Haláp Hill is an eroded remnant of young (∼3 Ma) alkaline basalt in the western part of the Bakony–Balaton Highland Volcanic Field, Tapolca, Hungary. Cavities in the basalt contain miarolitic minerals (augite, apatite, magnetite, plagioclase and sanidine), zeolites (analcime, chabazite-Ca, chabazite-Na, garronite, gismondine, gmelinite-Ca, gmelinite-Na, gobbinsite, gonnardite-Na, natrolite, mesolite, phillipsite-Ca, phillipsite-K, phillipsite-Na and scolecite) and other secondary minerals (calcite, smectite-group minerals, goethite and Mn-oxides). Chabazite-Na, gmelinite-Ca, gonnardite-Na, phillipsite-Na and phillipsite-K are reported from Haláp Hill for the first time. The Ca-rich and Na-rich zeolites and abundant calcite were produced by hydrothermal alteration. Mineral assemblages were characterized by X-ray diffraction, differential thermal analysis, energy-dispersive spectrometry and wavelength-dispersive spectrometry. The secondary mineral assemblages were probably formed as a result of low-temperature hydrothermal activity at 50—100°C. Miarolitic minerals crystallized first in cavities in the basalt; they were followed by zeolite-group minerals and calcite. Analcime and phillipsite with or without chabazite/gmelinite/garronite or gobbinsite were the first zeolite-group minerals to crystallize; gonnardite-Na and natrolite crystallized later from Na-rich fluids. Calcite and smectite-group minerals crystallized continually. This paragenetic sequence is similar to others which have been reported in basalt from other localities in the Balaton Highland, Iceland and Northern Ireland.

Quartz from different zones within five granitic pegmatites of the rare-element class from the Borborema Pegmatite Province in northeast Brazil were analysed for fourteen trace elements using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). The concentrations of Li (6—150 ppm), B (1—9 ppm) and Ge (1—23 ppm) in quartz show a positive correlation with Al (30—770 ppm). The concentrations of these elements increase from the border zone to the quartz core of pegmatites of the spodumene or lepidolite subtypes. The Ge concentrations in the quartz core are the highest so far reported in igneous quartz. In the less evolved pegmatites of the beryl-columbite subtype, the Al, Li, B, and Ge concentrations in quartz from all zones remain at the same level as the border and wall zones. The Ti concentrations in quartz from the core of the more evolved pegmatites are below 3 ppm (with Al >250 ppm), contrasting with 7—25 ppm (with Al <280 ppm) in samples from the border and wall zones of the less evolved and more evolved pegmatites. The concentrations of Al. Li, B, Ge, and Ti in quartz are therefore confirmed as good indicators of the degree of magma fractionation and analyses of pegmatite quartz cores can be used for exploration purposes to distinguish pegmatites with high metallogenic potential. Atoms of Li and Al are incorporated into quartz such that Li/Al ranges between 0.75 and 1.0. This suggests a coupled substitution of the form Si4+ ↔ (Li+ + Al3+). The other elements analysed either showed an erratic distribution (e.g. Be and P) or were below the respective limits of detection (Na, K, Rb, Ca, Sr, Mn, Fe) in most samples.

The study discusses the mineralogical, geochemical and thermometric properties of rock-forming blue quartz from eight worldwide occurrences. Compared to non-blue quartz, blue quartz contains significant amounts of submicron-sized (1 μm—100 nm) and nanometre-sized (<100 nm) inclusions. Mica, ilmenite and rutile constitute the most abundant submicron-sized inclusions, and are formed probably by syngenetic precipitation in the boundary layer between quartz and melt (entrapment model). Nanometre-sized rutile possibly originated by epigenetic exsolution of Ti from the quartz structure (exsolution model). Rayleigh scattering of light by nano-particulate inclusions best explains the origin of the blue colour. Blue quartz is generally Ti-rich (∼100—300 ppm) and formed at high temperatures (∼700°C—900°C). The large number, and high spatial density, of tiny xenocrystic inclusions of Ti-bearing minerals make calculations of crystallization temperatures using the Ti-in-quartz thermometer unreliable. The geological significance of blue quartz remains obscure.

Bavenite is an orthorhombic calcium beryllium aluminosilicate, a ≈ 23.2, b ≈ 5.0, c ≈ 19.4 Å, V ≈ 2250 Å3, Z = 4, that crystallizes in the space group Cmcm. The crystal structures of 24 bavenite samples from various localities worldwide were refined to R1 values from 2.4 to 7.5% based on ∼1330 unique reflections collected with Mo-Kα X-radiation on a Bruker P4 CCD single-crystal diffractometer. The composition of each crystal was determined by electron microprobe analysis. There is extensive solid-solution in bavenite according to O(2)OH– + T(4)Si4+ + T(3)Be2+ ⇌ O(2)O2– + T(4)Al3+ + T(3)Si4+, such that the general formula may be written Ca4BexSi9Al4–xO28–x(OH)x, where x ranges from 2.00 to ∼3.00 a.p.f.u. Small amounts of additional Be may be incorporated into bavenite via the substitution T(3)Be + O(2)OH– + Na + T(4)Si2 ⇌ T(3)Si + O(2)O2– + Ca + T(4)Al2. Local (short-range) bond-valence considerations indicate that Short-Range Order (SRO) should be extensive in the bavenite structure, and this is confirmed by Fourier Transform Infrared (FTIR) spectroscopy in the principal OH-stretching region and by 27Al Magic Angle Spinning Nuclear Magnetic Resonance (MAS NMR) spectroscopy. Short-range bond-valence considerations indicate that the T(3)–T(4)–T(3)–T(4) rings of the framework can incorporate any short-range arrangement of cations consonant with their site populations [T(3) = Be,Si; T(4) = Si,Al], and 27Al MAS NMR spectroscopy confirms this, showing the presence of the local clusters T(3)Be–T(4)Al–T(3)Be, T(3)Si–T(4)Al–T(3)Be and T(3)Si–T(4)Al–T(3)Si. Incorporation of Be at the T(3) site is accompanied by local replacement of O2– by (OH)– at the O(2) site and hydrogen bonding to the adjacent O(3) anion; the latter promotes Be → Si substitution at the T(3) tetrahedron adjacent in the b direction. T(3)–T(4)–T(3)–T(4) rings link in the c direction through a T(3)–(1)–(3) linkage [T(1) = Si]. Local bond-valence considerations show that occupancy of both T(3) tetrahedra by Be violates the valence-sum rule, and that the linkage T(3)Be–T(1)Si–T(3)Si provides the constraint whereby Be does not exceed 3 a.p.f.u. in bavenite when incorporated via the substitution O(2)OH– + T(4)Si4+ + T(3)Be2+ ⇌ O(2)O2– + T(4)Al3+ + T(3)Si4+.

Sodic pyroxene is reported from an Ordovician metatrachyte of the Kaczawa Mountains, SW Poland. Its composition ranges from Jd0.98Ae0.02 to Jd0.15Ae0.85. Relict jadeite and phengite (up to 3.75 Si atoms per fomula unit) belong to the peak-pressure assemblage of an early HP-LT event. Later greenschist-facies stages are represented by riebeckite, biotite, chlorite, low-Si potassic white mica and actinolite. P-T pseudosections calculated for the range 200–450°C, 3–13 kbar allow evaluation of the conditions of formation of jadeite in the metatrachyte and derivaton of a P-T path. Considering the position of prograde, peak and retrograde metamorphic assemblages and respective mineral compositions, we can derive the following equilibration stages: 8.5±0.5 kbar, 270±20°C for the pressure maximum, 6.0±1.0 kbar, 310±20°C for the temperature maximum and 3.5±0.5 kbar, 280±20°C as well as <3.5 kbar, <280°C for the retrograde stages.

The metamorphic gradient for the peak-pressure is estimated at ∼10°C/km, which is typical of a subduction setting involving subducted continental crust, in particular of an exhumation channel within a collision zone of a microplate. Based on earlier structural observations, the ESE-oriented subduction in the NE Bohemian Massif was confined with WNW thrusting and followed by extension and ESE backward normal faulting during Devonian–Early Carboniferous times.