In greenhouse studies, the butyl ester of fluazifop {(±)-2-[4-[[5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy]propanoic acid} applied preemergence at 0.035 kg ai/ha gave 91% control of goosegrass (Eleusine indica Gaertn. ♯ ELEIN), 79% control of large crabgrass [Digitaria sanguinalis (L.) Scop. ♯ DIGSA], and 73% control of giant foxtail (Setaria faberi Herrm. ♯ SETFA). In field studies, the butyl ester of fluazifop at 0.56 kg ai/ha applied preemergence gave 79% control of goosegrass, 76% control of large crabgrass, and 53% control of giant foxtail. The butyl ester of fluazifop at 0.07 kg/ha gave 79 to 85% control of each grass at the pretillering stage in field studies. The same rate applied at the early tillering stage gave 84% control of goosegrass but only 53 and 58% control of large crabgrass and giant foxtail, respectively. Relative species response was similar from spray and leaf-spot applications of the herbicide. The butyl ester of fluazifop at 4 μg/plant when spot-applied to leaves of the three grasses at the tillering stage resulted in 65% control of goosegrass but only 20 and 25% control of large crabgrass and giant foxtail, respectively.

Season-long interference of shattercane, giant foxtail, common cocklebur, and common lambsquarters in corn was evaluated in the field at weed densities from 0.4 to 13.1 plants or clumps/m of corn row during 1985, 1986, and 1987. Corn seed yields decreased linearly with increases in the density of clumps of 2 to 3 shattercane plants and 5 to 8 giant foxtail plants, reaching 22% yield loss at 6.6 shattercane clumps/m of row and 18% yield loss at 13.1 giant foxtail clumps/m of row. Increases in common cocklebur density caused corn yields to decrease curvilinearly in 1985 with a maximum predicted yield loss of 27% occurring at a density of 4.7 common cocklebur plants/m of row. In 1986 and 1987, yields decreased linearly as common cocklebur density increased to 6.6 plants/m of row, where a 10% yield loss was observed. Common lambsquarters reduced corn yields only in 1985. In this year, yields decreased curvilinearly with increasing weed density, resulting in a maximum yield loss of 12% at 4.9 common lambsquarters plants/m of row. Corn yields averaged 11600 kg/ha when grown without weed interference in these experiments.

Efficacy of primisulfuron and reduced rates of nicosulfuron on woolly cupgrass, wild-proso millet, and giant foxtail in field corn was evaluated in 1994 and 1995. Nicosulfuron was applied at 18, 27, and 36 g ai/ha alone and with 20 g ai/ha primisulfuron. Woolly cupgrass control from nicosulfuron at 18 and 27 g/ha was less than control from 36 g/ha (79% and 84% vs. 90%, respectively). Woolly cupgrass control was 5% greater when primisulfuron was combined with nicosulfuron at 27 and 36 g/ha than when nicosulfuron was applied alone. Corn grain yields were similar among all nicosulfuron plus primisulfuron treatments applied to control woolly cupgrass in 1994. In 1995, corn grain yield was increased 900 kg/ha when primisulfuron was combined with nicosulfuron at 18 g/ha compared to nicosulfuron applied at the same rate alone. Wild-proso millet control 3 WAT with nicosulfuron at 18 g/ha was less than control with nicosulfuron at 36 g/ha. Wild-proso millet control 8 WAT with nicosulfuron alone was greater than when nicosulfuron at any rate was applied with primisulfuron. No differences in corn grain yields were observed across nicosulfuron rates or combinations with primisulfuron to control wild-proso millet either year. Giant foxtail control and corn grain yield were not affected by nicosulfuron rate or combined applications of nicosulfuron and primisulfuron either year.

Greenhouse and field experiments were conducted to investigate degradation rates and efficacy of EPTC (S-ethyl dipropyl carbamothioate), butylate [S-ethyl bis(2-methylpropyl)carbamothioate], vernolate (S-propyl dipropylcarbamothioate), and cycloate (S-ethyl cyclohexylethylcarbamothioate) in soils with and without prior history of thiocarbamate use. Herbicide persistence was measured by an oat (Avena sativa L.) bioassay, and giant foxtail (Setaria faberi Herrm. # SETFA) control was visually estimated in field studies. Both greenhouse and field studies indicated that enhanced thiocarbamate degradation occurred when the same herbicide (EPTC, butylate, or vernolate) was applied over successive years. Addition of dietholate (O,O-diethyl O-phenyl phosphorothioate) or fonofos (O-ethyl-S-phenylethylphosphonodithioate) increased thiocarbamate persistence and giant foxtail control in soils with prior thiocarbamate exposure. Use of dietholate or fonofos two or three consecutive years with EPTC or butylate again resulted in enhanced degradation. EPTC persistence and giant foxtail control were not affected by prior treatments or tank mixes with carbofuran (2,3-dihydro-2,2-dimethyl-7-benzofuranyl methylcarbamate). Rotation away from successive applications of the same thiocarbamate herbicide (EPTC, butylate, or vernolate) improved herbicide efficacy.

Field experiments were conducted from 1979 to 1989 to determine the influence of conventional, reduced, and no-tillage systems and different herbicide combinations on weed species and population, weed control, and soybean injury, population, and yield. In no-till (NT) non-treated plots, there was an abrupt shift from horseweed as the dominant early spring emerging weed to gray goldenrod in 1985. Following its initial observation, gray goldenrod became the dominant species within 2 yr, with giant foxtail as the only other species observed in these plots. Giant foxtail was the dominant weed species from 1980 to 1989 in conventional till (CT) and reduced-till (RT) plots. There also was a shift in the frequency of occurrence and in density of several broadleaf weed species during the 11-yr study. Most herbicides provided excellent control of all weeds in all tillage systems, especially those that included POST herbicides. There was little difference between glyphosate and paraquat in controlling weeds present at the time of planting in NT. PRE herbicides caused 2 to 9% soybean injury with slightly greater injury occurring in CT and RT than in NT. The POST broadleaf herbicides did not significantly increase soybean injury. There were no differences in soybean population or yield among the herbicide treatments regardless of tillage. There also was no difference in soybean population or yield in NT compared with CT when averaged over all herbicide treatments.

Field studies were conducted in 1996 and 1997 at Belleville and Pawnee, IL, to evaluate single and sequential applications of glufosinate on tolerance of glufosinate-resistant corn and annual weed control. Glufosinate caused 0 to 13% corn injury 7 days after treatment (DAT) and 0 to 6% corn injury 28 DAT. Injury was characterized as stunting with glufosinate. Glufosinate at 400 to 1,200 g ai/ha did not reduce final corn height or grain yield. At Pawnee in both years and at Belleville in 1996, a single application of glufosinate at 400 g/ha controlled giant foxtail, velvetleaf, ivyleaf morningglory, and common lambsquarters 85 to 100%. At Belleville in 1997, sequential applications of glufosinate provided greater weed control (87 to 100%) than a single application (0 to 63%) because of weed emergence after application. Weed control with a single application of glufosinate or with nicosulfuron plus bromoxynil was similar at both locations. Height and grain yield of glufosinate-resistant corn were not different from that of glufosinate-susceptible corn (isoline of glufosinate-resistant corn).

Greenhouse and laboratory studies were conducted to determine the effect of 22 postemergence corn broadleaf herbicide combinations on the efficacy of sethoxydim applied to giant foxtail, large crabgrass, and shattercane. Eighteen combinations caused a reduction in sethoxydim efficacy on at least one grass species. Dicamba, atrazine plus dicamba, atrazine plus bentazon, bromoxynil, primisulfuron, CGA-152005 plus primisulfuron, MON 12000, and flumetsulam plus clopyralid plus 2,4-D (NAF-73) were evaluated further on the efficacy and foliar absorption of sethoxydim applied to giant foxtail, large crabgrass, and shattercane. In timing studies, applying all herbicide combinations at 7 or 3 d before sethoxydim application eliminated significant antagonistic interactions. However, applying NAF-73, primisulfuron, or CGA-152005 plus primisulfuron 1 d prior resulted in a reduction in sethoxydim efficacy on at least one grass species. Dicamba, atrazine plus dicamba, and atrazine plus bentazon decreased 14C-sethoxydim absorption 9 to 63% across grass species. Replacing crop oil concentrate (COC) with DASH increased sethoxydim absorption when applied with these herbicides but not to the full extent of sethoxydim applied alone with DASH. Sethoxydim efficacy was retained or improved with DASH when applied with dicamba, atrazine plus dicamba, atrazine plus bentazon, or bromoxynil. When primisulfuron, CGA-152005 plus primisulfuron, MON 12000, or NAF-73 was applied with 14C-sethoxydim no effect on sethoxydim absorption was observed. DASH was less effective than COC at restoring sethoxydim efficacy when applied with these herbicides.

Greenhouse and laboratory studies were conducted to determine the effects of tank-mixing the sodium salt of dicamba (Na-dicamba) with imazethapyr on the efficacy and foliar absorption of imazethapyr, applied with non-ionic surfactant (NIS) or methylated seed oil (MSO), by shattercane, giant foxtail, and large crabgrass. The effects of various salt formulations of dicamba and the addition of ammonium sulfate on efficacy, 14C-absorption and on foliar spray retention by the same species were also evaluated. Na-dicamba antagonized imazethapyr efficacy by reducing 14C-absorption. Using MSO instead of NIS prevented antagonism when Na-dicamba was applied at 70 and 140 g/ha and reduced the severity of the antagonism at greater application rates by greatly increasing 14C-absorption compared to NIS. Reductions in 14C-absorption and spray retention were due to the salt formulations of dicamba rather than the parent acid. The addition of ammonium sulfate prevented dicamba antagonism of imazethapyr toxicity to grassy weeds by maintaining 14C foliar absorption and spray retention at normal levels.

Barnyardgrass and many broadleaf weeds were severely stunted by POST applications of isoxaben. Most grasses were only moderately affected by isoxaben at rates up to 1 kg/ha. POST activity was enhanced by soil interception, but evident with foliar interception alone. Cell swelling in stems and in interveinal leaf lamina was observed after foliar application. A radiotracer study in redroot pigweed showed that only a small amount (3.3% of applied) of isoxaben entered the leaf following foliar application, and that little (0.08% of applied) isoxaben migrated beyond the point of application. The potential of isoxaben as a POST herbicide may be limited, in part, by poor absorption and translocation.

The effect of methylated seed oil (MSO), the organosilicone adjuvant DC-X2-5394, and ammonium sulfate on the efficacy, absorption, and spray retention of primisulfuron applied alone or with atrazine, dicamba, and bentazon to shattercane and giant foxtail was evaluated. Primisulfuron efficacy on both species was reduced by the three tank-mix combinations. Atrazine antagonism was not explained by decreases in foliar absorption and/or spray retention. Reductions in primisulfuron absorption and/or foliar spray retention appeared to cause bentazon antagonism on both weeds and dicamba antagonism on shattercane. MSO, DC-X2-5394, and ammonium sulfate completely reversed dicamba and bentazon antagonism on shattercane and partially reversed bentazon antagonism on giant foxtail by increasing foliar absorption and/or spray retention. Compared with non-ionic surfactant, MSO and DC-X2-5394 consistently increased giant foxtail control with primisulfuron by increasing foliar absorption and/or spray retention.

The influence of various factors on the tolerance of corn and selected weed species to thifensulfuron was studied in greenhouse experiments. Corn fresh weight was reduced by postemergence application of thifensulfuron when applied at 180 g ai ha−1 without surfactant or at 18 g ha−1 with a nonionic surfactant. Corn was more susceptible to root exposure whereas velvetleaf was more susceptible to foliar exposure. Velvetleaf was most susceptible when plants were young, when a nonionic surfactant was added, and at 20 rather than 30 C. Simulated rainfall 8 h after application reduced velvetleaf injury by thifensulfuron at 18 g ha−1 without surfactant; however, with addition of a nonionic surfactant, velvetleaf injury was reduced only if rainfall occurred less than 2 h after application. Soil moisture level did not affect velvetleaf susceptibility.

In 1992 and 1993, rimsulfuron alone at 17, 35, and 70 g ai/ha, and at 35 g/ha plus metribuzin at 280 g ai/ha, respectively, was evaluated PRE and POST for weed control in potato. Rimsulfuron at 35 g/ha PRE and POST controlled common lambsquarters and giant foxtail and when combined with 280 g/ha metribuzin, controlled common ragweed and jimsonweed. Rimsulfuron and rimsulfuron with metribuzin caused slight to moderate chlorosis in new terminal growth of potato but chlorosis disappeared within 3 wk. Potato height, tuber yields, and tuber quality were not affected by rimsulfuron alone or with metribuzin.

Greenhouse and field experiments were conducted to evaluate early postemergence (POST) tank mixtures of SAN 582 with fluazifop-P, imazethapyr, or sethoxydim. In the greenhouse, SAN 582 synergistically improved barnyardgrass, broadleaf signalgrass, and johnsongrass control from imazethapyr and sethoxydim. Half-rates of imazethapyr and sethoxydim tank-mixed with SAN 582 controlled grass weeds as well as full rates of either herbicide applied alone. Grass weed control with imazethapyr increased up to 40% with the addition of SAN 582. In field experiments, SAN 582 increased grass control with imazethapyr to a lesser degree than observed in the greenhouse. In a multispecies study, grass weed control increased up to 15% when SAN 582 was tank-mixed with a reduced rate of imazethapyr, although the full rate of imazethapyr applied POST with or without SAN 582 controlled grass weeds 80% or less. The combination of SAN 582 with sethoxydim was synergistic for barnyardgrass and johnsongrass control in this experiment. When applied POST in soybean, SAN 582 plus fluazifop-P or sethoxydim controlled barnyardgrass throughout the season better than a single POST application of a graminicide.

Consecutive annual applications of alachlor [2-chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide] and metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide] were made to continuous no-till corn (Zea mays L. ‘Pioneer 3184’ in 1982 and 1983, ‘Pioneer 3744’ in 1984, and ‘Pioneer 3378’ in 1985 to 1987). In a 5-yr study, control of the dominant annual grass species, large crabgrass [Digitaria sanguinalis (L.) Scop. # DIGSA], by alachlor declined to less than 50% by the fifth year. Control of large crabgrass by metolachlor remained greater than 80% throughout the study but metolachlor allowed the establishment of a greater fall panicum (Panicum dichotomiflorum Michx. # PANDI) population in this and an additional 3-yr study than in chloroacetamide-free checks. In the 3-yr study in which giant foxtail (Setaria faberi Herrm. # SETFA) was dominant, annual applications of metolachlor and a microencapsulated formulation of alachlor provided better control in the second year than the emulsifiable concentrate formulation of alachlor, but formulation differences diminished in the third year.

Growth chamber and laboratory experiments evaluated the effects of seed-soil microsite characteristics on seed germination. When corn (Zea mays L. ‘Pioneer 3541’), soybean [Glycine max (L.) Merr. ‘Corsoy 79’], velvetleaf (Abutilon theophrasti Medic. ♯ ABUTH), and giant foxtail (Setaria faberi Herrm. ♯ SETFA) were seeded among soil aggregates 2.50 to 1.25 cm in diameter in the growth chamber, there was decreased seedling emergence with decreasing frequency of irrigation. These same species seeded inside artificial soil aggregates showed increased seedling emergence with decreasing frequency of irrigation. The germination of corn and soybean seed inside 0.4-g, fully moist soil aggregates incubated in the laboratory under high relative humidity conditions was significantly decreased relative to seed incubated in the absence of soil. Velvetleaf and giant foxtail germination was significantly reduced by 0.1-g soil aggregates. Rice (Oryza sativa L.) had 68% emergence from 1.0-g, fully moist soil aggregates, whereas larger seeded corn and soybean had only 20 and 10% emergence, respectively. Germination inhibition of giant foxtail seed by fully moist soil was partially reversed by incubating seed-containing aggregates in an atmosphere of 75% oxygen.

Field research was conducted at Arlington, WI in 1984 and 1985 to determine the influence of application timing on weed control with atrazine and metolachlor in conservation tillage corn production systems. Early preplant treatments controlled fewer weeds than preemergence or early preplant/preemergence sequential treatments in a chisel plow system. Velvetleaf control was only 50% late in the growing season with early preplant atrazine compared with 88% with an early preplant/preemergence sequential treatment of the same amount of atrazine. In the no-till system, early preplant applications of atrazine and/or metolachlor had reduced weed control late in the growing season compared with preemergence and early preplant/preemergence sequential treatments of the same amount of herbicide. Giant foxtail control 110 d after corn planting was only 73% with an early preplant treatment compared with 99% when the same amount of herbicide was evenly divided between early preplant and preemergence applications.

Application of 112 to 336 kg/ha N as ammonium nitrate [NH4(NO−3)] failed to affect population numbers of common lambsquarters (Chenopodium album L.), giant foxtail (Setaria faberi Herrm.), velvetleaf (Abutilon theophrasti Medic.), jimsonweed (Datura stramonium L.), or redroot pigweed (Amaranthus retroflexus L.). Common lambsquarters seeds harvested from NO−3-treated plots were less dormant than control seeds. Seed germination in the laboratory increased from 3.0% for control seeds to 34.0% for seeds harvested from plots treated with 280 kg/ha N as NH4(NO−3). Nitrate concentration in common lambsquarters seeds increased as nitrogen fertilization increased. Seeds from nonfertilized plots contained 18.7 μg/g NO−3, while seeds from plots fertilized with 280 kg/ha N contained 126.3 μg/g. Adding exogenous NO−3 to the germination medium brought the germination of most seed lots to a similar level, except for control seeds which germinated at a lower rate. In contrast to common lambsquarters, nitrogen fertilization did not greatly affect dormancy or NO−3 accumulation in velvetleaf seeds. Exogenous NO−3 failed to stimulate velvetleaf germination because dormant velvetleaf seeds did not imbibe.

In field studies in 1991, 1992, and 1993, rimsulfuron at 26 and 35 g ai/ha, sequentially at 26 g/ha, at 26 g/ha plus metribuzin at 280 g ai/ha, and metribuzin at 280 g/ha were evaluated POST for weed control in transplanted ‘Agriset’ tomato. Common lambsquarters was controlled by rimsulfuron at 35 g/ha. Rimsulfuron plus metribuzin gave consistent control of common ragweed, but jimsonweed control was inconsistent and goosegrass control was generally low. Rimsulfuron treatments caused slight (< 12%) temporary injury to new terminal growth of tomato. Yield of tomato fruit was consistently high in the metribuzin, metribuzin plus rimsulfuron, and rimsulfuron sequential treatments. In greenhouse studies, giant foxtail and large crabgrass control by rimsulfuron was above 95 and 85%, respectively, but goosegrass was not controlled. Height of four tomato cultivars was not reduced, but dry weight of ‘Floradade’ and ‘Sunbeam’ was reduced by rimsulfuron.

Experiments were conducted at Urbana, IL, in 1983 and 1984 to determine the effect of adjuvants, adjuvant rate, and carrier volume on postemergence weed control with bentazon [3-(1-methylethyl)-(1H)-2,1,3-benzothiadiazin-4(3H)-one 2,2-dioxide] and sethoxydim {2-[1-(ethoxyimino)butyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one} in soybeans [Glycine max (L.) Merr. ‘Williams’]. Little difference was observed between a petroleum oil:emulsifier blend (83:17, v/v) (POC) and a soybean oil: emulsifier blend (85:15, v/v) (SBOC) in enhancing control of velvetleaf (Abutilon theophrasti Medik. # ABUTH) with 0.6 or 1.1 kg ai/ha bentazon. Application of bentazon in a carrier volume of 94 L/ha provided velvetleaf control equivalent to that applied in 187 L/ha. Increasing the adjuvant rate from 2.3 to 11.7 L/ha increased visible soybean injury but had no effect on velvetleaf control with bentazon. Control of giant foxtail (Setaria faberi Herrm. # SETFA) with 0.1 kg ai/ha sethoxydim was enhanced more by POC than by SBOC. Phytotoxicity of sethoxydim was not altered by changes in carrier volume or adjuvant rate under conditions of adequate soil moisture in 1983. Under limiting soil moisture in 1984, giant foxtail control with sethoxydim increased slightly when the adjuvant rate was increased from 4.6 to 11.7 L/ha, and carrier volume was increased from 47 to 187 L/ha.

The butyl ester of fluazifop {[(±)-2-[4-[[5-trifluoromethyl)-2-pyridinyl] oxy] phenoxy)propanoic acid} at 0.26 μM in nutrient solution inhibited root growth of hydroponically grown goosegrass (Eleusine indica Gaertn. ♯ ELEIN), large crabgrass [Digitaria sanguinalis (L.) Scop. ♯ DIGSA], and giant foxtail (Setaria faberi Herrm. ♯ SETFA). Treating the soil and plant foliage at 0.035 or 0.07 kg ai/ha did not result in greater phytotoxicity than exposing only the foliage of each grass to the herbicide. Foliar-applied fluazifop was retained on the foliage in similar amounts by each of the species. Translocation of 14C to all plant parts was detected 6 h after foliar application of the butyl ester of 14C-fluazifop to the grasses in the pretillering or tillering stage. The majority (90%) of 14C absorbed by each of the species remained in the treated leaf. In hydroponic studies, each species exuded 14C into nutrient solution following foliar application of the 14C-labeled herbicide. The exuded material was predominantly fluazifop with small amounts of compounds more polar than the butyl ester of fluazifop. Uptake and translocation studies suggest that the greater sensitivity of goosegrass to fluazifop may be related to higher concentrations of the herbicide present in plant tissue.