Presented here are the preliminary results of a long-term study of S-stars on the AGB. S-stars are important as possible transition objects between oxygen-rich M-stars and carbon stars. The aim of the study is to compare results from our newly gathered observational database for the S-stars with those already obtained for the M- and carbon stars. We can thus follow the changes as the stars evolve along the AGB and more firmly establish the suggested M-MS-S-SC-C evolutionary sequence. It will also allow us to determine the relative importance of processes such as non-equilibrium chemistry, grain formation, and photodissociation in regulating the chemistry in circumstellar envelopes of AGB stars.

We report a spectral line survey of the circumstellar envelopes of evolved stars at millimeter wavelengths. The data allow us to investigate the chemical processes in different physical environments and evolutionary stages. A total of more than 500 emission features (mostly rotational transitions of molecules) are detected in the survey. Our observations show that the sources in different evolutionary stages have remarkably different chemical composition. As a star evolves from AGB stage to proto-planetary nebula, the abundances of Si-bearing molecules (SiO, SiCC, and SiS) decrease, while the abundances of some long-chain molecules, such as CH3CN, C4H, and HC3N, increase. After further evolution to planetary nebula, the abundances of neutral molecules dramatically decrease, and the emission from molecular ions becomes more intense. These differences can be attributed to the changes of the role that dust, stellar winds, shock waves, and UV/X-rays from the central star play in different evolutionary stages. These results will provide significant constraints on models of circumstellar chemistry.

We present preliminary results of an unbiased spectral survey at 1 mm of the oxygen-rich supergiant, VY CMa. A number of exotic molecules have been detected, including NaCl and PO, and a relatively rich organic chemistry is observed. Results of the survey will be compared with carbon-rich stars.

Water maser emission has been detected only toward three planetary nebulae (PNe). In particular, in K3-35, the first PN where water vapor maser emission was detected, the components are located in a torus-like structure with a radius of 85 AU and also at the surprisingly large distance of 5000 AU from the star, in the tips of the bipolar lobes. The existence of these water molecules in PNe is puzzling, probably related to some unknown mechanism shielding them against the ionizing radiation. We report the detection of HCO+ (J = 1 − 0) emission toward K 3-35, that not only suggests that dense molecular gas (~105 cm−3) is present in this PN, but also that this kind of PN can enrich their surroundings with organic molecules.

Through the techniques of millimeter-wave and infrared spectroscopy, over 60 species of gas-phase molecules and a variety of inorganic and organic solids have been detected in the short phase of stellar evolution between the asymptotic giant branch and planetary nebulae. The chemical pathways that lead to the synthesis of complex organic compounds in such low-density environments are therefore important topics of astrochemistry. In this review, we summarize the observational evidence for the existence of complex aliphatic and aromatic compounds in these circumstellar environments, and discuss the nature of their possible carriers. Also discussed are a number of unidentified emission features which may also have an organic origin. The possible relations between these circumstellar organic matter with Solar System organic matter are explored.

One of the key questions of infrared astronomy is how the characteristics of dust depend on the physical properties of the surrounding medium. To address this question, we present results from the Spitzer Space Telescope on two projects designed to study the dust properties of a sample of 25 Planetary Nebulae (PNe) in the Magellanic Clouds, and three well-known Giant Hii regions (NGC 3603, 30 Doradus and N 66/NGC 346). Most PNe show emission from polycyclic aromatic hydrocarbons (PAHs) and only two of them show amorphous silicates. Eleven PNe display a strong broad feature around 11 μm which is attributed to silicon carbide and 8 of them show magnesium sulfide. One PNe, SMP LMC 11, shows spectacular absorption bands due to molecules which are the precursors from which more complex hydrocarbons are formed. The Spitzer spectra of the Hii regions, NGC 3603, 30 Doradus, and NGC 346 are very rich, displaying a wealth of spectral features within each region. This not only allows us to compare the dust at different metallicities but also to study the spatial variations of many features across a given region and correlate it with the distance to the ionizing cluster(s) and other parameters.

The Spitzer Space Telescope has discovered several objects with unusual spectra, where the emission features from polycyclic aromatic hydrocarbons (PAHs) are shifted to longer wavelengths than normally observed. Previously, only two of these class C PAH spectra had been identified. The new and larger sample reveals that PAHs emit at longer wavelengths when processed by cooler radiation fields. Limited laboratory data show that samples with mixtures of aromatic and aliphatic hydrocarbons produce emission features at longer wavelengths than purely aromatic samples. The aliphatic bonds are more fragile and would only survive in cooler radiation fields. In harsher radiation fields, the aliphatics attached to the aromatic hydrocarbons are destroyed.

Although unidentified infrared bands (UIBs) have been observed in many astrophysical environments, there is one notable exception: carbon (C) stars. Only a handful of C stars have been shown to emit UIBs and most have hot companions. This makes C stars with hot companions an ideal location to investigate the emitters of the UIBs. PAHs are excited by absorption of single photons whose energy is then distributed over the whole molecule. These molecules then emit the energy at the characteristic wavelengths, but the precise wavelengths and strength ratios depend on the size, composition and charge state of the individual PAHs. Furthermore, the wavelength of photons needed to excite PAHs depends on their size and charge state. While small PAHs undoubtedly need higher energy (UV) photons, it has been suggested that large or ionized PAHS (>100 C atoms) can be excited by visible or even near-IR photons. The lack of PAH emission from single carbon stars suggests that either PAHs do not form around C stars or that only small neutral grains form, which cannot be excited by a C star's radiation field.

There are two competing formation mechanisms for PAHs around C stars: (1) “bottom-up” where acetylene molecules react to form aromatic rings, building up to PAHs; or (2) “top-down”, where small carbon grains react with H atoms and desorb PAHs

Using spatially resolved spectroscopic observations from Gemini/Michelle, of five carbon stars with hot companions, we investigate the circumstance under which PAH emission occurs and try to discriminate between formation mechanisms.

We have obtained infrared spectra of carbon-rich AGB stars in three nearby galaxies – the Large and Small Magellanic Clouds, and the Fornax dwarf spheroidal galaxy. Our primary aim is to investigate gas compositions and mass-loss rate of these stars as a function of metallicity, by comparing AGB stars in several galaxies with different metallicities. C2H2 are detectable from AGB stars, and possibly PAHs are subsequently formed from C2H2. Thus, it is worth investigating chemical processes at low metallicity. These stars were observed using the Infrared Spectrometer (irs) onboard the Spitzer Space Telescope which covers 5–35 μm region, and the Infrared Spectrometer And Array Camera (isaac) on the Very Large Telescope which covers the 2.9–4.1 μm region. HCN, CH and C2H2 molecular bands, as well as SiC and MgS dust features are identified in the spectra. The equivalent width of C2H2 molecular bands is larger at lower metallicity, thus PAHs might be abundant in AGB stars at low metallicity. We find no evidence that mass-loss rates depend on metallicity. Chemistry of carbon stars is affected by carbon production during the AGB phase rather than the metallicities. We argue that lower detection rate of PAHs from the interstellar medium of lower metal galaxies is caused by destruction of PAHs in the ISM by stronger UV radiation field.

We are conducting multi-transition observations of circumstellar line emission from common molecules such as HCN, SiO, CS, SiS and CN for a large sample of AGB stars with varying photospheric C/O-ratios and mass-loss charachteristics. Our recently published results for SiO and SiS clearly show that major constraints on the relative roles of non-equilibrium chemistry, dust condensation, and photodissociation can be obtained from the study of circumstellar molecular line emission. Presented here are also preliminary results based on detailed radiative transfer modelling of HCN line emission.

We present results of the mid-IR spectra decomposition for planetary nebulae and compact H ii regions in our Galaxy and Magellanic Clouds. The striking correlation between the required PAH component with “7.7” μm band shifted to about 7.8 μm and electron densities of the modeled sources allows us to argue that this PAH component may be in fact PAH anions (PAH−).

Aromatic features at 3.3, 6.2, 7.7, 8.6, 11.3 μm are observed in proto-planetary nebulae (PPNe) as well as in PNe and H ii regions. Aliphatic features at 3.4 and 6.9 μm are also observed; however, these features are often stronger in PPNe than in PNe. These observations suggest an evolution in the features from simple molecules (C2H2) in AGB stars to aliphatics in PPNe to aromatics in PNe. In the same carbon-rich PPNe, a strong, broad, unidentified 21 μm emission feature has been found. We will present recent observations of the aromatic, aliphatic, and 21 μm emission features, along with C2H2 (13.7 μm) and a new feature at 15.8 μm, and discuss correlations among them and other properties of these PPNe.

The mysterious 21 μm emission feature seen in only 12 C-rich proto-planetary nebulae (PPNe) remains unidentified since its discovery in 1989. Over a dozen materials have been suggested as the carrier candidates while none of them has received general acceptance. We investigate the inorganic carrier candidates by applying the observational constraints of the feature strength and associated features. It is found that: (1) three candidates, TiC clusters, fullerenes with Ti impurity atoms, and SiS2, are not abundant enough to account for the emission power of the 21 μm band, (2) five candidates, doped-SiC, SiO2-mantled SiC dust, carbon and silicon mixtures, Fe2O3, and Fe3O4, all show associated features which are either not detected in the 21 μm sources or detected but with a much lower strength, and (3) FeO, which satisfies the abundance constraints, does not display any associated features which are not seen in the 21 μm sources. Moreover, FeO is more likely to survive in the C-rich environment than Fe2O3 and Fe3O4. Thus FeO seems to be the most plausible one among the inorganic carrier candidates.

We present the results of a systematic analysis of the solid state features identified in the circumstellar environments of a large sample of evolved stars with ISO/SWS and Spitzer/IRS spectroscopy. The sample includes several hundred stars with a wide variety of progenitor masses evolving from the early AGB phase to the PN stage. Our observations are used to propose an evolutionary scheme in which the results obtained can be interpreted as a consequence of the nucleosynthesis processes that take place in this short phase of the stellar evolution, in particular the third dredge-up and hot bottom burning, which in turn are also strongly modulated by the stellar metallicity.

We have performed a study of 3.3 micron PAH emission in planetary nebulae using ground-based observations with FLITECAM, one of a suite of instruments designed for airborne astronomy aboard SOFIA, NASA's Stratospheric Observatory for Infrared Astronomy. The survey was performed on the Shane 3 meter telescope at Lick Observatory as part of the ground-based commissioning of the FLITECAM grism spectroscopy mode. Spectral resolution of R ~ 1700 was obtained with direct-ruled KRS-5 grisms. Targets included AGB stars and sources showing PAH emission in KAO, ISO or IRAS observations. Additionally, several oxygen-rich nebulae were observed in order to test methodology. Twenty objects were surveyed, of which 11 showed PAH emission. In objects exhibiting PAH emission, the relationship between the nebular C/O ratio and PAH equivalent width was found, showing a detectable PAH emission cutoff at a nebular C/O ratio of 0.65 ± 0.28. Selected objects with detected PAH emission were further investigated to trace PAH emission spectral variation within individual nebulae.

We present new chemical models of supernova (SN) ejecta based on a chemical kinetic approach. We focus on the formation of inorganic and organic molecules including gas phase dust precursors, and consider zero-metallicity progenitor, massive supernovae and nearby core-collapse supernovae such as SN1987A. We find that both types are forming large amounts of molecules in their ejecta at times as early as 200 days after explosion. Upper limits on the dust formation budget are derived. Our results on dust precursors do not agree with existing studies on dust condensation in SN ejecta. We conclude that PMSNe could be the first non-primodial molecule providers in the early universe, ejecting up to 34% of their progenitor mass under molecular form to the pristine, local gas.

We present an ISOCAM-CVF map of the ρ Oph A region, covering 3′ × 3′. For each 6 arcsec2 pixel, we extract the spectrum from 5–15 μm. We determine the fluxes of the main PAH features by fitting Lorentzian profiles to the spectrum. The peaks of the various PAH components correspond well with the known positions of the PDRs in this vicinity. The spectrum in several pixels exhibits strong rotational lines of molecular hydrogen which can be used to derive the physical properties of the cloud. The H2 emission traces the hot gas of the bipolar CO outflow from VLA1623.

The unidentified infrared (UIR) emission bands in the near- to mid-infrared are thought to originate from organic compounds in the interstellar medium. Recent space observations with Spitzer and AKARI have clearly revealed that the UIR bands are commonly seen in external galaxies, including elliptical galaxies, except for very metal-poor dwarf galaxies. They are also detected in extended structures of galaxies, such as extra-planar components and filaments produced by outflows, suggesting that the band carriers are ubiquitous organic compounds in galaxies. Since the UIR bands are prominent features in the infrared spectrum of galaxies and are linked to the star-formation activity, it is highly important to understand the nature, formation, processing, and destruction of the UIR band carriers in galaxies. While there is no systematic variation detected in the UIR spectrum in normal galaxies, significantly low values are derived for the ratio of the 7.7 μm to 11.2 μm bands in elliptical galaxies as well as in galaxies with low-luminosity AGNs compared to normal star-forming galaxies. Relatively low band ratios are also seen in the UIR band spectrum of extended structures in galaxies. If the same mechanism leads to the low band ratio, it would provide important information on the band carrier properties. It should also be noted that the band carriers are believed to be destroyed in a short time scale in environments where low band ratios are detected. The survival and supply processes in these environments are a key to understand the nature of the band carriers.

We report on recent developments in the study of diffuse interstellar bands in the Local Group galaxies. We present preliminary results on the detection of the 5780 Å DIB toward 17 targets in the vicinity of NGC 206 in M31.

We have carried out the mid-infrared slit spectroscopic observations of sources in the LMC and in NGC 6946 with AKARI/IRC. We investigate the properties of the UIR bands in terms of the star forming activities. We find systematically larger ratios of UIR bands in 6–9 μm to 11.2 μm band in active star forming regions than in the quiet regions. This behavior is consistent with the photo-ionization model of PAHs. Our results suggest that the ratios of UIR bands in 6–9 μm to 11.2 μm band can be used as more efficient and vigorous tools to measure the extent of on-going star formation in remote galaxies rather than just the presence or absence of the features themselves.