Cation Binding by Humic Substances

Edward Tipping

doi:10.1017/CBO9780511535598

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Edward Tipping, Centre for Ecology & Hydrology, Windermere

Publisher:: Cambridge University Press
Online publication date:: August 2009
Print publication year:: 2002
Online ISBN:: 9780511535598
DOI:: https://doi.org/10.1017/CBO9780511535598

Subjects:: Earth and Environmental Sciences, Geochemistry and Environmental Chemistry, Environmental Chemistry, Chemistry
Series:: Cambridge Environmental Chemistry Series (12)

81.99 (GBP)

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Humic substances are highly-abundant organic compounds formed in soils and sediments by the decay of dead plants, microbes and animals. This book focuses on the important binding properties of these compounds which regulate the chemical reactivity and bioavailability of hydrogen and metal ions in the natural environment. Topics covered include the physico-chemical properties of humic matter and interactions of protons and metal cations with weak acids and macromolecules. Experimental laboratory methods are also discussed, together with mathematical modelling. Finally the author looks at how the results of this research can be used to interpret environmental phenomena in soils, waters and sediments. This comprehensive account of cation binding by humic matter is a valuable resource for advanced undergraduate and graduate students, environmental scientists, ecologists and geochemists.

‘I wholeheartedly recommend the book to all workers in the field.’

John Hamilton-Taylor Source: Chemistry and Industry

' … this is a very useful and important monograph'.

Source: Angewandte Chemie

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Cation Binding by Humic Substances

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Contents

Frontmatter
pp i-iv

Contents
pp v-viii

Preface
pp ix-x

1 - Introduction
pp 1-3

2 - Humic substances – a brief review
pp 4-31

3 - Environmental solution and surface chemistry
pp 32-51

4 - Proton dissociation from weak acids
pp 52-76

5 - Metal–ligand interactions
pp 77-102

6 - Methods for measuring cation binding by humic substances
pp 103-127

7 - Quantitative results with isolated humic substances
pp 128-156

8 - Cation binding sites in humic substances
pp 157-170

9 - Parameterised models of cation–humic interactions
pp 171-209

10 - Applications of comprehensive parameterised models
pp 210-252

11 - Predictive modelling
pp 253-261

12 - Cation–humic binding and other physico-chemical processes
pp 262-287

13 - Cation binding by humic substances in natural waters
pp 288-333

14 - Cation binding by humic substances in soils and sediments
pp 334-379

15 - Research needs
pp 380-390

References
pp 391-421

Index
pp 422-434

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Cation Binding by Humic Substances

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