Light stimulation can realise the remote control of the deformation of the specific position of 4D printing structure. Shape-memory polymer–carbon nanotube (CNT) composite materials, with outstanding near-infrared photothermal conversion rate and shape-memory ability, is one type of the most popular light responsive smart materials. However, current studies focused on the photothermal effect and shape-memory applications of light-responsive shape-memory polymer composite (SMPC) sheet structures, and there is no research on the photothermal effect in the depth direction of light-responsive SMPC three-dimensional structures. Here, we prepared a UV curable, mechanically robust, and highly deformable shape-memory polymer (IBBA) as the matrix of light responsive SMPC. CNTs were added as photothermal conversion materials. We explore the photothermal effect of near-infrared laser on the surface and depth of IBBA–CNT composites cube. Shape-memory experiments show that different folded shapes can be obtained by selective near-infrared laser programming. Selective near-infrared laser programming three-dimensional movable type plate shows a programming application in depth direction of three-dimensional light-responsive intelligent structure. This research extends the application of near-infrared laser in 4D printing to the depth direction of intelligent structures, which will bring more complex and interesting 4D printing structures in the future.

Programmable active matter (PAM) combines information processing and energy transduction. The physical embodiment of information could be the direction of magnetic spins, a sequence of molecules, the concentrations of ions, or the shape of materials. Energy transduction involves the transformation of chemical, magnetic, or electrical energies into mechanical energy. A major class of PAM consists of material systems with many interacting units. These units could be molecules, colloids, microorganisms, droplets, or robots. Because the interaction among units determines the properties and functions of PAMs, the programmability of PAMs is largely due to the programmable interactions. Here, we review PAMs across scales, from supramolecular systems to macroscopic robotic swarms. We focus on the interactions at different scales and describe how these (often local) interactions give rise to global properties and functions. The research on PAMs will contribute to the pursuit of generalised crystallography and the study of complexity and emergence. Finally, we ponder on the opportunities and challenges in using PAM to build a soft-matter brain.

Herein, a new method to synthesise epoxide-based sequence-controlled polymers via anionic ring-opening monomer addition, a form of anionic ring-opening polymerisation, is presented. This technique allows in combination with post-polymerisation modification (PPM) reactions for the successful preparation of modified mPEG-b-oligo(allyl glycidyl ether) featuring the incorporation of one repeating unit on average at a time. Due to the possible introduction of a vast variety of molecules to the polymeric system via PPM reactions, a multitude of advanced functional polymeric materials can be generated. This, in combination with the chain extension reactions, allows for the synthesis of well-controlled and programmable architectures with particular properties. The structure of the sequence-controlled polymer was confirmed via 1H NMR spectroscopy, size exclusion chromatography, attenuated total reflection Fourier-transform infrared spectroscopy, and differential scanning calorimetry.

Teaching “calm technology” and “smart materials” as prospective trends in product design is the motivation of the educational workshop presented in this paper. Materials can trigger creative thinking. Indeed, concepts can be generated ideas that come from the encounter with a material showing the material's unexpressed potential. However, a smart material is a complex hybrid object. It is a highly technical matter that requires years of R&D to be developed and matured. It is also a highly social matter, that blurs the traditional boundary between matter and function in a product, creates an experience, and enhances sensations. The workshop presented in this paper is an opportunity for the students to analyze the complexity of user experience related to ambient devices using smart materials. In order to provide a guideline to perform this analysis, an approach based on heuristic evaluation is proposed to the students.

This paper reports an investigation on thermo-electro-mechanical vibration of graphene/piezoelectric graphene/piezoelectric/graphene sandwich nanobeams. Based on the nonlocal elasticity theory, Timoshenko beam theory and Hamilton's principles, the governing equations are developed and solved using generalized differential quadrature (GDQ) method. The effects of the nonlocal parameter, external electrical voltage, temperature change and axial force on vibration of graphene/piezoelectric/graphene sandwich nanobeams are examined. The performance and the accuracy of the presented model are highlighted through numerical examples with different boundary conditions. This study reports that the nonlocal parameter and thermo-electro-mechanical loadings have important effect on the natural frequencies and the deflection mode shapes of the graphene/piezoelectric/graphene sandwich nanobeam. The present work can serve as guideline for the design of a nanoscale graphene/piezoelectric/graphene beams based electromechanical resonator sensors.