals. The reagent used is sodium diethyl-dithio-carbamate, which gives a yellow colour with copper in slightly ammoniacal solution. The authors give a list of other metals which also give a coloration or turbidity with this reagent.