Let $\mathbb F$ be a finite field of odd order and $a,b\in\mathbb F\setminus\{0,1\}$ be such that $\chi(a) = \chi(b)$ and $\chi(1-a)=\chi(1-b)$, where χ is the extended quadratic character on $\mathbb F$. Let $Q_{a,b}$ be the quasigroup over $\mathbb F$ defined by $(x,y)\mapsto x+a(y-x)$ if $\chi(y-x) \geqslant 0$, and $(x,y)\mapsto x+b(y-x)$ if $\chi(y-x) = -1$. We show that $Q_{a,b} \cong Q_{c,d}$ if and only if $\{a,b\}= \{\alpha(c),\alpha(d)\}$ for some $\alpha\in \operatorname{Aut}(\mathbb F)$. We also characterize $\operatorname{Aut}(Q_{a,b})$ and exhibit further properties, including establishing when $Q_{a,b}$ is a Steiner quasigroup or is commutative, entropic, left or right distributive, flexible or semisymmetric. In proving our results, we also characterize the minimal subquasigroups of $Q_{a,b}$.

Let q be an odd prime power and suppose that $a,b\in \mathbb {F}_q$ are such that $ab$ and $(1{-}a)(1{-}b)$ are nonzero squares. Let $Q_{a,b} = (\mathbb {F}_q,*)$ be the quasigroup in which the operation is defined by $u*v=u+a(v{-}u)$ if $v-u$ is a square, and $u*v=u+b(v{-}u)$ if $v-u$ is a nonsquare. This quasigroup is called maximally nonassociative if it satisfies $x*(y*z) = (x*y)*z \Leftrightarrow x=y=z$. Denote by $\sigma (q)$ the number of $(a,b)$ for which $Q_{a,b}$ is maximally nonassociative. We show that there exist constants $\alpha \approx 0.029\,08$ and $\beta \approx 0.012\,59$ such that if $q\equiv 1 \bmod 4$, then $\lim \sigma (q)/q^2 = \alpha $, and if $q \equiv 3 \bmod 4$, then $\lim \sigma (q)/q^2 = \beta $.

We prove that the existence spectrum of Mendelsohn triple systems whose associated quasigroups satisfy distributivity corresponds to the Loeschian numbers, and provide some enumeration results. We do this by considering a description of the quasigroups in terms of commutative Moufang loops. In addition we provide constructions of Mendelsohn quasigroups that fail distributivity for asmany combinations of elements as possible. These systems are analogues of Hall triple systems and anti-mitre Steiner triple systems respectively.