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Chemical Bonding Studies of Solutions by High Resolution X-ray Fluorescence Spectroscopy

Published online by Cambridge University Press:  06 March 2019

Tom Scimeca ,
Sei Fukushima ,
Kazuo Miyamura  and
Yohichi Gohshi
Tom Scimeca
Affiliation:
University of Tokyo Hongo, Bunkyo, Tokyo 113, Japan
Sei Fukushima
Affiliation:
University of Tokyo Hongo, Bunkyo, Tokyo 113, Japan
Kazuo Miyamura
Affiliation:
University of Tokyo Hongo, Bunkyo, Tokyo 113, Japan
Yohichi Gohshi
Affiliation:
University of Tokyo Hongo, Bunkyo, Tokyo 113, Japan
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Extract

High resolution X-Ray Fluorescence Spectroscopy(HRXRFS) has been extensively used as a chemical bonding probe for both solids and gases for quite some time. However there have been virtually no HRXRFS studies reported on liquid phase systems and particularly on solution systems. This seems somewhat surprising not only because this is an unexplored area, but because much of chemistry and chemical bonding occurs in solution. Furthermore, since HRXRFS is a “photon in - photon out” technique, providing one uses relatively energetic x-rays, the experimental techniques for performing these types of measurements are relatively straightforward, especially when compared to techniques which utilize charged particles.

Type
III. Long-Wavelength X-Ray Spectrometry
Information
Advances in X-Ray Analysis , Volume 34: Thirty-Ninth Annual Conference on Applications of X-ray Analysis, July 30 - August 3, 1990 , 1990 , pp. 123 - 130
Copyright
Copyright © International Centre for Diffraction Data 1990

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References

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