The lower Carboniferous–late Permian dyke swarms of the Scottish Highlands and Islands comprise a mild-strongly alkaline basic series of dolerites, camptonites and monchiquites. Differentiation within the suite was largely controlled by olivine + clinopyroxene fractionation. Major and trace element data indicate that dolerites and camptonites chemically overlap, their mineralogical contrasts resulting from differential loss of an H2O, CO2-rich fluid phase during ascent. By contrast most monchiquites have high Mg-values and are relatively primitive compositions, some being near-primary magmas which have risen rapidly from mantle levels with little chemical modification.

HREE-buffered incompatible element profiles imply a garnet–lherzolite source, which must underlie the lithospheric mantle region represented by spinel lherzolite xenoliths found in some monchiquites. C. 0·5–2·0% partial melting can account for the gross incompatible element variation in the suite, but relative fluctuations in K, Ba, Rb, Sr, P and Zr imply chemical heterogeneity controlled either by refractory mantle accessory phases or by modification of magmas during ascent through variably metasomatised lithospheric mantle.

Geochemical data are presented for 166 minor intrusions collected across the axis of the Ardgour swarm in the Isle of Lismore. The intrusions can be divided into: an alkali basalt-camptonite-monchiquite group resembling other Scottish Permo-Carboniferous dykes; a group of calc-alkaline (shoshonitic) lamprophyres, diorites and porphyrites with affinities to the late Silurian-early Devonian appinite suite of Scotland; and Tertiary dolerites. The different groups cannot be unambiguously distinguished in the field and secondary alteration precludes petrographic division in many cases. The data indicate that Caledonian and Permo-Carboniferous lamprophyres have probably been confused in previous accounts of dyke distributions in the region. In Lismore the two groups have identical azimuths but the Caledonian intrusions appear to have a greater aggregate volume. The implications for tectonic and regional models of the area are discussed.

Subaerial lavas and intercalated sediments crop out on the islet of Glas Eilean and the Black Rock skerries in the Sound of Islay between Islay and Jura. The visible succession is c. 120 m thick and is traceable c. 2 km along strike (NNW–SSE). The lavas are alkali olivine-basalts containing olivine ± plagioclase and augite phenocrysts. Decreasing Mg, Cr and Ni upwards, coupled with decreasing average flow thickness and increasing amounts of inter-flow sediment, suggest progressively waning volcanic activity marked by decreasing ascent rates and greater degrees of differentiation. K-Ar dating on one sample gave an early Permian age of 285 ± 5 Ma. It is inferred that the lavas erupted from an isolated basalt volcano situated on a NNW–SSE trending fracture, associated with a narrow developing half-graben within the Dalradian metasediments. The tectonism and magmatism is inferred to be related to the ‘Clyde Belt’ of fault-bounded basins extending from Cheshire to the Little Minch.

Archival and recent boreholes over an area of c. 3 km2 have revealed complex magma-host interaction at the termination of an olivine–dolerite sill in Fife. The sill interior has zones rich in plastically deformed, vesiculated heterogeneous sediment surrounded by amygdaloidal basalt. Sediments at the contacts have been reconstituted and enclose blebs of chilled vesicular basalt. Intrusion into low rank coal seams has produced multicomponent tuffisite. A vertically nested and laterally fingered sill front is envisaged as having propagated down dip under a thin cover (<500 m) of wet Namurian sediments. Non-explosive bulk interaction of fluidised sediment and devolatilising magma occurred at intrusive contacts. Steam explosivity was more vigorous where lobes of magma repeatedly intruded moist lignite, to produce compositionally banded tuffisite rich in basalt clasts and coal fragments. The hydrovolcanic explosions did not give rise to surface eruptions because the low volumes of porewater and the high permeability and low tensile strength of the lignite prevented a build-up of high pressure steam.

Namurian alkali-dolerites in W and central Fife comprise up to nine component sills. These have three-dimensional shapes which are directly related to penecontemporaneous structures in the sedimentary host rocks. Two forms of control are identified. Basinal control is apparent where restored sill geometry shows thickening towards the bottoms of saucer-shapes which mimic sediment disposition at the time of emplacement. Fault control is evidenced by sills which change horizon along extensive E–W fractures once assumed to be entirely post-Carboniferous but now confirmed as growth-faults.

There are no associated dykes representing likely feeders comparable with those of the later tholeiitic Midland Valley Sill, but evidence is presented to suggest that at least some of the alkali-dolerite magma reached sill intrusion levels through volcanic pipes.

A 49 m complete section through the 288 Ma Lugar Sill obtained from drill cores can be subdivided into nine units. The uppermost four units are teschenitic and are mirror images of the bottom four. A 35 m thick central unit consists of theralite passing down into kaersutite theralite and then picrite. Marginal chilling 'of the units indicates multiple intrusion from the outside inwards. Olivine in the central unit (Fo88–90) encloses Cr-rich spinels and increases in amount inwards to over 50%. Clinopyroxene, kaersutite and biotite show symmetrically increasing Fe/Mg from the centre of the sill outwards. Most major and trace elements vary symmetrically throughout the sill with those in the central unit reflecting mainly olivine distribution but incompatible elements exhibit upward enrichment. Remarkably, the most-evolved rocks in the sill are at its margins. The sill was formed by multiple injections of successively less-evolved teschenitic magmas followed by a larger pulse of theralitic liquid carrying abundant olivine phenocrysts. The amount of olivine in this final pulse increased during emplacement. Subsequent in-situ differentiation in the central unit, with upward enrichment in residual liquid and volatiles, gave rise to lugarites. The various magmas were produced in a lower-level magma chamber by differentiation of a mantle-derived, alkali-rich picritic magma.

Post-Variscan magmatism in SW England involved the synchronous emplacement of basaltic and potassic lavas, minette dykes and the Cornubian granite batholith at c. 290 Ma. The basaltic and potassic rocks have high contents of Ni and Cr, which suggest that both are not excessively fractionated. The basaltic lavas are moderately enriched in LREE and LIL elements relative to HREE, whereas the chemically-varied potassic lavas are more strongly enriched in LREE and LIL elements, with notable depletions in Nb, Ta and Ti relative to LREE. These features are consistent with the view that these rocks are subduction-related. Possibly the potassic rocks were derived from an ultimate source in lithosphere subducted or downthrust during the Variscan orogeny. The source of the basaltic rocks was probably in the asthenosphere. The minette dykes are chemically similar to the potassic lavas, suggesting that they are genetically related. Most dykes occur in a zone up to 25 km wide around the margin of the granite batholith, in a “shadow-zone” relationship. The granite batholith (c. 48,000 km3) is moderately enriched in Th and HFS elements, but is strongly enriched in Rb. Rb-Th relationships indicate an origin for the granite by fractionation from potassic magma in addition to melting of crust.

Potassium (K)-rich volcanic rocks occur within Permian sedimentary rocks in SW England and are approximately contemporaneous with the emplacement of the Cornubian granite batholith. The volcanic rocks have chemical characteristics of subduction-related magmas and may have been derived by small amounts of partial melting of heterogeneous large-ion lithophile (LIL) enriched mantle with the assemblage olivine–pyroxene–garnet–phlogopite–titanate. The LIL enrichment may have occurred during shallow or oblique subduction of oceanic lithosphere below SW England during the Devonian and Carboniferous. Such LIL-enriched mantle may have contributed some components to the Cornubian granite batholith.