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Model, Equations, and Correcting Factors for the X-Ray Fluorescence Analysis of Geological Material

Published online by Cambridge University Press:  06 March 2019

Liberto de Pablo Galán
Liberto de Pablo Galán*
Affiliation:
Consejo de Recursos Naturales No Renovables México 7, D. F. - México
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Abstract

A procedure is presented for the chemical analysis of rocks by x-ray fluorescence. Rocks are grouped within a set of twelve empirical standard compositions, prepared by sintering to 1200°C appropriate mixes of minerals and chemicals. For the major rock components silica, alumina, calcia, magnesia, potash, and ferric oxide, and the trace elements silver, copper, lead, zinc, molybdenum, manganese, tin, and antimony, quadratic equations are derived correlating concentration and intensity ratios corrected for dead time, background, and equipment drift. Interelemental effects are computed as a series of correcting factors modifying the basic analytical equations.

Type
Mathematical Correction Procedures for X-Ray Spectrochemical Analysis
Information
Advances in X-Ray Analysis , Volume 19: Twenty-Fourth Annual Conference on Applications of X-ray Analysis, August 6-8, 1975 , 1975 , pp. 227 - 238
Copyright
Copyright © International Centre for Diffraction Data 1975

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References

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