Ash layers from Searles Lake, California, were sampled in core of drill hole KM-3, which penetrated 693 m of lacustrine sediment deposited in a playa-lake complex over the past 3.2 my. Lake water changed from moderately saline and slightly alkaline (pH ~7.5) to highly saline 2.04 my ago and to highly saline and alkaline (pH ~9.5) 1.28 my ago. As a result of brines flushing downward, the upper 291 m of sediment, spanning the past 1.28 my, contain highly saline, alkaline pore fluid. Silicic ash layers in contact with highly saline, alkaline pore fluid were first altered to phillipsite and meriinoite and then to K-feldspar and searlesite. The transformation of phillipsite and/or meriinoite to K-feldspar required more than 45,000 years and was largely completed in 140,000 years. Tephra layers in contact with moderately saline, slightly alkaline pore fluid vary from uncemented vitric ash containing minor smectite to bentonites in which glass is wholly altered to smectite, clinoptilolite, analcime, and opal. Layers with much fine tephra are more altered than the coarser, better-sorted layers. Alteration is attributed to hydrolysis in essentially a closed hydrologic system, in which the alteration of glass to smectite raised the pH, aSiO2, and (Na+ + K+)/H+ activity ratio to the level where clinoptilolite formed. Some diffusion and/ or fluid flow is, however, indicated by the loss of SiO2 during the alteration of ash layers to smectite and by anhydrite deposited during and after clinoptilolite in some tuffaceous sandstones.

In the post-closure period of a geological disposal facility for radioactive waste, leaching of cement components is likely to give rise to an alkaline plume which will be in chemical disequilibrium with the host rock (which is clay in some concepts) and other engineered barrier system materials used in the facility, such as bentonite. An industrial analogue for cement-clay interaction can be found at Tournemire, southern France, where boreholes filled with concrete and cement remained in contact with the natural mudstone for 15–20 years. The boreholes have been overcored, extracted and mineralogical characterization has been performed. In this study, a reactive-transport model of the Tournemire system has been set up using the general-purpose modelling tool QPAC. Previous modelling work has been built upon by using the most up-to-date data and modelling techniques, and by adding both ion exchange and surface complexation processes in the mudstone. The main features observed at Tournemire were replicated by the model, including porosity variations and precipitation of carbonates, K-feldspar, ettringite and calcite. It was found that ion exchange needed to be included in order for C-S-H minerals to precipitate in the mudstone, providing a better match with the mineralogical characterization. The additional inclusion of surface complexation, however, led to limited calcite growth at the concrete-mudstone interface unlike samples taken from the Tournemire site that have a visible line of crusty carbonates along the interface.

The interaction of two different bulk bentonites (Na- and Ca-types) with three types of simulated cement waters (pH 9.7, 11.3 and 12.0) and one saline groundwater simulate (pH 8.3) as a reference, was studied in batch reactors at 25°C. The solution pH was monitored in order to keep the pH as steady as possible by replacing the leaching solution with fresh one when needed. After 554 days, one set of parallel samples was removed from the experiment in order to investigate the possible changes in the bentonite materials.

The buffering capacity of bentonite was clearly observed, especially at the beginning of the high-pH experiments, as the pH of the leaching solutions decreased quite dramatically due to interaction with bentonite. The solution chemistry results showed a decrease of Ca content in all leachate samples, but especially in pH 12.0 experiments. Small amounts of silica were released throughout the experiment. Both bentonites in pH 12.0 experiments also released detectable amounts of Al, while in the lower pH experiments the levels were below detection limit. These observations were also supported by chemical analyses of the bentonite materials. Only minor changes were detected in the mineralogy, and they were mainly concentrated on experiments at pH 11.3 and pH 12.0. The measured swelling pressure showed an increase in pH 12.0 experiments. The results obtained in this research may facilitate modelling of bentonite interaction with high-pH solutions.

Carbonatite magmas are considered to be ultimately derived from mantle sources, which may include lithospheric and asthenospheric reservoirs. Isotopic studies of carbonatite magmatism around the globe have typically suggested that more than one source needs to be invoked for generation of the parental melts to carbonatites, often involving the interaction of asthenosphere and lithosphere.

In the rift-related, Proterozoic Gardar Igneous Province of SW Greenland, carbonatite occurs as dykes within the Igaliko Nepheline Syenite Complex, as eruptive rocks and diatremes at Qassiarsuk, as a late plug associated with nepheline syenite at Grønnedal-Íka, and as small bodies associated with ultramafic lamprophyre dykes. The well-known cryolite deposit at Ivittuut was also rich in magmatic carbonate. The carbonatites are derived from the mantle with relatively little crustal contamination, and therefore should provide important information about the mantle sources of Gardar magmas. In particular, they are found intruded both into Archaean and Proterozoic crust, and hence provide a test for the involvement of lithospheric mantle.

A synthesis of new and previously published major and trace element, Sr, Nd, C and O isotope data for carbonatites and associated lamprophyres from the Gardar Province is presented. The majority of Gardar carbonatites and lamprophyres have consistent geochemical and isotopic signatures that are similar to those typically found in ocean island basalts. The geochemical characteristics of the two suites of magmas are similar enough to suggest that they were derived from the same mantle source. C and O isotope data are also consistent with a mantle derivation for the carbonatite magmas, and support the theory of a cogenetic origin for the carbonatites and the lamprophyres. The differences between the carbonatites and lamprophyres are considered to represent differing degrees of partial melting of a similar source.We suggest that the ultimate source of these magmas is the asthenospheric mantle, since there is no geochemical or isotopic evidence for their having been derived directly from ancient, enriched sub-continental lithospheric mantle. However, it is likely that the magmas actually formed through a two-stage process, with small-degree volatile-rich partial melts rising from the asthenospheric mantle and being ‘frozen in’ as metasomites, which were then rapidly remobilized during Gardar rifting.

The Inagli complex, one of several Mesozoic intrusive complexes of the Aldan Shield (Siberian Platform), exhibits a concentric structure comprising several alkaline ultramafic rock-types. A central dunite body is surrounded by olivine- and phlogopite-clinopyroxenites forming an inner rim. The outer rim consists of different shonkinitic and malignitic rocks. The K-Ar ages obtained for the whole complex vary around 132 Ma.

The dunites and clinopyroxenites are characterized by cumulate textures. With increasing modal abundances of clinopyroxene and subordinate phlogopite, the rocks develop to olivine-clinopyroxenite, shonkinite, and malignite with intercumulus potassium feldspar. Mineralogical characterization of the rocks suggests they evolved by fractional crystallization. The highly forsteritic olivines (Fo up to 95) require a melt as magnesian as mg# 87.1, representing ±26 wt.% MgO. The parental melt is likely to be an olivine-, H2O- and K2O-rich picritic liquid of shoshonitic character. Major and trace element systematics show high LILE/LREE and LREE/HFSE ratios indicating the involvement of a subduction zone component in the genesis of these rocks.

The incorporation of pertechnetate (TcO4–) into feldspathoids produced by alkaline alteration of aluminosilicate clays may offer a potential treatment route for 99Tc-containing groundwater and liquors. Kaolinite was aged in NaOH to determine the effect of base concentration, temperature, and solution composition on mineral transformation and pertechnetate uptake. In all reactions, increased temperature and NaOH concentration increased the rate of kaolinite transformation to feldspathoid phases. In reactions containing only NaOH, sodalite was the dominant alteration product; however, small amounts (6–15%) of cancrinite also formed. In experiments containing NaOH/Cl and NaOH/NO3 mixtures, sodalite and nitrate cancrinite were crystallized (at 70°C), with no reaction intermediates. The addition of SO42– crystallized sulfatic sodalite at 40 and 50°C, but at higher temperatures (60 and 70°C) sulfatic sodalite transforms to vishnevite (sulfatic cancrinite). In experiments where a pertechnetate tracer was added (at ∼1.5 μmol l–1), only 3–5% of the 99Tc was incorporated into the feldspathoid phases. This suggests that the larger pertechnetate anion was unable to compete as favourably for the internal vacancies with the smaller OH–, NO3–, SO42– or Cl– anions in solution, making this method likely to be unsuitable for groundwater treatment.

Black greasewood (greasewood) and gray rabbitbrush are important shrub components of several plant communities throughout western North America. Land managers may view these species differently depending on their goals. Greasewood and gray rabbitbrush shrub communities may be invaded by several invasive plants including Russian knapweed, perennial pepperweed, hoary cress, halogeton, and several annual mustards. Metsulfuron and chlorsulfuron are commonly used for controlling these and other invasive plants, but little is known regarding their impacts on greasewood and gray rabbitbrush. Our objective was to quantify the impact of these herbicides on greasewood and gray rabbitbrush communities from both an efficacy and nontarget impact perspective. Field studies were established in the spring of 2004 and repeated twice in 2005 near Laramie, WY, in a pasture with mixed stands of greasewood and gray rabbitbrush. Treatments included metsulfuron applied at 21, 42, 63, 84, 126, and 168 g ai/ha (0.3, 0.6, 0.9, 1.2, 1.8 and 2.4 oz ai/A), chlorsulfuron applied at 52, 105, and 157 g ai/ha (0.75, 1.5 and 2.25 oz ai/A), and an untreated control. All treatments contained methylated seed oil at 2% v/v. Treatments were applied in mid-June to 3.3 by 9-m (10 by 30 ft) plots with a handheld broadcast sprayer delivering 187 L/ha (20 gal/ac) in a randomized complete block, with three blocks per study. Plots were sampled 12 and 24 mo after treatment (MAT), utilizing visual control estimates and point frame sampling for vegetative cover of greasewood, gray rabbitbrush, perennial grasses, and bare ground. Metsulfuron at 42 g/ha and chlorsulfuron at 105 g/ha provided > 75% visual control of greasewood 24 MAT. For gray rabbitbrush, metsulfuron at 63 g/ha provided approximately 60% control 24 MAT, while chlorsulfuron provided negligible control at any rate. These results suggest differential impacts of these herbicides on greasewood and gray rabbitbrush, and provide land managers with a decision tool for noxious and invasive weed control when managing for or against greasewood and gray rabbitbrush.

We investigated the chemical characteristics of the astatic soda pans in the Carpathian Basin based on comprehensive new and archive data. Analysed parameters were salinity and ionic composition. The most frequent type of soda waters was the basic alkaline type (Na-HCO3) that represented more than half of the natural soda pans. Besides 11 subtypes occurred. The second and third most frequent types were the chloride (13%) and sulphate subtypes (11%), with the secondary dominance of these anions. The other subtypes meant <4% of the pans. Magnesium sometimes occurred as a secondary dominant cation beside sodium. Until now, this subtype of soda waters has not been published in any part of the world, because of the general rule of soda lake formation (depending on low levels of magnesium and calcium). We found a regionally constant correction factor [Salinity (mg.L−1)=0.8×El.Cond. (μS.cm−1)] for confidentially estimating salinity from electrical conductivity in these habitats. Salinity varied between sub- (0.5–3 g.L−1) and hypersaline (>50 g.L−1) ranges, with its mean value (∼4 g.L−1) in the hyposaline range (3–20 g.L−1). The basic alkaline type had random geographical distribution, while the other subtypes were restricted to certain regions of the Basin. The high number of subtypes reflects the high chemical diversity of alkaline soda pans in the relatively small territory of the Carpathian Basin.

Collision-related rocks intrude metamorphic rocks overthrust by ophiolitic units to make up the Central Anatolian Crystalline Complex. A wide variety of rock types were produced by the latest Cretaceous magmatism in the complex. These rocks can be divided into three distinct units: (1) calc-alkaline (Ağaçören, Behrekdağ, Cefalıkdağ, Çelebi, Ekecikdağ, Halaçlı, Karamadazı, Kösefakılı, Terlemez, Üçkapılı, Yozgat); (2) sub-alkaline (Baranadağ); and (3) alkaline (Atdere, Davulalan, Eğrialan, Hamit, İdişdağı, Karaçayır). The calc-alkaline rocks are metaluminous/peraluminous I- to S-type plutons ranging from monzodiorite to granite. The sub-alkaline rocks are metaluminous I-type plutons ranging from monzonite to granite. The alkaline rocks are metaluminous to peralkaline plutons, predominantly A-type, ranging from foid-bearing monzosyenite to granite. These plutons crystallized under varying pressures (5.3–2.6 kbar) and a wide range of temperatures (858–698 °C) from highly oxidized magmas (log fO2 −17 to −12). All intrusive rocks display enrichment in LILE and LREE compare to HFSE and have high 87Sr/86Sr and low 143Nd/144Nd ratios. These characteristics indicate that these rocks are derived from a mantle source containing large subduction components, and have experienced assimilation coupled with fractional crystallization (AFC) during uprise through crust. The coexistence of calc-alkaline and alkaline magmatism in the complex may be ascribed to mantle source heterogeneity before collision. Either thermal perturbation of the metasomatized lithosphere by delamination of the thermal boundary layer or removal of a subducted plate (slab breakoff) are the likely mechanisms for the initiation of the collision-related magmatism in the complex.

A 49 m complete section through the 288 Ma Lugar Sill obtained from drill cores can be subdivided into nine units. The uppermost four units are teschenitic and are mirror images of the bottom four. A 35 m thick central unit consists of theralite passing down into kaersutite theralite and then picrite. Marginal chilling 'of the units indicates multiple intrusion from the outside inwards. Olivine in the central unit (Fo88–90) encloses Cr-rich spinels and increases in amount inwards to over 50%. Clinopyroxene, kaersutite and biotite show symmetrically increasing Fe/Mg from the centre of the sill outwards. Most major and trace elements vary symmetrically throughout the sill with those in the central unit reflecting mainly olivine distribution but incompatible elements exhibit upward enrichment. Remarkably, the most-evolved rocks in the sill are at its margins. The sill was formed by multiple injections of successively less-evolved teschenitic magmas followed by a larger pulse of theralitic liquid carrying abundant olivine phenocrysts. The amount of olivine in this final pulse increased during emplacement. Subsequent in-situ differentiation in the central unit, with upward enrichment in residual liquid and volatiles, gave rise to lugarites. The various magmas were produced in a lower-level magma chamber by differentiation of a mantle-derived, alkali-rich picritic magma.

Geochemical data are presented for 166 minor intrusions collected across the axis of the Ardgour swarm in the Isle of Lismore. The intrusions can be divided into: an alkali basalt-camptonite-monchiquite group resembling other Scottish Permo-Carboniferous dykes; a group of calc-alkaline (shoshonitic) lamprophyres, diorites and porphyrites with affinities to the late Silurian-early Devonian appinite suite of Scotland; and Tertiary dolerites. The different groups cannot be unambiguously distinguished in the field and secondary alteration precludes petrographic division in many cases. The data indicate that Caledonian and Permo-Carboniferous lamprophyres have probably been confused in previous accounts of dyke distributions in the region. In Lismore the two groups have identical azimuths but the Caledonian intrusions appear to have a greater aggregate volume. The implications for tectonic and regional models of the area are discussed.