Bayer Crop Science anticipates launching several premixtures for use in soybean, targeted at control of Palmer amaranth. One of the premixtures will contain diflufenican (Weed Science Society of America [WSSA] Group 12), metribuzin (WSSA Group 5), and flufenacet (WSSA Group 15) (DFF-containing premixture), offering an alternative site of action for soybean producers. Field experiments were conducted in Arkansas and Michigan to evaluate application timings of the DFF-containing premixture for soybean tolerance and weed control and possible cultivar tolerance differences to diflufenican and the DFF-containing premixture. Soybean injury from the 1X and 2X rates of the DFF-containing premixture ranged from 0% to 60% 14 d after planting (DAP), with injury increasing the closer the herbicide was applied to soybean emergence. Excluding the 2X rate applied 3 DAP in Arkansas in 2023, soybean injury was <20% regardless of location, site-year, application timing, and rate. For weed control experiments, only a 1X rate of the DFF-containing premixture was applied at the various application timings. Control of five weed species, encompassing broadleafs and grasses, ranged from 81% to 98%, regardless of application timing, by 28 DAP. By 42 DAP, weed control ranged from 71% to 97%, with the 14-d preplant application timing typically being the least effective. The DFF-containing premixture and diflufenican alone were applied PRE at 1X and 2X rates for the soybean cultivar study. Soybean metribuzin sensitivity did not affect the degree of crop response, even in a high-pH soil, and injury to soybean never exceeded 20%. Overall, the DFF-containing premixture will be a tool that soybean producers can integrate into a season-long herbicide program for use across the United States regardless of soybean cultivar.

Multiple herbicide–resistant (MHR) Palmer amaranth is among the most problematic summer annual broadleaf weeds in Nebraska and several other states. A new MHR corn cultivar (resistant to 2,4-D/glufosinate/glyphosate, also known as Enlist corn) has been commercially available in the United States since 2018. Growers are searching for herbicide programs for control and reduce seed production of MHR Palmer amaranth among Enlist corn crops. The objectives of this study were to evaluate herbicides applied preemergence, early postemergence, or preemergence followed by (fb) late postemergence for the management of MHR Palmer amaranth in Enlist corn fields and to assess their effect on Palmer amaranth biomass, density, seed production, and corn yield. Field experiments were conducted near Carleton, NE, in 2020 and 2021, in a grower’s field of Enlist corn infested with acetolactate synthase–inhibitor/atrazine/glyphosate–resistant Palmer amaranth. Herbicides applied preemergence, such as flufenacet/isoxaflutole/thiencarbazone-methyl, acetochlor/clopyralid/flumetsulam, or acetochlor/clopyralid/mesotrione, provided 75% to 99% control of Palmer amaranth 30 d after preemergence. Preemergence fb late postemergence herbicides resulted in 94% Palmer amaranth control 90 d after late postemergence, reduced weed density to 0 to 8 plants m−2 30 d after late postemergence, and reduced biomass to 2 to 14 g m−2 15 d after late postemergence compared to preemergence-only (59% control, 0 to 15 plants m−2, and 4 to 123 g m−2) and early postemergence–only herbicides (78% control, 6 to 30 plants m−2, and 8 to 25 g m−2). Based on contrast analysis, Palmer amaranth seed production was reduced to 14,050 seeds m–2 in preemergence fb late postemergence herbicide programs compared with 325,490 seed m–2 in preemergence-only and 376,750 seed m–2 in early postemergence–only programs. Based on orthogonal contrast, higher corn yield of 12,340 and 11,730 kg ha−1 was obtained with preemergence fb late postemergence herbicide programs compared with preemergence-only (10,840 and 11,510 kg ha−1) and early postemergence–only programs (10,850 and 10,030 kg ha−1) in 2020 and 2021, respectively.

Six field experiments were established in southwestern Ontario in 2021 and 2022 to evaluate whether the addition of a grass herbicide (acetochlor, dimethenamid-p, flufenacet, pendimethalin, pyroxasulfone, or S-metolachlor) to tolpyralate + atrazine improves late-season weed control in corn. Tolpyralate + atrazine caused 12% and 5% corn injury at 1 and 4 wk after herbicide application (WAA); corn injury was not increased with the addition of a grass herbicide. Weed interference reduced corn yield 60%. The addition of a grass herbicide to tolpyralate + atrazine did not enhance velvetleaf control. The addition of acetochlor or dimethenamid-p to tolpyralate + atrazine enhanced pigweed species control 4% 4 WAA; the addition of other grass herbicides tested did not increase pigweed species control. The addition of acetochlor enhanced common ragweed control 5% at 4 WAA, and the addition of acetochlor or dimethenamid-p enhanced common ragweed control 8% at 8 WAA; the addition of other grass herbicides did not improve common ragweed control. The addition of acetochlor to tolpyralate + atrazine enhanced common lambsquarters control up to 4%; there was no enhancement in common lambsquarters control with the addition of the other grass herbicides. Tolpyralate + atrazine controlled barnyardgrass 90% and 78% at 4 and 8 WAA, respectively; the addition of a grass herbicide enhanced barnyardgrass control 9% to 10% and 21% at 4 and 8 WAA, respectively. Tolpyralate + atrazine controlled green or giant foxtail 80% and 69% at 4 and 8 WAA, respectively; the addition of a grass herbicide enhanced foxtail species control 15% to 19% and 24% to 29% at 4 and 8 WAA, respectively. This research shows that adding a grass herbicide to tolpyralate + atrazine mixture can improve weed control efficacy, especially increased annual grass control in corn production.

Common bean and azuki bean are poor competitors with weeds and demonstrate sensitivity to herbicides used for weed control in soybean. S-metolachlor, flufenacet, and acetochlor are categorized as Group 15 herbicides and provide control of multiple annual grass and select small-seeded broadleaf weeds. By way of field trials near Exeter and Ridgetown, Ontario, in 2019, 2020, and 2021, four dry bean market classes (azuki, kidney, small red, and white bean) were evaluated for their tolerance to 1× established label rates and 2× rates of S-metolachlor (1,600 and 3,200 g ai ha−1), flufenacet (750 and 1,500 g ai ha−1) and acetochlor (1,700 and 3,400 g ai ha−1) applied preplant incorporated (PPI). Injury was evaluated by assessing visible injury symptoms, density, shoot biomass, height, seed moisture content, and seed yield. Azuki bean was more sensitive to the Group 15 herbicides than other dry bean market classes; the Group 15 herbicides caused a 12% reduction in azuki bean growth at 2 wk after emergence; growth reduction was ≤2% in the other bean classes. Flufenacet (2× rate) was the most injurious treatment, causing a 27% reduction in azuki bean yield. This study concludes that kidney, small red, and white bean have a sufficient margin of crop safety to flufenacet, acetochlor, and S-metolachlor applied PPI. Azuki bean was sensitive to flufenacet; additional research is needed to investigate azuki bean tolerance to acetochlor and S-metolachlor applied PPI.

Italian ryegrass is a major weed in winter cereals in the south-central United States. Harvest weed seed control (HWSC) tactics that aim to remove weed seed from crop fields are a potential avenue to reduce Italian ryegrass seedbank inputs. To this effect, a 4-yr, large-plot field study was conducted in College Station, Texas, and Newport, Arkansas, from 2016 to 2019. The treatments were arranged in a split-plot design. The main-plot treatments were (1) no narrow-windrow burning (a HWSC strategy) + disk tillage immediately after harvest, (2) HWSC + disk tillage immediately after harvest, and (3) HWSC + disk tillage 1 mo after harvest. The subplot treatments were (1) pendimethalin (1,065 g ai ha−1; Prowl H2O®) as a delayed preemergence application (herbicide program #1), and (2) a premix of flufenacet (305 g ai ha−1) + metribuzin (76 g ai ha−1; Axiom®) mixed with pyroxasulfone (89 g ai ha−1; Zidua® WG) as an early postemergence application followed by pinoxaden (59 g ai ha−1; Axial® XL) in spring (herbicide program #2). After 4 yr, HWSC alone was significantly better than no HWSC. Herbicide program #2 was superior to herbicide program #1. Herbicide program #2 combined with HWSC was the most effective treatment. The combination of herbicide program #1 and standard harvest practice (no HWSC; check) led to an increase in fall Italian ryegrass densities from 4 plants m−2 in 2017 to 58 plants m−2 in 2019 at College Station. At wheat harvest, Italian ryegrass densities were 58 and 59 shoots m−2 in check plots at College Station and Newport, respectively, whereas the densities were near zero in plots with herbicide program #2 and HWSC at both locations. These results will be useful for developing an improved Italian ryegrass management strategy in this region.

Giant reed recently was promoted as a biofuel crop in Oregon. Because giant reed is a highly invasive plant in North American rivers, the planting of this species in Oregon is a cause for concern to scientists and local land managers. However, some growers in the area were interested in producing giant reed as a rotational crop. To find potential herbicides to control the giant reed or to control it as a volunteer, 13 foliar and 13 cut-and-spray herbicide treatments were preevaluated in greenhouse studies. We chose 10% and 85% reduction in aboveground biomass for either crop safety or control, respectively. When applied at the standard rates, acetochlor and dimethenamid-p reduced aboveground dry biomass of the crop by 10% or less. Acetochlor+atrazine, atrazine, flufenacet, and mesotrione reduced aboveground biomass of the crop by at least 85%, indicating that these compounds have the potential to serve as controls against giant reed.

Weed competition severely constrains cassava root yield in sub-Saharan Africa; thus, good weed control measures, including the use of herbicides, are increasingly important. Herbicide trials were conducted at five locations across eastern, western, and north-central Nigeria over two cropping seasons (2014 and 2015). Nineteen premixed PRE herbicides applied at different rates were evaluated for efficacy on weeds and selectivity on cassava. Manual hoe-weeding at 4, 8, and 12 wk after planting (WAP) and two S-metolachlor + atrazine treatments commonly used by cassava growers were included for comparison. Six of the 19 PRE herbicide treatments (indaziflam + isoxaflutole, indaziflam + metribuzin, flumioxazin + pyroxasulfone, isoxaflutole, acetochlor + atrazine + terbuthylazine, and terbuthylazine + S-metolachlor) consistently provided 80% to 98% broadleaf and grass weed control up to 8 wk after treatment. Overall, PRE herbicide treatments and cassava yield were significantly positively correlated. Herbicide treatments terbuthylazine + S-metolachlor, flumioxazin + pyroxasulfone, diflufenican + flufenacet + flurtamone (respectively, 60 + 60 + 60, 120 + 120 + 120, 90 + 360 + 120, and 135 + 360 + 180 g ha−1), acetochlor + atrazine + terbuthylazine (875 + 875 + 875 g ha−1), S-metolachlor + atrazine (870 + 1,110 g ha−1), oxyfluorfen (240 g ha−1), indaziflam + isoxaflutole (75 + 225 g ha−1), indaziflam + metribuzin (75 + 960 g ha−1), and aclonifen + isoxaflutole (500 + 75 g ha−1) contributed to yields exceeding twice the Nigerian national average of 8.76 tonnes ha−1. These treatments had root yields of 1.4 to 2 times higher than plots that had been hoe-weeded three times. There were some adverse herbicide treatment effects such as delayed cassava sprouting and temporary leaf bleaching observed in indaziflam and diflufenican + flufenacet + flurtamone treatments, whereas sulfentrazone caused prolonged leaf crinkling. The PRE applications alone at rates safe for cassava did not provide adequate season-long weed control; supplemental POST weed control is needed about 10 WAP for satisfactory season-long control.

Many Italian ryegrass populations in Oregon are resistant to more than one herbicide; therefore, the resistance patterns of these populations must be determined to identify alternative herbicides for management. Two suspected resistant Italian ryegrass populations (R2 and R4) survived flufenacet plus metribuzin applications under typical winter wheat production conditions. Populations R2 and R4 were resistant to clethodim, pinoxaden, quizalofop, mesosulfuron-methyl, flufenacet, but not to acetochlor, dimethenamid-p, metolachlor, pyroxasulfone, imazapyr, sulfometuron, or glyphosate. R4 was resistant to diuron, but R2 was not. The estimated flufenacet doses required for 50% growth reduction (GR50) were 438 g ai ha−1 (R2) and 308 g ai ha−1 (R4). Both populations were controlled by pyroxasulfone at rates greater than 15 g ai ha−1. An Asp-2078-Gly substitution in the ACCase gene was found in both populations, while an Ile-2041-Asn was found only in the R4 population. A Ser-264-Gly substitution in psbA gene was found in the R4 population. These mutations previously have been reported to provide resistance to ACCase and photosynthetic inhibitors, respectively. No resistance mutations were identified in the acetolactate synthase (ALS) gene of either population. The addition of the P450 inhibitor, chlorpyrifos, increased the injury resulting from mesosulfuron-methyl on both resistant populations providing indirect evidence that the ALS resistance may be metabolic. Multiple herbicide-resistant Italian ryegrass populations were identified in this study with both target site and nontarget site based mechanisms likely involved. However, several herbicides were identified including pyroxasulfone, a herbicide in the same group as flufenacet, which could be used to control these two populations.

Field studies were conducted in 1999 and 2000 at seven locations in south Texas to evaluate flufenacet plus metribuzin for weed control and corn tolerance. Texas panicum control with flufenacet plus metribuzin was variable with less than 70% control in 1999 and greater than 75% control in 2000. Palmer amaranth and pitted morningglory control ranged from 41 to 100%. Corn stunting (4 to 13%) was noted in soils with greater than 75% sand. Corn yields with flufenacet and metribuzin combinations were increased up to 19% over the untreated check where stunting was not observed.

Field studies were conducted in central Missouri and central Kansas to evaluate the crop tolerance and efficacy of various combinations of atrazine, flufenacet + isoxaflutole, flumetsulam + clopyralid, isoxaflutole, and S-metolachlor applied PPI or PRE in conventional-till corn. Application technique did not influence crop injury in Kansas. In Missouri, greater crop injury was observed with treatments containing isoxaflutole when applied PPI vs. PRE. Application technique influenced giant foxtail, ivyleaf morningglory, large crabgrass, Palmer amaranth, and common waterhemp control. In dry years, control of these weeds was usually either same or greater with PPI than it was with PRE treatments. In years with average to above average precipitation, isoxaflutole provided greater control as a PRE application than as a PPI application. Palmer amaranth and common waterhemp control was usually greater with atrazine, isoxaflutole, and S-metolachlor applied PRE than it was applied PPI. Differences in control of all weeds between PPI and PRE applications were less obvious with two or three herbicides compared with treatments with a single herbicide. In general, the corn yield was greater with most of the treatments having two, three, or four herbicides than it was with treatments having a single herbicide, which was due to better weed control with the tank-mixtreatments.

Field studies were conducted to compare the effectiveness of PRE and POST applications of a prepackaged mixture of flufenacet plus metribuzin with that of diclofop for winter wheat tolerance and control of Italian ryegrass. Additional studies investigated the effectiveness of reduced rates of flufenacet plus metribuzin applied POST to Italian ryegrass when wheat was in the spike stage. All PRE and POST applications of flufenacet plus metribuzin produced similar or greater injury to wheat and more consistent control of Italian ryegrass than PRE or POST applications of diclofop. PRE applications of flufenacet plus metribuzin controlled Italian ryegrass 73 to 77%, whereas POST applications controlled Italian ryegrass 77 to 99%. PRE applications of diclofop controlled Italian ryegrass 57%; POST application controlled Italian ryegrass 78%. Wheat injury from flufenacet plus metribuzin applications varied with application rate, cultivar, and year of application.

Italian ryegrass resistance to diclofop has been documented in several countries, including the United States. The purpose of this research was to screen selected putative resistant populations of Italian ryegrass for resistance to the acetyl-CoA carboxylase (ACCase)–inhibiting herbicides diclofop and pinoxaden and the acetolactate synthase (ALS)–inhibiting herbicides imazamox, pyroxsulam, and mesosulfuron in the greenhouse and to use field experiments to develop herbicide programs for Italian ryegrass control. Resistance to diclofop was confirmed in eight populations from Tennessee. These eight populations did not show cross-resistance to pinoxaden. One additional population (R1) from Union County, North Carolina, was found to be resistant to both diclofop and pinoxaden. The level of resistance to pinoxaden of the R1 population was 15 times that of the susceptible population. No resistance was confirmed to any of the ALS-inhibiting herbicides examined in this research. Field experiments demonstrated PRE Italian ryegrass control with chlorsulfuron (71 to 94%) and flufenacet + metribuzin (84 to 96%). Italian ryegrass control with pendimethalin applied PRE or delayed preemergence (DPRE) was variable (0 to 85%). POST control of Italian ryegrass was acceptable with pinoxaden, mesosulfuron, flufenacet + metribuzin, and chlorsulfuron + flucarbazone (> 80%). Application timing and herbicide treatment had no effect on wheat yield, except for diclofop and pendimethalin treatments, in which uncontrolled Italian ryegrass reduced wheat yield.

Persistence of microencapsulated (ME) and emulsifiable concentrate (EC) formulations of alachlor and acetochlor, as well as EC formulations of metolachlor, s-metolachlor, dimethenamid, and flufenacet were studied using a bioassay based on root response of oat Kassandra grown in soil. Flufenacet was the most persistent of the herbicides, but biologically available residues were not detected at 0- to 10-cm soil depth 50 d after any herbicide treatment. All herbicides applied preemergence (PRE) in field trials gave good to excellent control of redroot pigweed, black nightshade, barnyardgrass, and green foxtail but only partial control of jimsonweed. Furthermore, when they were applied postemergence (POST) in mixture with atrazine in the field, the control obtained for black nightshade, common lambsquarters, common purslane, and redroot pigweed was excellent, but good to excellent for bristly foxtail and green foxtail. Their efficacy against yellow foxtail and large crabgrass was fair to good. Generally, the EC-alachlor and EC-acetochlor applied POST in mixture with atrazine gave better control of grasses than did their ME-formulations. None of the herbicide treatments showed any phytotoxic effect on corn, and all of them produced corn yield greater than that of weedy control but slightly lower than that of the weed-free control. Flufenacet, s-metolachlor, and dimethenamid were suitable alternatives to acetochlor, alachlor, and metolachlor.

Field studies were conducted to evaluate Italian ryegrass control and winter wheat tolerance to applications of diclofop, mesosulfuron plus methylated seed oil (MSO) alone or with 30% urea ammonium nitrate (UAN), mesosulfuron plus thifensulfuron plus tribenuron plus MSO, mesosulfuron plus MCPA plus MSO, or flufenacet plus metribuzin. Treatments were applied to wheat PRE, two- to three-leaf wheat (2–3 LF) at Feekes stage 1.0 or to one- to two-tiller wheat (TILL) at Feekes stage 3.0, depending on label recommendations. Studies were conducted in Williamson, GA, and Plains, GA, from autumn 2003 to spring 2005. Italian ryegrass control was variable, depending on location and year. Maximum and most-consistent Italian ryegrass control (> 90%) occurred with mesosulfuron plus MSO and UAN. Without UAN, control of Italian ryegrass with mesosulfuron varied from 44 to 97%. That variability was partially attributed to unfavorable environmental conditions associated with cold night time temperatures at or below 0 C, following applications. Wheat injury observed in response to herbicide treatments was minimal (< 15%) and transient; wheat recovered with no differences in yield.

Field studies were conducted in 1999 and 2000 at seven locations in south Texas to evaluate flufenacet plus isoxaflutole for weed control and corn tolerance. Palmer amaranth control with flufenacent plus isoxaflutole was variable, with no greater than 60% control at one location and greater than 95% control at another. The poor control at the one location was probably due to lack of rainfall for 3 to 4 wk after corn was planted. Flufenacet plus isoxaflutole at 0.56 or 0.7 kg/ha controlled Texas panicum at least 80%, whereas flufenacet plus isoxaflutole rates lower than 0.56 kg/ha provided variable control (55 to 99%). Flufenacet plus isoxaflutole at 0.35 and 0.49 kg/ha controlled pitted morningglory at least 83%. Corn stunting (3 to 16%) with flufenacet plus isoxaflutole was noted at the one location where the soil sand content was greater than 80% and moisture was received within 48 h of herbicide application. With few exceptions, corn weed control and yield with flufenacet plus isoxaflutole combinations were generally comparable to those observed for the atrazine and acetochlor standard treatments.

Management of Italian ryegrass in cereal-based cropping systems continues to be a major production constraint in areas of the United States, including the soft white winter wheat producing regions of the Pacific Northwest. Pyroxasulfone is a soil-applied herbicide with the potential to control broadleaf and grass weed species, including grass weed biotypes resistant to group 1, 2, and 7 herbicides, in several crops for which registration has been completed or is pending, including wheat, corn, sunflower, dry bean, and soybean. Field experiments were conducted from 2006 through 2009 near Corvallis, OR, to evaluate the potential for Italian ryegrass control in winter wheat with applications of pyroxasulfone. Application rates of PRE treatments ranged from 0.05 to 0.15 kg ai ha−1. All treatments were compared to standard Italian ryegrass soil-applied herbicides used in winter wheat, including diuron, flufenacet, and flufenacet + metribuzin. Visual evaluations of Italian ryegrass and ivyleaf speedwell control and winter wheat injury were made at regular intervals following applications. Winter wheat yields were quantified at grain maturity. Ivyleaf speedwell control was variable, and Italian ryegrass control following pyroxasulfone applications ranged from 65 to 100% and was equal to control achieved with flufenacet and flufenacet + metribuzin treatments and greater than that achieved with diuron applications. Winter wheat injury from pyroxasulfone ranged from 0 to 8% and was most associated with the 0.15–kg ha−1 application rate. However, this early-season injury did not negatively impact winter wheat yield. Pyroxasulfone applied at the application rates and timings in these studies resulted in high levels of activity on Italian ryegrass and excellent winter wheat safety. Based on the results, pyroxasulfone has the potential to be used as a soil-applied herbicide in winter wheat for Italian ryegrass management and its utility for management of other important grass and broadleaf weeds of cereal-based cropping systems should be evaluated.

Experiments were conducted in 2000 and 2001 to evaluate efficacy of AE F130060 03 plus AE F107892 applied postemergence for the control of Italian ryegrass in barley. AE F130060 03 plus AE F107892 controlled Italian ryegrass when applied at two application rates and at three timings. Barley successfully recovered from initial injury caused by early-postemergence (EP) and middle-postemergence (MP) application timings. The late-postemergence (LP) timing resulted in lower yield than the EP or MP application timings. AE F130060 03 plus AE F107892 applied EP controlled Italian ryegrass similar to flufenacet plus metribuzin applied delayed preemergence (DPRE) when rainfall was received. Barley yields were also similar. However, with insufficient rainfall, AE F130060 03 plus AE F107892 provided superior Italian ryegrass control. EP treatments of AE F130060 03 plus AE F107892 after a DPRE application of flufenacet plus metribuzin or chlorsulfuron plus metsulfuron completely controlled Italian ryegrass and resulted in excellent yields.

Field studies were conducted near Oxnard, CA and in two locations near Salinas, CA in 2002 and 2003 to evaluate efficacy and safety of six herbicides in celery. s-metolachlor at 0.6 and 0.7 kg ai/ha and flufenacet at 0.5, 0.6, and 0.7 kg ai/ha PRE were safe to celery and controlled 81 to 94% of yellow nutsedge at densities < 20 plants/m2. At yellow nutsedge densities > 20 plants/m2, the most efficacious treatments were 1.1 kg/ha of s-metolachlor or 0.7 kg/ha of flufenacet, which reduced nutsedge densities by 71 or 53%, respectively; however, both resulted in slight injury to celery. All other herbicides generally did not injure celery and none reduced marketable crop yield. Flumioxazin pretransplant (PRE) at 0.1 and 0.2 kg ai/ha controlled broadleaf weeds near 100% at all locations, suggesting that it can be an effective alternative to standard linuron and prometryn, which are applied post-transplant (POST) in celery.

The persistence and efficacy of acetamide herbicides at application timings from fall to preemergence (PRE) were studied in 1998 and 1999 on mollisols (1.1 to 2.8% organic carbon). Metolachlor, s-metolachlor, acetochlor (as an emulsifiable concentrate [EC] formulation and two encapsulated formulations, capsule suspension [CS] and microencapsulated [ME]), and the combination of flufenacet + metribuzin were evaluated at five application times including late fall, 60 and 30 d early preplant (EPP), preplant incorporated, and PRE. Soil bioassays 180 d after application indicated flufenacet + metribuzin, metolachlor, s-metolachlor, and the acetochlor CS had 62 to 74% giant foxtail control, whereas acetochlor EC and ME had 43 to 46% control. Applications at 60 EPP of metolachlor, s-metolachlor, and acetochlor CS provided 70 to 75% giant foxtail control in greenhouse bioassays, whereas flufenacet + metribuzin, acetochlor ME, and acetochlor EC provided 38 to 57% control. At the 30 EPP timing, metolachlor and acetochlor CS had 80 to 82% control, whereas acetochlor EC provided 46% control, and acetochlor ME, flufenacet + metribuzin, and s-metolachlor had 65 to 74% control. Quantitative soil analysis (0 to 6 cm) 10 d after planting (DAP) indicated metolachlor, s-metolachlor, and acetochlor CS concentrations ranged from 12 to 16% and 32 to 47% of applied herbicide for the fall and PRE application timings, respectively, whereas acetochlor (ME and EC) were from 1 to 3% and 16 to 21% of applied for the fall and PRE application timings, respectively. Bioassay reduction was correlated (R2 = 0.68) with soil-herbicide concentrations at 10 DAP.

Field studies were conducted to evaluate the tolerance of Italian ryegrass and the metribuzin-sensitive winter wheat cultivar Dozier to metribuzin, chlorsulfuron, flufenacet plus metribuzin, chlorsulfuron plus metsulfuron, diclofop, and combinations of these herbicides applied preemergence (PRE) and postemergence (POST) to wheat in the two- to three-leaf (2–3 LF) at Feekes' stage 1 and to one to two tiller wheat (TILL) at Feekes' stage 3. Italian ryegrass control was 80% or greater with diclofop at all rates and application timings; flufenacet plus metribuzin PRE at all rates; metribuzin POST at 2–3 LF at all rates; and chlorsulfuron or chlorsulfuron plus metsulfuron PRE followed by (fb) metribuzin POST at 2–3 LF. Control of 2–3 LF Italian ryegrass was inconsistent with flufenacet plus metribuzin, chlorsulfuron, and chlorsulfuron plus metsulfuron. Italian ryegrass control was poor with flufenacet plus metribuzin TILL, metribuzin PRE, and metribuzin TILL. Metribuzin applied alone and after chlorsulfuron or chlorsulfuron plus metsulfuron injured wheat. Wheat recovered from flufenacet plus metribuzin injury. However, injury from metribuzin at 280 g ai/ha PRE, 2–3 LF, and at 420 g/ha, 2–3 LF, resulted in season-long injury. Yields were significantly reduced because of metribuzin (PRE, 2–3 LF, or TILL) injury and also by chlorsulfuron or chlorsulfuron plus metsulfuron (PRE) fb metribuzin (2–3 LF).