We report textural and compositional data for the titanosilicate narsarsukite [Na2(Ti,Fe3+)Si4(O,F)11] in peralkaline granites from the Papanduva Pluton in Graciosa Province, south-southeastern Brazil. Two distinct narsarsukite generations, one late magmatic and the other post-magmatic, were identified on the basis of textural and compositional features. The magmatic generation consists of larger, euhedral to subhedral variably zoned crystals and late poikilitic intergrowths between narsarsukite and albite laths, representing the crystallisation of the latest melt pockets. The post-magmatic generation forms smaller, typically fibrous crystals and irregular aggregates that occur interstitially or replace the primary mafic minerals, particularly arfvedsonite. Compositions of narsarsukite from the Papanduva Pluton cover most of the compositional range described in known occurrences. The magmatic generation is enriched in Zr and depleted in Al. The Fe3+ and Al contents show a positive correlation for the magmatic crystals, but a negative correlation for the post-magmatic narsarsukite. The Al/Fe3+ ratios are higher in the post-magmatic crystals and can be used to discriminate between the two generations. The compositional variations are controlled mainly by the heterovalent substitution (Ti, Zr)4+ + O2– = (Al, Fe)3+ + F1–, and are compatible with (OH)1– ions in the O site. Narsarsukite has significantly higher concentrations of mid REE+Y and HFSE and very low to absent contents of LREE and LILE relative to the host-rocks. The average REE pattern of the magmatic crystals is highly fractionated, consistent with the expected strong preference for the smaller HREE. The post-magmatic crystals that replace arfvedsonite have flatter patterns, with higher concentrations of LREE and MREE. Their compositions suggest a fluid phase relatively rich in HFSE, REE, Y, Pb, Th and U. Narsarsukite is a common phase in strongly peralkaline granites such as the Papanduva Pluton and the well-known Strange Lake Complex, and should be considered a diagnostic mineral of highly peralkaline SiO2-oversaturated rocks containing rare Ti and Zr mineral assemblages.

Magnetite is a common mineral in the Paleoproterozoic Stollberg Zn–Pb–Ag plus magnetite ore field (~6.6 Mt of production), which occurs in 1.9 Ga metamorphosed felsic and mafic rocks. Mineralisation at Stollberg consists of magnetite bodies and massive to semi-massive sphalerite–galena and pyrrhotite (with subordinate pyrite, chalcopyrite, arsenopyrite and magnetite) hosted by metavolcanic rocks and skarn. Magnetite occurs in sulfides, skarn, amphibolite and altered metamorphosed rhyolitic ash–siltstone that consists of garnet–biotite, quartz–garnet–pyroxene, gedrite–albite, and sericitic rocks. Magnetite probably formed from hydrothermal ore-bearing fluids (~250–400°C) that replaced limestone and rhyolitic ash–siltstone, and subsequently recrystallised during metamorphism. The composition of magnetite from these rock types was measured using electron microprobe analysis and LA–ICP–MS. Utilisation of discrimination plots (Ca+Al+Mn vs. Ti+V, Ni/(Cr+Mn) vs. Ti+V, and trace-element variation diagrams (median concentration of Mg, Al, Ti, V, Co, Mn, Zn and Ga) suggest that the composition of magnetite in sulfides from the Stollberg ore field more closely resembles that from skarns found elsewhere rather than previously published compositions of magnetite in metamorphosed volcanogenic massive sulfide deposits. Although the variation diagrams show that magnetite compositions from various rock types have similar patterns, principal component analyses and element–element variation diagrams indicate that its composition from the same rock type in different sulfide deposits can be distinguished. This suggests that bulk-rock composition also has a strong influence on magnetite composition. Principal component analyses also show that magnetite in sulfides has a distinctive compositional signature which allows it to be a prospective pathfinder mineral for sulfide deposits in the Stollberg ore field.

En este trabajo presentamos un análisis zooarqueológico de las relaciones humano-camélido durante el Holoceno en la Puna de Atacama (norte de Chile y Noroeste argentino) a través del estudio de composiciones rupestres interpretadas como escenas de caza durante el lapso entre 9700 y 2500 aP. Estas representaciones aluden a interacciones sociales y a un imaginario visual que vincula humanos y camélidos en un mismo acontecimiento. Planteamos que el estudio de estas manifestaciones pintadas puede aportar evidencia sustancial sobre las características de la caza comunal, la demografía de los cazadores recolectores y los primeros pastores del área surandina. Así, hemos podido identificar con el análisis del arte rupestre, tanto eventos de caza llevada a cabo por grupos locales, como así también cazas colectivas o comunales efectuadas por grupos agregados de población dentro de un ciclo anual o de agregaciones poblacionales extraordinarias. Esto representa un cálculo demográfico efectuado por primera vez a partir de las escenas de caza del arte rupestre.

Making sense of digital security practice requires grasping how data are put to use to compose the governing of individuals. Data need to be understood in their becoming, and in their becoming something across diverse practices. To do this, we suggest embracing two conceptual tropes that jointly articulate the being together of, and in, data compositions: composting and computing. With composting, we approach data as lively entities, and we explore the decaying and recycling processes inside Big Data security. With computing, we approach data as embodied and embodying elements, and we unpack the surveillance of ‘asylum speakers’. Together, composting and computing challenge recurrent images of data. Our conceptual composition takes sound as a necessary sensory counterpoint to popular data visions, notably in light of Ryoji Ikeda's artworks.

Suppose that the function $f$ is analytic in the open unit disk $\unicode[STIX]{x1D6E5}$ in the complex plane. For each $\unicode[STIX]{x1D6FC}>0$ a function $f^{[\unicode[STIX]{x1D6FC}]}$ is defined as the Hadamard product of $f$ with a certain power function. The function $f^{[\unicode[STIX]{x1D6FC}]}$ compares with the fractional derivative of $f$ of order $\unicode[STIX]{x1D6FC}$. Suppose that $f^{[\unicode[STIX]{x1D6FC}]}$ has a limit at some point $z_{0}$ on the boundary of $\unicode[STIX]{x1D6E5}$. Then $w_{0}=\lim _{z\rightarrow z_{0}}f(z)$ exists. Suppose that $\unicode[STIX]{x1D6F7}$ is analytic in $f(\unicode[STIX]{x1D6E5})$ and at $w_{0}$. We show that if $g=\unicode[STIX]{x1D6F7}(f)$ then $g^{[\unicode[STIX]{x1D6FC}]}$ has a limit at $z_{0}$.