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X-ray photoelectron spectroscopy characterization of aerosol particles in Antarctica

Published online by Cambridge University Press:  30 April 2015

Simona Rella  and
Cosimino Malitesta
Simona Rella
Affiliation:
Laboratory of Analytical Chemistry, Department of Biological and Environmental Sciences and Technologies, Di.S.Te.B.A., University of Salento, via Monteroni, 73100 Lecce, Italy
Cosimino Malitesta*
Affiliation:
Laboratory of Analytical Chemistry, Department of Biological and Environmental Sciences and Technologies, Di.S.Te.B.A., University of Salento, via Monteroni, 73100 Lecce, Italy
*
cosimino.malitesta@unisalento.it
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Abstract

Qualitative and quantitative analysis of surface species on size-segregated atmospheric particulate collected in Antarctica during the 2010–11 summer was performed by X-ray photoelectron spectroscopy (XPS). This represents the first example of surface characterization of Antarctic aerosols. The size class with particle cut-off diameter of 3 μm was richest in terms of chemical elements. Peculiar findings of the application included detection of Ca (possibly surface-segregated) and surface enrichment of Mg. The determination of nitrate, ammonium and sulphate species on collection filters provides evidence for a possible advantage of XPS over more laborious techniques (e.g. ion chromatography). The presence of these species is in reasonable agreement with other recent reports from Antarctica.

Keywords

Antarctic particulate mattersurface characterization of particulateXPS
Type
Physical Sciences
Information
Antarctic Science , Volume 27 , Issue 5 , October 2015 , pp. 493 - 499
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Copyright
© Antarctic Science Ltd 2015 

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References

Araktingi, Y.E., Bhacca, N.S., Robinson, J.W. & Proctor, W.G. 1971. Analysis of airborne particulates by electron spectroscopy for chemical analysis (ESCA). Spectroscopy Letters, 4, 365–376.Google Scholar
Atzei, D., Fantauzzi, M., Rossi, A., Fermo, P., Piazzalunga, A., Valli, G. & Vecchi, R. 2014. Surface chemical characterization of PM10 samples by XPS. Applied Surface Science, 307, 120–128.Google Scholar
Briggs, D. 1978. X-ray photoelectron spectroscopy as an analytical technique. In Briggs, D., eds . Handbook of x-ray and ultraviolet photoelectron spectroscopy. London: Heyden, 174–176.Google Scholar
Briggs, D. & Seah, M.P. 1990. Practical surface analysis. Vol. 1. Auger and x-ray photoelectron spectroscopy, 2nd Edition. Chichester: Wiley, 674 pp.Google Scholar
Beamson, G. & Briggs, D. 1992. High resolution XPS of organic polymers: the Scienta ESCA300 database. Chichester: Wiley, 306 pp.Google Scholar
Cazaux, J. 2000. About the charge compensation of insulating samples in XPS. Journal of Electron Spectroscopy and Related Phenomena, 113, 15–33.Google Scholar
Dreyer, A., Weinberg, I., Temme, C. & Ebinghaus, R. 2009. Polyfluorinated compounds in the atmosphere of the Atlantic and Southern oceans: evidence for a global distribution. Environment Science & Technology, 43, 6507–6514.Google Scholar
Fattori, I., Becagli, S., Bellandi, S., Castellano, E., Innocenti, M., Mannini, A., Severi, M., Vitale, V. & Udisti, R. 2005. Chemical composition and physical features of summer aerosol at Terra Nova Bay and Dome C, Antarctica. Journal of Environmental Monitoring, 7, 1265–1274.Google Scholar
Ghosal, S., Shbeeb, A. & Hemminger, J.C. 2000. Surface segregation of bromine in bromide doped NaCl: implications for the seasonal variations in Arctic ozone. Geophysical Research Letters, 27, 1879–1882.Google Scholar
Johansson, L.S. & Campbell, J.M. 2004. Reproducible XPS on biopolymers: cellulose studies. Surface and Interface Analysis, 36, 1018–1022.CrossRefGoogle Scholar
Jourdain, B. & Legrand, M. 2002. Year-round records of bulk and size-segregated aerosol composition and HCl and HNO3 levels in the Dumont d’Urville (coastal Antarctica) atmosphere: implications for sea-salt aerosol fractionation in the winter and summer. Journal of Geophysical Research - Atmospheres, 107, 10.1029/2002JD002471.Google Scholar
Kratos Analytical . 2009. AXIS Ultra DLD operators manual, Ref: 39-306. Manchester: Kratos Analytical.Google Scholar
Minikin, A., Legrand, M., Hall, J., Wagenbach, D., Kleefeld, C., Wolff, E., Pasteur, E.C. & Ducroz, F. 1998. Sulfur-containing species (sulfate and methanesulfonate) in coastal Antarctic aerosol and precipitation. Journal of Geophysical Research - Atmospheres, 103, 10 975–10 990.Google Scholar
Mustafi, N., Raine, R. & James, B. 2010. Characterization of exhaust particulates from a dual fuel engine by TGA, XPS, and Raman techniques. Aerosol Science and Technology, 44, 954–963.Google Scholar
Planchon, F.A.M., Boutron, C.F., Barbante, C., Cozzi, G., Gaspari, V., Wolff, E.W., Ferrari, C.P. & Cescon, P. 2002. Changes in heavy metals in Antarctic snow from Coats Land since the mid-19th to the late-20th century. Earth and Planetary Science Letters, 200, 207–222.Google Scholar
Song, J. & Peng, P. 2009. Surface characterization of aerosol particles in Guangzhou, China: a study by XPS. Aerosol Science and Technology, 43, 1230–1242.Google Scholar
Teinilä, K., Kerminen, V.-M. & Hillamo, R. 2000. A study of size-segregated aerosol chemistry in the Antarctic atmosphere. Journal of Geophysical Research - Atmospheres, 105, 3893–3904.Google Scholar
Wagenbach, D., Ducroz, F., Mulvaney, R., Keck, L., Minikin, A., Legrand, M., Hall, J.S. & Wolff, E.W. 1998. Sea-salt aerosol in coastal Antarctic regions. Journal of Geophysical Research - Atmospheres, 103, 10 961–10 974.Google Scholar
Wolff, E.W., Suttie, E.D. & Peel, D.A. 1999. Antarctic snow record of cadmium, copper, and zinc content during the twentieth century. Atmospheric Environment, 33, 1535–1541.Google Scholar
Wolff, E.W., Hall, J.S., Mulvaney, R., Pasteur, E.C., Wagenbach, D. & Legrand, M. 1998. Relationship between chemistry of air, fresh snow and firn cores for aerosol species in coastal Antarctica. Journal of Geophysical Research - Atmosphere, 103, 11 057–11 070.Google Scholar